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Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

We extend the stochastic energetics to a relativistic system. The thermodynamic laws and equipartition theorem are discussed for a relativistic Brownian particle and the first and the second law of thermodynamics in this formalism are…

High Energy Physics - Theory · Physics 2013-05-24 T. Koide , T. Kodama

In this paper, heat and Carnot's working substance are defined respectively by the equations $E=3pV$ and $E=3/2pV$, relating the energy $E$, the pressure $p$ and the volume $V$ of these two corpuscular systems. The thermodynamic-kinetic…

Chemical Physics · Physics 2019-10-08 Claudio Zamitti Mammana

We show that classical thermodynamics has a formulation in terms of Hamilton-Jacobi theory, analogous to mechanics. Even though the thermodynamic variables come in conjugate pairs such as pressure/volume or temperature/entropy, the phase…

High Energy Physics - Theory · Physics 2008-11-26 S. G. Rajeev

A new microcanonical equilibrium state is introduced for quantum systems with finite-dimensional state spaces. Equilibrium is characterised by a uniform distribution on a level surface of the expectation value of the Hamiltonian. The…

Quantum Physics · Physics 2007-10-25 Dorje C. Brody , Daniel W. Hook , Lane P. Hughston

A consequence of the Second Law of thermodynamics is that no thermodynamic system with a single heat source at constant temperature can convert heat into mechanical work in a recurrent manner. First we note that this is equivalent to…

Optimization and Control · Mathematics 2020-06-30 Arjan van der Schaft , Dimitri Jeltsema

Despite its enormous empirical success, the formalism of quantum theory still raises fundamental questions: why is nature described in terms of complex Hilbert spaces, and what modifications of it could we reasonably expect to find in some…

Quantum Physics · Physics 2017-04-27 Marius Krumm , Howard Barnum , Jonathan Barrett , Markus P. Mueller

A general quantum theory encompassing Mechanics, Thermodynamics and irreversible dynamics is presented in two parts. The first part is concerned exclusively with the description of the states of any individual physical system. It is based…

Quantum Physics · Physics 2007-05-23 Gian Paolo Beretta

In the presence of feedback control by "Maxwell's demon," the second law of thermodynamics and the nonequilibrium equalities such as the Jarzynski equality need to be generalized. In this paper, we derive the generalized Jarzynski…

Statistical Mechanics · Physics 2015-05-28 Takahiro Sagawa

We pointed out that the generalized second law of thermodynamics on a de Sitter universe whose energy density stochastically fluctuates due to quantum fluctuations is seemingly violated. We have shown that even in such a case, the…

General Relativity and Quantum Cosmology · Physics 2018-01-17 Naritaka Oshita

We review our approach to the second law of thermodynamics, viewed as a theorem asserting the growth of the mean (Gibbs-von Neumann) entropy of quantum spin systems undergoing automorphic (unitary) adiabatic transformations. Non-automorphic…

Mathematical Physics · Physics 2022-08-16 Walter F. Wreszinski

An essential role of information in microscopic thermodynamics (e.g. Maxwell's demon) opens a challenging question if there exists a formulation of the second law of thermodynamics based only on pure information ideas. Here, such a…

Statistical Mechanics · Physics 2022-04-29 Miroslav Holeček

We extend the Carath\'{e}odory principle of the Second Law to quantum thermodynamics with energy levels depending on macroscopic variables, such as volume and magnetic field. This extension introduces the concept of Quantum Thermodynamic…

Statistical Mechanics · Physics 2025-09-09 Ruo-Xun Zhai , C. P. Sun

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park

We investigate the thermodynamics at the apparent horizon of the FRW universe in $f(R,T)$ theory under non-equilibrium description. The laws of thermodynamics have been discussed for two particular models of $f(R,T)$ theory. The first law…

General Relativity and Quantum Cosmology · Physics 2014-09-26 M. Sharif , M. Zubair

We consider a single harmonic oscillator coupled to a bath at zero temperature. As is well known, the oscillator then has a higher average energy than that given by its ground state. Here we show analytically that for a damping model with…

Quantum Physics · Physics 2009-11-13 ILki Kim , Guenter Mahler

We solve a set of selected exercises on rotational motion requiring a mechanical and thermodynamical analysis. When non-conservative forces or thermal effects are present, a complete study must use the first law of thermodynamics together…

Classical Physics · Physics 2014-04-08 Julio Güémez , Manuel Fiolhais

Remarkable progress of quantum information theory (QIT) allowed to formulate mathematical theorems for conditions that data-transmitting or data-processing occurs with a non-negative entropy gain. However, relation of these results…

Quantum Physics · Physics 2016-09-26 G. B. Lesovik , A. V. Lebedev , I. A. Sadovskyy , M. V. Suslov , V. M. Vinokur

We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…

Statistical Mechanics · Physics 2008-07-30 Antonin Coutant , S. G. Rajeev

Classical thermodynamics is unrivalled in its range of applications and relevance to everyday life. It enables a description of complex systems, made up of microscopic particles, in terms of a small number of macroscopic quantities, such as…

Quantum Physics · Physics 2016-01-13 James Millen , André Xuereb
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