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In a recent Letter we introduced Hellmann-Feynman operator sampling in diffusion Monte Carlo calculations. Here we derive, by evaluating the second derivative of the total energy, an efficient method for the calculation of the static…

Other Condensed Matter · Physics 2015-05-13 R. Gaudoin , J. M. Pitarke

This letter is about effective approximation for a stochastic parabolic equation with a large potential in a periodic medium. Under a condition on the spectral properties of the associated cell problem, we prove that the solution can be…

Analysis of PDEs · Mathematics 2020-11-20 Ao Zhang , Jinqiao Duan

An iterative Monte Carlo inversion method for the calculation of particle pair potentials from given particle pair correlations is proposed in this paper. The new method, which is best referred to as Iterative Ornstein-Zernike Inversion,…

Soft Condensed Matter · Physics 2018-04-13 Marco Heinen

We present a wavefunction-based approach to correlated ab initio calculations on crystalline insulators of infinite extent. It uses the representation of the occupied and the unoccupied (virtual) single-particle states of the infinite solid…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Peter Fulde , Hermann Stoll

It was recently shown that the exact factorization of the electron-nuclear wavefunction allows the construction of a Schr\"odinger equation for the electronic system, in which the potential contains exactly the effect of coupling to the…

Atomic and Molecular Clusters · Physics 2016-01-20 Elham Khosravi , Ali Abedi , Neepa T. Maitra

The optical manifold method to compute the one-loop effective action in a static space-time is extended from the massless scalar field to the Maxwell field in any Feynman-like covariant gauge. The method is applied to the case of the…

High Energy Physics - Theory · Physics 2014-11-18 Valter Moretti , Devis Iellici

We calculate the scalar potential in the gauged N=2 supergravity with a single hypermultiplet, whose generic quaternionic moduli space metric has an abelian isometry. This isometry is gauged by the use of a graviphoton gauge field. The…

High Energy Physics - Theory · Physics 2010-04-05 Sergei V. Ketov

The fast Ewald methods are widely used to compute the point-charge electrostatic interactions in molecular simulations. The key step that introduces errors in the computation is the particle-mesh interpolation. In this work, the optimal…

Chemical Physics · Physics 2017-10-25 Han Wang , Jun Fang , Xingyu Gao

The 1/r Coulomb potential is calculated for a two dimensional system with periodic boundary conditions. Using polynomial splines in real space and a summation in reciprocal space we obtain numerically optimized potentials which allow us…

Other Condensed Matter · Physics 2016-03-15 Markus Holzmann , Bernard Bernu

We consider the geometry relaxation of an isolated point defect embedded in a homogeneous crystalline solid, within an atomistic description. We prove a sharp convergence rate for a periodic supercell approximation with respect to uniform…

Numerical Analysis · Mathematics 2018-11-22 Julian Braun , Christoph Ortner

Ions are critical to the structure and stability of polyelectrolytes such as nucleic acids. In this work, we systematically calculated the potentials of mean force between two like-charged nanoparticles in salt solutions by Monte Carlo…

Biological Physics · Physics 2015-06-15 Yuan-Yan Wu , Feng-Hua Wang , Zhi-Jie Tan

The use of electrostatic ion beam traps require to set many potentials on the electrodes (ten in our case), making the tuning much more difficult than with quadrupole traps. In order to obtain the best trapping conditions, an analytical…

Atomic Physics · Physics 2010-12-03 Alexandre Vallette , Paul Indelicato

In this work, we provide the mathematical elements we think essential for a proper understanding of the calculus of the electrostatic energy of point-multipoles of arbitrary order under periodic boundary conditions. The emphasis is put on…

Chemical Physics · Physics 2021-03-30 Benjamin Stamm , Louis Lagardère , Étienne Polack , Yvon Maday , Jean-Philip Piquemal

To minimise systematic errors in Monte Carlo simulations of charged particles, long range electrostatic interactions have to be calculated accurately and efficiently. Standard approaches, such as Ewald summation or the naive application of…

Computational Physics · Physics 2021-02-24 William Robert Saunders , James Grant , Eike Hermann Müller

In this paper, we propose, analyze and demonstrate a dynamic momentum method to accelerate power and inverse power iterations with minimal computational overhead. The method can be applied to real diagonalizable matrices, is provably…

Numerical Analysis · Mathematics 2024-07-08 Christian Austin , Sara Pollock , Yunrong Zhu

A new method for Ewald summation in planar/slablike geometry, i.e. systems where periodicity applies in two dimensions and the last dimension is "free" (2P), is presented. We employ a spectral representation in terms of both Fourier series…

Computational Physics · Physics 2015-05-30 Dag Lindbo , Anna-Karin Tornberg

In this article, we propose an efficient method for sampling the relevant state space in condensed phase reactions. In the present method, the reaction is described by solving the electronic Schr\"{o}dinger equation for the solute atoms in…

Chemical Physics · Physics 2009-11-10 Radu Iftimie , Dennis Salahub , Jeremy Schofield

In this work, an efficient approximation scheme has been proposed for getting accurate approximate solution of nonlinear partial differential equations with constant or variable coefficients satisfying initial conditions in a series of…

Analysis of PDEs · Mathematics 2020-09-04 Prakash Kumar Das , M. M. Panja

We consider approximating analytic functions on the interval $[-1,1]$ from their values at a set of $m+1$ equispaced nodes. A result of Platte, Trefethen \& Kuijlaars states that fast and stable approximation from equispaced samples is…

Numerical Analysis · Mathematics 2022-03-08 Ben Adcock , Alexei Shadrin

We consider an ionic fluid made with two species of mobile particles carrying either a positive or a negative charge. We derive a sum rule for the fourth moment of equilibrium charge correlations. Our method relies on the study of the…

Statistical Mechanics · Physics 2016-11-30 Angel Alastuey , Riccardo Fantoni