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We consider how trapped molecules can be sympathetically cooled by ultracold atoms. As a prototypical system, we study LiH molecules co-trapped with ultracold Li atoms. We calculate the elastic and inelastic collision cross sections of LiH…

A model of the collisional kinetics of energetic hydrogen atoms, molecules, and ions in pure H$_2$ discharges is used to predict H$_\alpha$ emission profiles and spatial distributions of emission from the cathode regions of low-pressure,…

Plasma Physics · Physics 2015-05-20 A. V. Phelps

Polar molecules in superpositions of rotational states exhibit long-range dipolar interactions, but maintaining their coherence in a trapped sample is a challenge. We present calculations that show many laser-coolable molecules have…

We present an extensive range of quantum calculations for the state-changing rotational dynamics involving two simple molecular anions which are expected to play some role in evolutionary analysis of chemical networks in the Interstellar…

Chemical Physics · Physics 2020-10-28 Jan Franz , Barry Mant , Lola González-Sánchez , Roland Wester , Franco A. Gianturco

The one-particle density matrices for hard core bosons in a one-dimensional harmonic trap are computed numerically for systems with up to 160 bosons. Diagonalization of the density matrix shows that the many-body ground state is not…

Soft Condensed Matter · Physics 2007-05-23 T. Papenbrock

We report on the electrostatic trapping of neutral SrF molecules. The molecules are captured from a cryogenic buffer-gas beam source into the moving traps of a 4.5 m long traveling-wave Stark decelerator. The SrF molecules in…

The electron-electron correlation term in two-atomic collision is the most important, most difficult term to obtain the effective interatomic potential. Generally the H and H collision is a four center problem. It is extremely difficult to…

Atomic Physics · Physics 2013-11-14 Hasi Ray

The collisions between linear polar molecules, trapped in a microwave field with circular polarization, are theoretically analyzed. The microwave trap suggested by DeMille \cite{DeMille} seems to be rather advantageous in comparison with…

Atomic Physics · Physics 2015-05-13 Alexander V. Avdeenkov

We theoretically investigate the properties of highly polar diatomic molecules containing $^2S$-state transition-metal atoms. We calculate potential energy curves, permanent electric dipole moments, spectroscopic constants, and leading…

Atomic Physics · Physics 2021-02-16 Michał Śmiałkowski , Michał Tomza

We report the production of a high phase-space density mixture of $^{87}$Rb and $^{133}$Cs atoms in a levitated crossed optical dipole trap as the first step towards the creation of ultracold RbCs molecules via magneto-association. We…

Atomic Physics · Physics 2011-07-29 H. W. Cho , D. J. McCarron , D. L. Jenkin , M. P. Köppinger , S. L. Cornish

Exchange interaction strongly influences the long-range behaviour of localised electron orbitals. It violates the oscillation theorem (creates extra nodes) and produces a power-law decay instead of the usual exponential decrease at large…

Materials Science · Physics 2012-12-12 V. V. Flambaum

We study the formation of C$_{18}$H and C$_{18}$H$_2$ by irradiating a cyclo[$18$]carbon molecule with atomic and molecular hydrogen at impact energy, $E$, in the range of 0.5-25 eV. We utilize the density-functional tight-binding method to…

We study cold heteronuclear atom ion collisions by immersing a trapped single ion into an ultracold atomic cloud. Using ultracold atoms as reaction targets, our measurement is sensitive to elastic collisions with extremely small energy…

Atomic Physics · Physics 2010-10-19 Christoph Zipkes , Stefan Palzer , Lothar Ratschbacher , Carlo Sias , Michael Köhl

In recent experiments using the Stark-induced Adiabatic Raman Passage (SARP) technique, Zhou et al. measured the product's angular distribution for the collisions between He and aligned D2 molecules at cold collision energies. The…

Doubly dipolar molecules exhibit complex internal spin-dynamics when electric and magnetic fields are both applied. Near magnetic trap minima, these spin-dynamics lead to enhancements in Majorana spin-flip transitions by many orders of…

Atomic Physics · Physics 2018-01-03 David L. Reens , Hao Wu , Tim Langen , Jun Ye

Molecular dynamics calculations of inelastic collisions of atomic oxygen with molecular nitrogen are known to show orders of magnitude discrepancies with experimental results in the range from room temperature to many thousands of degrees…

Modeling environments that are not in local thermal equilibrium, such as protoplanetary disks or planetary atmospheres, with molecular spectroscopic data from space telescopes requires knowledge of the rate coefficients of rovibrationally…

Atomic Physics · Physics 2023-10-10 Taha Selim , Ad van der Avoird , Gerrit C. Groenenboom

We explore the potential energy surfaces for NH molecules interacting with alkali-metal and alkaline-earth atoms using highly correlated ab-initio electronic structure calculations. The surfaces for interaction with alkali-metal atoms have…

Chemical Physics · Physics 2015-05-13 Pavel Soldán , Piotr S. Żuchowski , Jeremy M. Hutson

Collisions with background atoms are known to induce a significant shift in the frequency of state-of-the-art optical atomic clocks and contribute to state decoherence in cold atom experiments. The effects of these collisions can be…

Near-threshold photodissociation of Br$_2$ from a supersonic beam produces slow bromine atoms that are trapped in the magnetic field minimum formed between two opposing permanent magnets. Here, we quantify the dominant trap loss rate due to…

Atomic Physics · Physics 2014-12-19 J. Lam , C. J. Rennick , T. P. Softley