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High temperature superconductivity is often found in the vicinity of antiferromagnetism. This is also true in LaFeAsO$_{1-x}$F$_{x}$ ($x \leq$ 0.2) and many other iron-based superconductors, which leads to proposals that superconductivity…

Superconductivity · Physics 2015-09-30 J. Yang , R. Zhou , L. L. Wei , H. X. Yang , J. Q. Li , Z. X. Zhao , Guo-qing Zheng

We report measurements of structural phase transition of four parent compounds $R$FeAsO ($R$ = La, Sm, Gd, and Tb) by means of low-temperature X-ray diffraction (XRD). Magnetic transition temperatures associated with Fe ions ($T_{N1}$) are…

We measure the resistivity and magnetic susceptibility in the temperature range from 5 K to 600 K for the single crystals $A$Fe$_{2-y}$Se$_2$ ($A$ = K$_{0.8}$, Rb$_{0.8}$, Cs$_{0.8}$, Tl$_{0.5}$K$_{0.3}$ and Tl$_{0.4}$Rb$_{0.4}$). A sharp…

Superconductivity · Physics 2015-05-27 R. H. Liu , X. G. Luo , M. Zhang , A. F. Wang , J. J. Ying , X. F. Wang , Y. J. Yan , Z. J. Xiang , P. Cheng , G. J. Ye , Z. Y. Li , X. H. Chen

The structure and electronic density of states in layered LnFeAsO$_{1-x}$F$_x$ (Ln=La,Sm; $x$=0.0, 0.125, 0.25) are investigated using density functional theory. For the $x$=0.0 system we predict a complex potential energy surface, formed…

Superconductivity · Physics 2009-11-13 P. V. Sushko , A. L. Shluger , M. Hirano , H. Hosono

Sr2VO{3-delta}FeAs superconductors with different oxygen deficiencies have been successfully fabricated. It is found that the superconducting transition temperature drops down monotonically with the increase of oxygen deficiency. The…

Superconductivity · Physics 2016-06-28 Fei Han , Xiyu Zhu , Gang Mu , Peng Cheng , Bing Shen , Bin Zeng , Hai-Hu Wen

We review neutron scattering investigations of the crystal structures, magnetic structures, and spin dynamics of the iron-based RFe(As,P)O (R=La, Ce, Pr, Nd), (Ba,Sr,Ca)Fe2As2, and Fe1+x(Te-Se) systems. On cooling from room temperature all…

Superconductivity · Physics 2009-05-20 Jeffrey W. Lynn , Pengcheng Dai

Temperature-dependent synchrotron powder diffraction on Cs0.83(Fe0.86Se)2 revealed first order I4/m to I4/mmm structural transformation around 216{\deg}C associated with the disorder of the Fe vacancies. Irreversibility observed during the…

Materials Science · Physics 2011-11-01 V. Svitlyk , D. Chernyshov , E. Pomjakushina , A. Krzton-Maziopa , K. Conder , V. Pomjakushin , V. Dmitriev

We report the temperature dependent x-ray powder diffraction of the FeAs-based superconductors in the range between 300 K and 95 K. In the case of NdOFeAs we have detected the structural phase transition from the tetragonal phase, with…

Superconductivity · Physics 2009-01-12 Alessandro Ricci , Michela Fratini , Antonio Bianconi

The recently discovered high-T$_c$ superconductor Ca$_{1-x}$La$_{x}$FeAs$_{2}$ is a unique compound not only because of its low symmetry crystal structure, but also because of its electronic structure which hosts Dirac-like metallic bands…

Strongly Correlated Electrons · Physics 2017-01-25 Chang-Jong Kang , Turan Birol , Gabriel Kotliar

By using a hydrothermal ion-exchange method, we have successfully grown superconducting crystals of LiOHFeS with ${T_c}$ of about 2.8 K. Being different from the sister sample (Li${_{1-x}}$Fe${_x}$)OHFeSe, the energy dispersion spectrum…

Superconductivity · Physics 2016-12-13 Hai Lin , RuiZhe Kang , Lu Kong , XiYu Zhu , Hai-Hu Wen

We present neutron scattering data on two single crystals of the high temperature superconductor La2-x(Ca,Sr)xCaCu2O6+delta. The Ca0.1-doped crystal exhibits a long-range antiferromagnetically ordered ground state. In contrast, the…

Superconductivity · Physics 2011-10-28 M. Huecker , Young-June Kim , G. D. Gu , B. D. Gaulin , J. W. Lynn , J. M. Tranquada

Here we report the synthesis and basic characterization of LaFe1-xCoxAsO for several values of x. The parent phase LaFeAsO orders antiferromagnetically (TN ~ 145 K). Replacing Fe with Co is expected to both electron dope the system and…

Superconductivity · Physics 2009-11-13 Athena S. Sefat , Ashfia Huq , Michael A. McGuire , Rongying Jin , Brian C. Sales , David Mandrus

While for a long time iron based superconductors have been investigated looking at the average crystalline structure there is now growing interest on the divergence of local from the average structure. Here we use advanced data analysis of…

Establishing a complete electronic phase diagram for REFeAsO (RE = rare earth, RE1111) ironbased superconductors has remained experimentally challenging. Here, we report a systematic investigation of PrFeAsO1-xFx over the full nominal…

The new quaternary iron arsenide-fluoride SrFeAsF with the tetragonal ZrCuSiAs-type structure was synthesized and the crystal structure was determined by X-ray powder diffraction (P4/nmm, a = 399.30(1), c = 895.46(1) pm). SrFeAsF undergoes…

Superconductivity · Physics 2009-01-06 M. Tegel , S. Johansson , V. Weiss , I. Schellenberg , W. Hermes , R. Poettgen , Dirk Johrendt

We report the results of a systematic investigation of the phase diagram of the iron-based superconductor, Ba1-xKxFe2As2, from x = 0 to x = 1.0 using high resolution neutron and x-ray diffraction and magnetization measurements. The…

Single crystal neutron diffraction is used to investigate the magnetic and structural phase diagram of the electron doped superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$. Heat capacity and resistivity measurements have demonstrated that Co…

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered…

Superconductivity · Physics 2015-05-27 P. Zavalij , Wei Bao , X. F. Wang , J. J. Ying , X. H. Chen , D. M. Wang , J. B. He , X. Q. Wang , G. F Chen , P-Y Hsieh , Q. Huang , M. A. Green

The microstructural evolution throughout the first order tetragonal to orthorhombic structural transition is analyzed by powder diffraction analysis for two different systems belonging to the class of compounds referred to as 1111…

Superconductivity · Physics 2015-06-04 A. Martinelli , A. Palenzona , M. Putti , C. Ferdeghini

Connections between crystal chemistry and critical temperature $T_c$ have been in the focus of superconductivity, one of the most widely studied phenomena in physics, chemistry and materials science alike. In most Fe-based superconductors,…

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