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Related papers: Daubechies wavelets as a basis set for density fun…

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We introduce a basis set consisting of three-dimensional Deslauriers--Dubuc wavelets and solve numerically the Schr\"odinger equations of H and He atoms and molecules $\mathrm{H}_2$, $\mathrm{H}_2^+$, and $\mathrm{LiH}$ with HF and DFT…

Quantum Physics · Physics 2023-08-08 Tommi Höynälänmaa , Tapio T. Rantala

Ab initio electronic structure calculations of two-dimensional layered structures are typically performed using codes that were developed for three-dimensional structures, which are periodic in all three directions. The introduction of a…

Strongly Correlated Electrons · Physics 2016-06-22 Paolo E. Trevisanutto , Giovanni Vignale

We consider the application of the polyharmonic subdivision wavelets (of Daubechies type) to Image Processing, in particular to Astronomical Images. The results show an essential advantage over some standard multivariate wavelets and a…

Numerical Analysis · Mathematics 2010-07-01 Ognyan Kounchev , Damyan Kalaglarsky , Milcho Tsvetkov

We consider the applicability of phase space Wannier functions" to electronic structure calculations. These generalized Wannier functions are analogous to localized plane waves and constitute a complete, orthonormal set which is…

Other Condensed Matter · Physics 2010-07-22 D. J. Sullivan , J. J. Rehr , J. W. Wilkins , K. G. Wilson

We give a fairly comprehensive review of wavelets and of their application to density-functional theory (DFT) and to our recent application of a wavelet-based version of linear-response time-dependent DFT (LR-TD-DFT). Our intended audience…

Other Condensed Matter · Physics 2011-10-24 Bhaarathi Natarajan , Mark E. Casida , Luigi Genovese , Thierry Deutsch

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

The representation of discrete, compact wavelet transformations (WTs) as circuits of local unitary gates is discussed. We employ a similar formalism as used in the multi-scale representation of quantum many-body wavefunctions using unitary…

Quantum Physics · Physics 2018-05-14 Glen Evenbly , Steven R. White

We have formulated and implemented a fully charge-self-consistent density functional theory plus dynamical mean field theory methodology which enables an efficient calculation of the total energy of realistic correlated electron systems.…

Strongly Correlated Electrons · Physics 2015-06-22 Hyowon Park , Andrew J. Millis , Chris A. Marianetti

A recent paper compares density functional theory results for atomization energies and dipole moments using a multi-wavelet based method with traditional Gaussian basis set results, and concludes that Gaussian basis sets are problematic for…

Computational Physics · Physics 2017-11-01 Frank Jensen

We present a detailed study of the use of localized spherical-wave basis sets, first introduced in the context of linear-scaling, in first-principles density-functional calculations. Several parameters that control the completeness of this…

Chemical Physics · Physics 2018-07-25 Chee Kwan Gan , Peter David Haynes , M. C. Payne

This article reviews recent developments in multiresolution analysis which make it a powerful tool for the systematic treatment of the multiple length-scales inherent in the electronic structure of matter. Although the article focuses on…

Materials Science · Physics 2009-10-31 T. A. Arias

We present an approach to accelerate real-space electronic structure methods several fold, without loss of accuracy, by reducing the dimension of the discrete eigenproblem that must be solved. To accomplish this, we construct an efficient,…

Computational Physics · Physics 2018-05-01 Qimen Xu , Phanish Suryanarayana , John E. Pask

Density-potential functional theory (DPFT) is an alternative formulation of orbital-free density functional theory that may be suitable for modeling the electronic structure of large systems. To date, DPFT has been applied mainly to quantum…

Materials Science · Physics 2023-04-21 Martin-Isbjörn Trappe , William C. Witt , Sergei Manzhos

A simple yet general method for constructing basis sets for molecular electronic structure calculations is presented. These basis sets consist of atomic natural orbitals from a multi-configurational self-consistent field calculation…

Materials Science · Physics 2015-05-19 F. R. Petruzielo , Julien Toulouse , C. J. Umrigar

We propose a unique scheme to construct fully optimized atomic basis sets for density-functional calculations. The shapes of the radial functions are optimized by minimizing the {\it spillage} of the wave functions between the atomic…

Materials Science · Physics 2015-05-19 Mohan Chen , G-C Guo , Lixin He

Ab initio study of magnetic superstructures (e.g., magnetic skyrmion) is indispensable to the research of novel materials but bottlenecked by its formidable computational cost. For solving the bottleneck problem, we develop a deep…

Computational Physics · Physics 2023-06-12 He Li , Zechen Tang , Xiaoxun Gong , Nianlong Zou , Wenhui Duan , Yong Xu

We present a computational approach which is tailored for reducing the complexity of the description of extended systems at the density functional theory level. We define a recipe for generating a set of localized basis functions which are…

Materials Science · Physics 2019-04-16 Laura E. Ratcliff , Luigi Genovese

We introduce a new basis function (the spherical gaussian) for electronic structure calculations on spheres of any dimension $D$. We find \alert{general} expressions for the one- and two-electron integrals and propose an efficient…

Chemical Physics · Physics 2015-06-09 Peter M. W. Gill , Pierre-François Loos , Davids Agboola

Compressed sensing has empowered quality image reconstruction with fewer data samples than previously though possible. These techniques rely on a sparsifying linear transformation. The Daubechies wavelet transform is a common sparsifying…

Image and Video Processing · Electrical Eng. & Systems 2021-06-17 Nicholas Dwork , Daniel O'Connor , Corey A. Baron , Ethan M. I. Johnson , Adam B. Kerr , John M. Pauly , Peder E. Z. Larson

A general procedure for the optimization of atomic density-fitting basis functions is designed with the balance between accuracy and numerical stability in mind. Given one-electron wavefunctions and energies, weights are assigned to the…

Chemical Physics · Physics 2020-10-13 Dimitri N. Laikov