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We present a combined high-resolution x-ray diffraction and x-ray resonant magnetic scattering (XRMS) study of as-grown BaFe2As2. The structural/magnetic transitions must be described as a two-step process. At T_S = 134.5 K we observe the…

SrRh2As2 exhibits structural phase transitions reminiscent to those of BaFe2As2, but crystallizes with three polymorphs derived from the tetragonal ThCr2Si2-type structure. The structure of \alpha-SrRh2As2 is monoclinic with a = 421.2(1)…

Superconductivity · Physics 2012-02-02 V. Zinth , V. Petricek , M. Dusek , D. Johrendt

Single crystals of Ca(Fe1-xRux)2As2 (0<x<0.065) and Ca1-yLay(Fe0.973Ru0.027)2As2 (0<y<0.2) have been synthesized and studied with respect to their structural, electronic and magnetic properties. The partial substitution of Fe by Ru induces…

Strongly Correlated Electrons · Physics 2015-12-23 K. Zhao , C. Stingl , R. S. Manna , C. Q. Jin , P. Gegenwart

A series of (Li$_{0.8}$Fe$_{0.2}$)OHFeSe$_{1-x}$S$_x$ (0 $\leq$ x $\leq$ 1) samples were successfully synthesized via hydrothermal reaction method and the phase diagram is established. Magnetic susceptibility suggests that an…

Superconductivity · Physics 2015-01-07 X. F. Lu , N. Z. Wang , X. G. Luo , G. H. Zhang , X. L. Gong , F. Q. Huang , X. H. Chen

Iron-based compounds (IBS) display a surprising variety of superconducting properties that seems to arise from the strong sensitivity of these systems to tiny details of the lattice structure. In this respect, systems that become…

We studied the effect of hydrostatic pressure (P) on the structural phase transitions and superconductivity in the ternary and pseudo-ternary iron arsenides CaFe2As2, BaFe2As2, and (Ba0.55K0.45)Fe2As2, by means of measurements of electrical…

Superconductivity · Physics 2015-05-13 M. S. Torikachvili , S. L. Budko , Ni Ni , P. C. Canfield

In this letter we show that superconducting Fe1.01Se undergoes a structural transition at 90 K from a tetragonal to an orthorhombic phase but that non-superconducting Fe1.03Se does not. Further, high resolution electron microscopy study at…

Superconductivity · Physics 2009-08-11 T. M. McQueen , A. J. Williams , P. W. Stephens , J. Tao , Y. Zhu , V. Ksenofontov , F. Casper , C. Felser , R. J. Cava

The transport properties, phase diagram, and dopant distribution are investigated in systematically Nd doped CaFe_2As_2 single crystals. Coexistence of two superconducting (SC) phases with different critical transition temperature (T_c) is…

Superconductivity · Physics 2014-11-13 Bo Gao , Xiaojiang Li , Qiucheng Ji , Gang Mu , Wei Li , Tao Hu , Ang Li , Xiaoming Xie

We use angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations to study the electronic structure of CaFe$_2$As$_2$ in previously unexplored collapsed tetragonal (CT) phase. This unusual phase of…

Pressure-dependent diffraction response of the superconducting phase separated Cs0.72Fe1.57Se2 has been studied using synchrotron radiation up to the pressure of 19 GPa. The main and secondary phases of Cs0.72Fe1.57Se2 have been observed in…

BaFe2Se3 (Pnma, CsAg2I3-type structure), recently assumed to show superconductivity at ~ 11 K, exhibits a pressure-dependent structural transition to the CsCu2Cl3-type structure (Cmcm space group) around 60 kbar, as evidenced from…

Single crystals of Ca1-xLaxFe2As2 for x ranging from 0 to 0.25 have been grown and characterized by structural, transport and magnetic measurements. Coexistence of two superconducting phases is observed, in which the low superconducting…

Superconductivity · Physics 2013-10-21 Y. Sun , W. Zhou , L. J. Cui , J. C. Zhuang , Y. Ding , F. F. Yuan , J. Bai , Z. X. Shi

We prepared the samples K$_{1-x}$Ln$_{x}$Fe$_2$As$_2$ (Ln=Sm, Nd and La) with ThCr$_2$Si$_2$-type structure. These samples were characterized by X-ray diffraction, resistivity, susceptibility and thermoelectric power (TEP). Substitution of…

Superconductivity · Physics 2008-11-18 R. H. Liu , G. Wu , H. Chen , Y. L. Xie , Y. J. Yan , T. Wu , X. F. Wang , J. J. Ying , Q. J. Li , B. C. Shi , X. H. Chen

The low-temperature crystal structure of Fe1.13Te, which exhibits an anomalous two-step magnetic transition, was clarified by the systematic x-ray diffraction measurements. It was found that two-step structural phase transition,…

The effects of Co-substitution on Ba(Ni$_{1-x}$Co$_x$)$_2$As$_2$ ($0\leq x\leq 0.251$) single crystals grown out of Pb flux are investigated via transport, magnetic, and thermodynamic measurements. BaNi$_2$As$_2$ exhibits a first order…

BaNi$_2$As$_2$ exhibits a first order structural transition at 130 K. Understanding this structural transition is a crucial step towards understanding the electronic properties of the material. We present a combined optical spectroscopy and…

Superconductivity · Physics 2009-09-15 Z. G. Chen , G. Xu , W. Z. Hu , X. D. Zhang , P. Zheng , G. F. Chen , J. L. Luo , Z. Fang , N. L. Wang

We present a systematic pressure study of poly- and single crystalline SrFe2As2 by electrical resistivity and X-ray diffraction measurements. SrFe2As2 exhibits a structural phase transition from a tetragonal to an orthorhombic phase at…

We use neutron scattering to study the spin and lattice structures of single crystal and powder samples of Na$_{1-\delta}$FeAs ($T_c = 23$ K). On cooling from room temperature, the system goes through a series of phase transitions: first…

Superconductivity · Physics 2009-07-10 Shiliang Li , Clarina de la Cruz , Q. Huang , G. F. Chen , T. -L. Xia , J. L. Lou , N. L. Wang , Pengcheng Dai

Single crystals of K$_x$Fe$_{2-y}$Se$_2$ are prepared by quenching at various temperatures. The crystals obtained at higher quenching temperatures have a surface morphology with mesh-like texture. They show a sharp superconducting…

Single crystals of undoped CaFe2As2 were grown by a FeAs self-flux method, and the crystals were quenched in ice-water rapidly after high temperature growth. The quenched crystal undergoes a collapsed tetragonal structural phase transition…

Superconductivity · Physics 2017-08-22 Dong-Yun Chen , Jia Yu , Bin-Bin Ruan , Qi Guo , Lei Zhang , Qing-Ge Mu , Xiao-Chuan Wang , Bo-Jin Pan , Gen-Fu Chen , Zhi-An Ren