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We demonstrate that Daubechies wavelets can be used to construct a minimal set of optimized localized contracted basis functions in which the Kohn-Sham orbitals can be represented with an arbitrarily high, controllable precision. Ground…

An efficient numerical quadrature is proposed for the approximate calculation of the potential energy in the context of pseudo potential electronic structure calculations with Daubechies wavelet and scaling function basis sets. Our…

Computational Physics · Physics 2009-11-11 A. I. Neelov , S. Goedecker

In a recent paper we presented a linear scaling Kohn-Sham density functional theory (DFT) code based on Daubechies wavelets, where a minimal set of localized support functions is optimized in situ and therefore adapted to the chemical…

Materials Science · Physics 2015-10-08 Laura E. Ratcliff , Luigi Genovese , Stephan Mohr , Thierry Deutsch

We use Lorentz polynomials to present the solutions explicitly of equations (6.1.7) of [I. Daubechies, Ten lectures on wavelets, CBMS-NSF Regional Conference Series in Applied Mathematics, 61. Society for Industrial and Applied Mathematics…

Functional Analysis · Mathematics 2015-07-14 Tian-Xiao He , Tung Nguyen

We introduce highly local basis sets for electronic structure which are very efficient for correlation calculations near the complete basis set limit. Our approach is based on gausslets, recently introduced wavelet-like smooth orthogonal…

Chemical Physics · Physics 2019-02-20 Steven R. White , E. Miles Stoudenmire

Collective variable-based enhanced sampling methods are routinely used on systems with metastable states, where high free energy barriers impede proper sampling of the free energy landscapes when using conventional molecular dynamics…

Chemical Physics · Physics 2022-08-09 Benjamin Pampel , Omar Valsson

First principles calculations based on density functional theory are having an incerasing impact on our understanding of molecule-surface interactions. For example, calculations of the multi-dimensional potential energy surface have…

Materials Science · Physics 2007-05-23 O. Gulseren , D. M. Bird , S. E. Humphreys

We present a detailed comparison between ONETEP, our linear-scaling density functional method, and the conventional pseudopotential plane wave approach in order to demonstrate its high accuracy. Further comparison with all-electron…

Materials Science · Physics 2009-11-11 Chris-Kriton Skylaris , Peter D. Haynes , Arash A. Mostofi , Mike C. Payne

Density Functional Theory calculations traditionally suffer from an inherent cubic scaling with respect to the size of the system, making big calculations extremely expensive. This cubic scaling can be avoided by the use of so-called linear…

This paper offers a new regard on compactly supported wavelets derived from FIR filters. Although being continuous wavelets, analytical formulation are lacking for such wavelets. Close approximations for daublets (Daubechies wavelets) and…

Numerical Analysis · Computer Science 2019-09-27 V. V. Vermehren , J. E. Wesen , H. M. de Oliveira

We investigate non-stationary orthogonal wavelets based on a non-stationary interpolatory subdivision scheme reproducing a given set of exponentials. The construction is analogous to the construction of Daubechies wavelets using the…

Numerical Analysis · Mathematics 2012-10-31 N. Dyn , O. Kounchev , D. Levin , H. Render

First-principles density functional theory (DFT) codes which employ a localized basis offer advantages over those which use plane-wave bases, such as better scaling with system size and better suitability to low-dimensional systems. The…

Materials Science · Physics 2024-11-25 Daniel Bennett , Michele Pizzochero , Javier Junquera , Efthimios Kaxiras

There are many ways to numerically represent of chemical systems in order to compute their electronic structure. Basis functions may be localized in real-space (atomic orbitals), in momentum-space (plane waves), or in both components of…

Chemical Physics · Physics 2019-09-09 James Brown , James D. Whitfield

Hybrid density functional calculation is indispensable to accurate description of electronic structure, whereas the formidable computational cost restricts its broad application. Here we develop a deep equivariant neural network method…

Materials Science · Physics 2023-02-17 Zechen Tang , He Li , Peize Lin , Xiaoxun Gong , Gan Jin , Lixin He , Hong Jiang , Xinguo Ren , Wenhui Duan , Yong Xu

Density functional theory (DFT) is an essential building block for modern theoretical physics, chemistry, and engineering, especially those concerning electronic properties. Through decades of development, various program packages for…

Materials Science · Physics 2022-11-21 Yusuke Nomura , Ryosuke Akashi

It is described how the coefficients of Daubechies wavelet matrices can be approximated by rational numbers in such a way that the perfect reconstruction property of the filter bank be preserved exactly

Numerical Analysis · Mathematics 2011-06-28 Lasha Ephremidze , Aleksander Gamkrelidze , Edem Lagvilava

We present an approach to solid-state electronic-structure calculations based on the finite-element method. In this method, the basis functions are strictly local, piecewise polynomials. Because the basis is composed of polynomials, the…

Condensed Matter · Physics 2009-10-31 J. E. Pask , B. M. Klein , C. Y. Fong , P. A. Sterne

We use Daubechies' orthonormal compact wavelets as a variational basis for the $XY$ model in two and three dimensions. Assuming that the fluctuations of the wavelet coefficients are Gaussian and uncorrelated, minimization of the free energy…

High Energy Physics - Lattice · Physics 2009-10-22 C. Best , A. Schaefer

Using the Daubechies conditions of compact support, orthogonal, and regularity, we were able to derive bivariate scaling functions with which to reproduce linear functions (planes). We describe how to create all possible masks of refinement…

Functional Analysis · Mathematics 2007-05-23 Edward Aboufadel , Amanda Cox , Amy Vander Zee

Accurate density estimation methodologies play an integral role in a variety of scientific disciplines, with applications including simulation models, decision support tools, and exploratory data analysis. In the past, histograms and kernel…

Statistics Theory · Mathematics 2012-06-14 Judson B. Locke , Adrian M. Peter
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