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Platelet-like single crystals of the Ca(Fe1-xCox)2As2 series having lateral dimensions up to 15 mm and thickness up to 0.5 mm were obtained from the high temperature solution growth technique using Sn flux. Upon Co doping, the c-axis of the…

We report the detection of unusual superconductivity up to 49 K in single crystalline CaFe2As2 via electron-doping by partial replacement of Ca by rare-earth. The superconducting transition observed suggests the possible existence of two…

Superconductivity · Physics 2011-10-28 B. Lv , L. Z. Deng , M. Gooch , F. Y. Wei , Y. Y. Sun , J. Meen , Y. Y. Xue , B. Lorenz , C. W. Chu

Iron-based superconductors can be categorized as two types of parent compounds by considering the nature of their temperature-induced phase transitions; namely, first order transitions for 122- and 11-type compounds and second-order…

The finding of superconductivity in Ba0.6K0.4Fe2As2 put the attention on the investigation of compounds that crystallize with ThCr2Si2 structure type such as AT2X2 (A = alkali/ alkaline earth/ rare earth element; T = transition metal and X…

Superconductivity · Physics 2012-12-10 Andrea V. Hoffmann , Viktor Hlukhyy , Thomas F. Fässler

We report the results of a systematic investigation of the phase diagram of the iron-based superconductor, Ba1-xKxFe2As2, from x = 0 to x = 1.0 using high resolution neutron and x-ray diffraction and magnetization measurements. The…

We report $^{75}$As Nuclear Magnetic Resonance data in a single crystal of CaFe$_2$As$_2$. The Knight shift, electric field gradient, and spin-lattice relaxation rate are strongly temperature dependent in the paramagnetic state, and change…

Strongly Correlated Electrons · Physics 2009-02-11 S. -H. Baek , N. J. Curro , T. Klimczuk , E. D. Bauer , F. Ronning , J. D. Thompson

The effects of pressure up to $\sim 20$ kbar, on the structural phase transition of SrFe$_2$As$_2$ and lightly Sn-doped BaFe$_2$As$_2$, as well as on the superconducting transition temperature and upper critical field of…

Superconductivity · Physics 2009-11-13 M. S. Torikachvili , S. L. Bud'ko , N. Ni , P. C. Canfield

EuFe2As2 is a member of the ternary iron arsenide family. Similar to BaFe2As2 and SrFe2As2, EuFe2As2 exhibits a clear anomaly in resistivity near 200 K. It suggests that EuFe2As2 is another promising parent compound in which…

Superconductivity · Physics 2009-11-13 Yanpeng Qi , Zhaoshun Gao , Lei Wang , Dongliang Wang , Xianping Zhang , Yanwei Ma

We report the synthesis and physical properties of single crystals of stoichiometric BaNi2As2 that crystalizes in the ThCr2Si2 structure with lattice parameters a = 4.112(4) \AA and c = 11.54(2) \AA. Resistivity and heat capacity show a…

Superconductivity · Physics 2008-08-12 F. Ronning , N. Kurita , E. D. Bauer , B. L. Scott , T. Park , T. Klimczuk , R. Movshovich , J. D. Thompson

Quantum transitions in Fe-based systems are believed to involve spin, charge and nematic fluctuations. Complex structural phase diagram in these materials often emphasizes importance of covalency in their exotic properties, which is…

Magnetization, susceptibility, specific heat, resistivity, neutron and x-ray diffraction have been used to characterize the properties of single crystalline CaFe2-xNixAs2 as a function of Ni doping for x varying from 0 to 0.1. The combined…

Single crystals of BaFe$_2$As$_2$ and (Ba$_{0.55}$K$_{0.45}$)Fe$_2$As$_2$ have been grown out of excess Sn with 1% or less incorporation of solvent. The crystals are exceptionally micaceous, are easily exfoliated and can have dimensions as…

Single crystals of Ba(Fe$_{1-x}$Ru$_x$)$_2$As$_2$, $x<0.37$, have been grown and characterized by structural, magnetic and transport measurements. These measurements show that the structural/magnetic phase transition found in pure…

Superconductivity · Physics 2015-05-19 A. Thaler , N. Ni , A. Kracher , J. Q. Yan , S. L. Bud'ko , P. C. Canfield

From first-principles density functional theory calculations combined with varying temperature Raman experiments, we show that AFe$_2$As$_2$ (A=Ba, Sr), the parent compound of the FeAs based superconductors of the new structural family,…

Superconductivity · Physics 2009-01-13 D. Hou , Q. M. Zhang , Z. Y. Lu , J. H. Wei

Transport and magnetic studies of PbTaSe$_2$ under pressure suggest existence of two superconducting phases with the low temperature phase boundary at $\sim 0.25$ GPa that is defined by a very sharp, first order, phase transition. The first…

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

Superconductivity · Physics 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

Aliovalent rare earth substitution into the alkaline earth site of CaFe2As2 single-crystals is used to fine-tune structural, magnetic and electronic properties of this iron-based superconducting system. Neutron and single crystal x-ray…

Superconductivity · Physics 2015-03-19 S. R. Saha , N. P. Butch , T. Drye , J. Magill , S. Ziemak , K. Kirshenbaum , P. Y. Zavalij , J. W. Lynn , J. Paglione

Using {\it ab initio} molecular dynamics we investigate the electronic and lattice structure of $A$Fe$_2$As$_2$ ($A$=Ca, Sr, Ba) under pressure. We find that the structural phase transition (orthorhombic to tetragonal symmetry) is always…

Superconductivity · Physics 2009-10-13 Yu-Zhong Zhang , Hem C. Kandpal , Ingo Opahle , Harald O. Jeschke , Roser Valenti

The structural features and physical properties of the antiferromagnetic K0.8Fe1.6Se2 (so called K2Fe4Se5 phase) have been studied in the temperature range from 300K up to 600K. Resistivity measurements on both single crystal and…

Superconductivity · Physics 2015-05-28 Y. J. Song , Z. Wang , Z. W. Wang , H. L. Shi , Z. Chen , H. F. Tian , G. F. Chen , H. X. Yang , J. Q. Li

CaFe2As2 single crystals under uniaxial pressure applied along the c axis exhibit the coexistence of several structural phases at low temperatures. We show that the room-temperature tetragonal phase is stabilized at low temperatures for…