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The propensity for ion-pairing can often dictate the thermodynamic and kinetic properties of electrolyte solutions. Fast and accurate estimates of ion-pairing can thus be extremely valuable for supplementing design and screening efforts for…

Soft Condensed Matter · Physics 2022-02-23 Ajay Muralidharan , Arun Yethiraj

When evaluating the electrostatic potential, periodic boundary conditions in one, two or three of the spatial dimensions are often needed for different applications. The triply periodic Ewald summation formula is classical, and Ewald…

Mathematical Physics · Physics 2014-04-15 Anna-Karin Tornberg

We present new efficient (O(N log N)) methods for computing three quantities crucial to electronic structure calculations: the ionic potential, the electron-ion contribution to the Born-Oppenheimer forces, and the electron-ion contribution…

Materials Science · Physics 2009-11-07 Nicholas Choly , Efthimios Kaxiras

In this work we provide a step by step derivation of an angular--averaged Ewald potential suitable for numerical simulations of disordered Coulomb systems. The potential was first introduced by E.\,Yakub and C.\,Ronchi without a clear…

Plasma Physics · Physics 2022-09-07 G. S. Demyanov , P. R. Levashov

We present a novel numerical method for solving the elliptic partial differential equation problem for the electrostatic potential with piecewise constant conductivity. We employ an integral equation approach for which we derive a system of…

Numerical Analysis · Mathematics 2022-06-01 Kyle Bower , Kirill Serkh , Spyros Alexakis , Adam R Stinchcombe

We introduce a direct Boltzmann inversion method to infer the interaction potential in particle systems using as input particle configurations generated at an arbitrary state point of the system. Unlike iterative Boltzmann inversion, the…

Statistical Mechanics · Physics 2026-05-25 Olivier Coquand , Davide Paolino , Ludovic Berthier

The in-plane polarizational stopping power of heavy-ion diclusters in a two-dimensional strongly coupled electron liquid is studied. Analytical expressions for the stopping power of both fast and slow projectiles are derived. To go beyond…

Strongly Correlated Electrons · Physics 2007-10-17 D. Ballester , A. M. Fuentes , I. M. Tkachenko

We address periodic-image errors arising from the use of periodic boundary conditions to describe systems that do not exhibit full three-dimensional periodicity. The difference between the periodic potential, as straightforwardly obtained…

Other Condensed Matter · Physics 2009-11-13 Ismaila Dabo , Boris Kozinsky , Nicholas E. Singh-Miller , Nicola Marzari

We calculate interdiffusion coefficients in a two-component, weakly or strongly coupled ion plasma (gas or liquid, composed of two ion species immersed into a neutralizing electron background). We use an effective potential method proposed…

Solar and Stellar Astrophysics · Physics 2015-06-22 M. V. Beznogov , D. G. Yakovlev

I propose a method to calculate logarithmic interaction in two dimensions and coulomb interaction in three dimensions under periodic boundary conditions. This paper considers the case of a rectangular cell in two dimensions and an…

Statistical Mechanics · Physics 2009-11-10 Sandeep Tyagi

We study the computation of equilibrium points of electrostatic potentials: locations in space where the electrostatic force arising from a collection of charged particles vanishes. This is a novel scenario of optimization in which…

Computational Complexity · Computer Science 2025-12-04 Abheek Ghosh , Paul W. Goldberg , Alexandros Hollender

In this work we demonstrate the robustness of a real-space approach for the treatment of infinite systems described with periodic boundary conditions that we have recently proposed [J. Phys. Chem. Lett. 17, 7090]. In our approach we extract…

Various properties of the general two-center two-electron integral over the explicitly correlated exponential function are analyzed for the potential use in high precision calculations for diatomic molecules. A compact one dimensional…

Chemical Physics · Physics 2015-06-11 Krzysztof Pachucki

The iterative Boltzmann inversion is an iterative scheme to determine an effective pair potential for an ensemble of identical particles in thermal equilibrium from the corresponding radial distribution function. Although the method is…

Mathematical Physics · Physics 2018-01-17 Martin Hanke

Describing long-ranged electrostatics using short-ranged pair potentials is appealing since the computational complexity scales linearly with the number of particles. The foundation of this approach is to mimic the long-ranged medium…

Statistical Mechanics · Physics 2020-05-13 Björn Stenqvist , Vidar Aspelin , Mikael Lund

We study property prediction for crystal materials. A crystal structure consists of a minimal unit cell that is repeated infinitely in 3D space. How to accurately represent such repetitive structures in machine learning models remains…

Chemical Physics · Physics 2023-11-08 Yuchao Lin , Keqiang Yan , Youzhi Luo , Yi Liu , Xiaoning Qian , Shuiwang Ji

Methods for calculating an electron density of a periodic crystal constructed using non-orthogonal localised orbitals are discussed. We demonstrate that an existing method based on the matrix expansion of the inverse of the overlap matrix…

Computational Physics · Physics 2009-11-10 Lev Kantorovich , Oleh Danyliv

We simulate the dynamics, including laser cooling, of 3D ion crystals confined in a Penning trap using a newly developed molecular dynamics-like code. The numerical integration of the ions' equations of motion is accelerated using the fast…

Quantum Physics · Physics 2026-02-27 John Zaris , Wes Johnson , Athreya Shankar , John J. Bollinger , Scott E. Parker

Here we develop a formalism for reversible ionic aggregation kinetics in an example concentrated electrolyte, building on previous equilibrium work of McEldrew and co-workers, and thermoreversible polymers and patchy particle systems. This…

Soft Condensed Matter · Physics 2026-05-04 Zachary A. H. Goodwin

We derive the exact longitudinal plasmon dispersion relations, $\omega(k)$ of classical one and two dimensional Wigner crystals at T=0 from the real space equations of motion, of which properly accounts for the full unscreened Coulomb…

Strongly Correlated Electrons · Physics 2011-11-09 Shimul Akhanjee