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Chemical oxidation of multilayer graphene grown on silicon carbide yields films exhibiting reproducible characteristics, lateral uniformity, smoothness over large areas, and manageable chemical complexity, thereby opening opportunities to…

Materials Science · Physics 2014-03-20 S. Zhou , S. Kim , E. Di Gennaro , Y. Hu , C. Gong , X. Lu , C. Berger , W. de Heer , E. Riedo , Y. J. Chabal , C. Aruta , A. Bongiorno

We develop a strategy for graphene growth on Ru(0001) followed by silicon-layer intercalation that not only weakens the interaction of graphene with the metal substrate but also retains its superlative properties. This G/Si/Ru architecture,…

Understanding the nature of the interaction at the graphene/metal interfaces is the basis for graphene-based electron- and spin-transport devices. Here we investigate the hybridization between graphene- and metal-derived electronic states…

Materials Science · Physics 2014-07-17 H. Vita , S. Boettcher , K. Horn , E. N. Voloshina , R. E. Ovcharenko , Th. Kampen , A. Thissen , Yu. S. Dedkov

We report on the structural and electronic properties of a single bismuth layer intercalated underneath a graphene layer grown on an Ir(111) single crystal. Scanning tunneling microscopy (STM) reveals a hexagonal surface structure and a…

We report an approach to synthesize high quality graphene by surface segregation and substrate transfer. Graphene was segregated from Ni surface under the ambient pressure by dissolving carbon in Ni at high temperatures followed by cooling…

Materials Science · Physics 2008-12-09 Qingkai Yu , Jie Lian , Sujitra Siriponglert , Hao Li , Yong Chen , Shin-Shem Pei

Realization of a free-standing graphene is always a demanding task. Here we use scanning probe microscopy and spectroscopy to study the crystallographic structure and electronic properties of the uniform free-standing graphene layers…

Materials Science · Physics 2016-02-09 Elena Voloshina , Nikolai Berdunov , Yuriy Dedkov

Graphene grown epitaxially on SiC has been proposed as a material for carbon-based electronics. Understanding the interface between graphene and the SiC substrate will be important for future applications. We report the ability to image the…

Epitaxial graphene grown on metallic substrates presents, in several cases, a long-range periodic structure due to a lattice mismatch between the graphene and the substrate. For instance, graphene grown on Ir(111), displays a corrugated…

Angle resolved photoelectron spectroscopy (ARPES) is extensively used to characterize the dependence of the electronic structure of graphene on Ir(111) on the preparation process. ARPES findings reveal that temperature programmed growth…

Materials Science · Physics 2011-08-10 M. Kralj , I. Pletikosic , M. Petrovic , P. Pervan , M. Milun , A. T. N'Diaye , C. Busse , T. Michely , J. Fujii , I. Vobornik

Epitaxial growth of graphene on transition metal substrates is an important route for obtaining large scale graphene. However, the interaction between graphene and the substrate often leads to multiple orientations, distorted graphene band…

Graphene and few-layer graphene at high bias expose a wealth of phenomena due to the high temperatures reached. With in-situ transmission electron microscopy (TEM) we observe directly how the current modifies the structure, and vice versa.…

Mesoscale and Nanoscale Physics · Physics 2013-01-30 Amelia Barreiro , Felix Boerrnert , Mark H. Ruemmeli , Bernd Buechner , Lieven M. K. Vandersypen

We report a method that uses van der Waals interactions to transfer continuous, high-quality graphene films from Ge(110) to a different substrate held by hexagonal boron nitride carriers in a clean, dry environment. The transferred films…

We report the near-edge x-ray absorption fine structure (NEXAFS) spectrum of a single layer of graphite (graphene) obtained by micromechanical cleavage of Highly Ordered Pyrolytic Graphite (HOPG) on a SiO2 substrate. We utilized a…

We present a systematical study via scanning tunneling microscopy (STM) and low-energy electron diffraction (LEED) on the effect of the exposure of Lithium (Li) on graphene on silicon carbide (SiC). We have investigated Li deposition both…

Materials Science · Physics 2017-09-29 Sara Fiori , Yuya Murata , Stefano Veronesi , Antonio Rossi , Camilla Coletti , Stefan Heun

Graphene has been recognized as an attractive two-dimensional material for fundamental research and wide applications in electronic and photonic devices owing to its unique properties. The technologies to modulate the properties of graphene…

Optics · Physics 2016-01-26 Yang Tan , Zhen Shang , Shavkat Akhmadaliev , Shengqiang Zhou , Feng Chen

We use anhydrous ferric chloride (FeCl3) to intercalate graphite flakes consisting of 2 to 4 graphene layers and to dope graphene monolayers. The intercalant, staging, stability and doping of the resulting intercalation compounds (ICs) are…

Materials Science · Physics 2011-06-07 W. J. Zhao , P. H. Tan , J. Liu , A. C. Ferrari

The reflectivity of low energy electrons from graphene on copper substrates is studied both experimentally and theoretically. Well-known oscillations in the reflectivity of electrons with energies 0 - 8 eV above the vacuum level are…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 N. Srivastava , Qin Gao , M. Widom , R. M. Feenstra , Shu Nie , K. F. McCarty , I. V. Vlassiouk

Ferroelectricity (Valasek, J. Phys. Rev. 1921, 17, 475) - a spontaneous formation of electric polarisation - is a solid state phenomenon, usually, associated with ionic compounds or complex materials. Here we show that, atypically for…

Materials Science · Physics 2023-05-29 Aitor Garcia-Ruiz , Vladimir Enaldiev , Andrew McEllistrim , Vladimir I. Fal'ko

An efficient route to synthesize macroscopic amounts of graphene is highly desired and a bulk characterization of such samples, in terms of the number of layers, is equally important. We present a Raman spectroscopy-based method to…

We describe the reversible intercalation of Na under graphene on Ir(111) by photo-dissociation of a previously adsorbed NaCl overlayer. After room temperature evaporation, NaCl adsorbs on top of graphene forming a bilayer. With a…

Materials Science · Physics 2019-04-26 I. Palacio , L. Aballe , M. Foerster , D. G. de Oteyza , M. García-Hernández , J. A. Martín-Gago
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