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In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…

Statistical Mechanics · Physics 2014-08-28 Barbara Drossel

On the one hand, the dissipated heat of a thermodynamic work extraction process upper bounds the non-predictive information, which the associated system encodes about its environment. Thus, emergent information processing capabilities can…

Neurons and Cognition · Quantitative Biology 2020-09-10 Kai Ueltzhöffer

Three different approaches to derive mutual information via thermodynamics are presented where the temperature-dependent energy is given by: (a) $\beta \mathcal{E} = -\ln[P(X,Y)]$, (b) $\beta \mathcal{E} =-\ln[P(Y|X)]$ or (c) $\beta…

Statistical Mechanics · Physics 2010-03-24 Yitzhak Peleg , Hadar Efraim , Ori Shental , Ido Kanter

The Kelvin-Planck statement of the Second Law of Thermodynamics is a stricture on the nature of heat receipt by any body suffering a cyclic process. It makes no mention of temperature or of entropy. Beginning with a Kelvin-Planck statement…

Mathematical Physics · Physics 2023-08-28 Martin Feinberg , Richard B. Lavine

The recent experimental realization of exotic matter states in isolated quantum systems and the ensuing controversy about the existence of negative absolute temperatures demand a careful analysis of the conceptual foundations underlying…

Statistical Mechanics · Physics 2015-01-05 Stefan Hilbert , Peter Hänggi , Jörn Dunkel

For binary mixtures of fluids without chemical reactions, but with components having different temperatures, the Hamilton principle of least action is able to produce the equation of motion for each component and a balance equation of the…

Mathematical Physics · Physics 2009-05-05 Henri Gouin , Tommaso Ruggeri

This work is concerned with our recently developed formalism of non-equilibrium thermodynamics. This formalism extends the classical irreversible thermodynamics which leads to classical thermodynamics and can not describe physical phenomena…

Analysis of PDEs · Mathematics 2018-09-06 Zaibao Yang , Wen-An Yong , Yi Zhu

Stochastic thermodynamics provides a framework for describing small systems like colloids or biomolecules driven out of equilibrium but still in contact with a heat bath. Both, a first-law like energy balance involving exchanged heat and…

Statistical Mechanics · Physics 2012-05-21 Udo Seifert

A new thermodynamic inequality is derived which leads to the maximum work that can be extracted from multi-heat baths with the assistance of discrete quantum feedback control. The maximum work is determined by the free-energy difference and…

Quantum Physics · Physics 2009-11-13 Takahiro Sagawa , Masahito Ueda

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

Carath\'eodory's formalism for classical thermodynamics is a rich alternative approach to this theory, although unpopular with students and physics professors. This approach dispenses with the content of thermal machines for the…

Classical Physics · Physics 2021-10-08 Pedro F. da Silva Júnior

The second law of thermodynamics, formulated as an ultimate bound on the maximum extractable work, has been rigorously derived in multiple scenarios. However, the unavoidable limitations that emerge due to the lack of control on small…

Quantum Physics · Physics 2016-04-27 H. Wilming , R. Gallego , J. Eisert

The second law of thermodynamics constitutes a fundamental principle of physics, precluding the existence of perpetual motion machines and providing a natural definition of the arrow of time. Its scope extends across virtually all areas of…

General Relativity and Quantum Cosmology · Physics 2025-10-21 Alejandro Corichi , Omar Gallegos

We treat a quantum mechanical system with certain general properties which are expected to be common in macroscopic quantum systems. Starting from a PURE initial state (which may not describe an equilibrium) in which energy is mildly…

Statistical Mechanics · Physics 2007-05-23 Hal Tasaki

We investigate the unified first law and the generalized second law in a modified holographic dark energy model. The thermodynamical analysis on the apparent horizon can work and the corresponding entropy formula is extracted from the…

General Relativity and Quantum Cosmology · Physics 2015-06-19 Hui Li , Yi Zhang

We provide a simple physical interpretation, in the context of the second law of thermodynamics, to the information inequality (a.k.a. the Gibbs' inequality, which is also equivalent to the log-sum inequality), asserting that the relative…

Information Theory · Computer Science 2009-03-29 Neri Merhav

This paper investigates generalized thermodynamic relationships in physical systems where relevant macroscopic variables are determined by the exponential Kolmogorov-Nagumo average. We show that while the thermodynamic entropy of such…

Statistical Mechanics · Physics 2025-01-23 Pablo A. Morales , Jan Korbel , Fernando E. Rosas

Universality of classical thermodynamics rests on the central limit theorem, due to which, measurements of thermal fluctuations are unable to reveal detailed information regarding the microscopic structure of a macroscopic body. When small…

Quantum Physics · Physics 2024-02-28 Lucas Chibebe Céleri , Łukasz Rudnicki

The present work deals with three alternative generalized Bekenstein-Hawking formulation of thermodynamical parameters namely entropy and temperature for the universal thermodynamical system bounded by a horizon in the frame work of…

General Physics · Physics 2017-02-21 Subhajit Saha , Subenoy Chakraborty

The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason
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