Related papers: Effect of Structural Parameters on Superconductivi…
Since the discovery of superconductivity\cite{1} at 26 K in oxy-pnictide $LaFeAsO_{1-x}F_x$, enormous interests have been stimulated in the fields of condensed matter physics and material sciences. Among the five different structures in…
We have synthesized two iron fluo-arsenides $A$Ca$_2$Fe$_4$As$_4$F$_2$ with $A$ = Rb and Cs, analogous to the newly discovered superconductor KCa$_2$Fe$_4$As$_4$F$_2$. The quinary inorganic compounds crystallize in a body-centered…
We have synthesized four iron-based oxyarsenide superconductors Rb$Ln_2$Fe$_4$As$_4$O$_2$ ($Ln$ = Sm, Tb, Dy and Ho) resulting from the intergrowth of RbFe$_2$As$_2$ and $Ln$FeAsO. It is found that the lattice match between RbFe$_2$As$_2$…
We report the realization of superconductivity by an isovalent doping with phosphorus in LaFeAsO. X-ray diffraction shows that, with the partial substitution of P for As, the Fe$_2$As$_2$ layers are squeezed while the La$_2$O$_2$ layers are…
We have synthesized oxygen-deficient fluorine-doped samples of nominal composition PrFeAsO$_{1-x}$F$_y$ to study the normal and superconducting state properties. Resistivity of undoped PrFeAsO exhibits a strong anomaly at around 155 K due…
Superconducting [(Li(1-x)Fex)OH](Fe(1-y)Liy)Se (x ~ 0.2, y ~ 0.08) was synthesized by hydrothermal methods and structurally characterized by single crystal X-ray diffraction. The crystal structure contains anti-PbO type (Fe(1-y)Liy)Se…
We have investigated the influence of Ca ions substitution on the structural and superconducting properties of (Nd1-xCax)(Ba1.6La0.4)Cu3Oz system. Magnetization, X-ray diffraction and neutron diffraction studies have been carried out on a…
We report on the synthesis and microstructural studies of fluorine based iron doped superconductors. We have successfully synthesized the fluorine based new superconducting material LaO1-xFxFeAs by choosing comparatively lower temperature…
Here we report a new class of superconductors prepared by high pressure synthesis in the quaternary family ReFeAsO1-delta (Re = Sm, Nd, Pr, Ce, La) without fluorine doping. The onset superconducting critical temperature (Tc) in these…
We report $^{75}$As nuclear magnetic resonance (NMR) / nuclear quadrupole resonance (NQR) and transmission electron microscopy (TEM) studies on LaFeAsO$_{1-x}$F$_{x}$. There are two superconducting domes in this material. The first one…
The tetragonal-to-orthorhombic structural phase transition (SPT) in LaFeAsO (La-1111) and SmFeAsO (Sm-1111) single crystals measured by high resolution x-ray diffraction is found to be sharp while the RFeAsO (R=La, Nd, Pr, Sm)…
The newly discovered superconductor FeSe1-x (x=0.08, Tconset=13.5 K at ambient pressure rising to 27 K at 1.48 GPa) exhibits a structural phase transition from tetragonal to orthorhombic below 70 K at ambient pressure - the crystal…
Raman spectra of polycrystalline NdFeAsO1-xFx (x=0.0, 0.1, 0.2) compound have been systematically investigated as functions of temperature and fluorine concentration. Scanning electron microscopic and Raman microscopic characterization…
Polycrystalline samples and single crystals of SmFeAs1-xPxO1-y were synthesized and grown employing different synthesis methods and annealing conditions. Depending on the phosphorus and oxygen content, the samples are either magnetic or…
Superconducting single crystals of SmFeAsO$_{1-x}$ without fluorine doping were grown at a pressure of 3.3 GPa and a temperature of 1350-1450 $^\circ$C by using the self-flux method. Plate-like single crystals of a few-150 $\mu$m in their…
We report on the synthesis and structural/ microstructural studies of iron based fluorine doped LaOFeAs superconductors. We have successfully synthesized fluorine doped superconducting LaO1-xFxFeAs materials by choosing lower temperature…
Single crystal synchrotron X-ray diffraction as a function of temperature and pressure has revealed a complex biphase mixture in superconducting FeSe. Based on our experimental results we construct a phase diagram where structural behavior…
A series of (Li$_{0.8}$Fe$_{0.2}$)OHFeSe$_{1-x}$S$_x$ (0 $\leq$ x $\leq$ 1) samples were successfully synthesized via hydrothermal reaction method and the phase diagram is established. Magnetic susceptibility suggests that an…
We report the synthesis and thermoelectric transport properties of As-doped layered pnictogen oxyselenides NdO0.8F0.2Sb1-xAsxSe2 (x < 0.7), which are predicted to show high-performance thermoelectric properties based on first-principles…
We have investigated experimentally how properties of NdFeAsO0.8F0.2 superconductor affected due to the substitution of the calcium by the neodymium. We have synthesized polycrystalline Nd1-xCaxFeAsO0.8F0.2 samples with x=0, 0.01, 0.025,…