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Calculations of the conductance of a carbon nanotube (CNT)-molecule-CNT structure are in agreement with experimental measurements [1]. The features in the transmission correspond directly to the features of the isolated molecular orbitals.…

Other Condensed Matter · Physics 2015-05-13 Nicolas A. Bruque , M. K. Ashraf , Roger K. Lake

Lewis acids like tris(pentafluorophenyl)borane (BCF) offer promising routes for efficient $p$-doping of organic semiconductors. The intriguing experimental results achieved so far call for a deeper understanding of the underlying doping…

Materials Science · Physics 2020-07-07 Richard Schier , Ana M. Valencia , Caterina Cocchi

Doped semiconductors are a central and crucial component of all integrated circuits. By using a combination of white light and a focused laser beam, and exploiting hBN defect states, heterostructures of hBN/Graphene/hBN are photodoped…

Mesoscale and Nanoscale Physics · Physics 2025-02-12 Son T. Le , Thuc T. Mai , Maria F. Munoz , Angela R. Hight Walker , Curt A. Richter , Aubrey T. Hanbicki , Adam L. Friedman

We report density-functional theory (DFT), atomistic simulations of the non-equilibrium transport properties of carbon nanotube (CNT) field-effect transistors (FETs). Results have been obtained within a self-consistent approach based on the…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. Latessa , A. Pecchia , A. Di Carlo

We investigate from first-principles many-body theory the role of the donor conjugation length in doped organic semiconductors forming charge-transfer complexes (CTCs) exhibiting partial charge transfer. We consider oligothiophenes (nT)…

Materials Science · Physics 2022-08-16 Ana M. Valencia , Caterina Cocchi

We present {\it ab initio} and self-consistent tight-binding calculations on the band structure of single wall semiconducting carbon nanotubes with high degrees (up to 25 %) of boron substitution. Besides a lowering of the Fermi energy into…

Materials Science · Physics 2009-11-10 Ludger Wirtz , Angel Rubio

Despite the highly porous nature with significantly large surface area, metal organic frameworks (MOFs) can be hardly used in electronic, and optoelectronic devices due to their extremely poor electrical conductivity. Therefore, the study…

The apex region of a capped (5,5) carbon nanotube (CNT) has been modelled with the DFT package ONETEP, using boundary conditions provided by a classical calculation with a conducting surface in place of the CNT. Results from the DFT…

Applied Physics · Physics 2019-01-17 C. J. Edgcombe , S. M. Masur , E. B. Linscott , J. A. J. Whaley-Baldwin , C. H. W. Barnes

Boron carbonitride (BxCyNz) represents an interesting family of materials containing all light elements and two dimensional graphene like hybrid layers. Although rich literature exists on this peculiar material in chemically processed form,…

Structural and electronic properties of pristine and transition metal doped ZnS monolayer are investigated within the framework of density functional theory. The pristine ZnS monolayer is showing direct band gap of about 2.8 eV. The…

Materials Science · Physics 2017-11-16 Rajneesh Chaurasiya , Ambesh Dixit

Boron nitride nanotubes (BNNTs) are of intense scientific interests due to their unique physiochemical properties and prospective applications in various nanotechnologies. A critical problem hampering the application processing of BNNTs is…

Materials Science · Physics 2014-01-24 Zhenghong Gao , Chunyi Zhi , Dimtri Golberg , Yoshio Bando , Takeshi Serizawa

GaSb:N displays promise towards realization of optoelectronic devices accessing the mid-infrared wavelength regime. Theoretical and experimental results on its electronic and optical properties are however few. To address this, we present a…

Materials Science · Physics 2014-03-06 Priyamvada Jadaun , Hari P. Nair , Vincenzo Lordi , Seth R. Bank , Sanjay K. Banerjee

The entanglement of two atoms (ions) doped into a carbon nanotube has been investigated theoretically. Based on the photon Green function formalism for quantizing electromagnetic field in the presence of carbon nanotubes, small-diameter…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 I. V. Bondarev , B. Vlahovic

Nonequilibrium Greens function techniques (NEGF) combined with density functional theory (DFT) calculations have become a standard tool for the description of electron transport through single molecule nanojunctions in the coherent…

Mesoscale and Nanoscale Physics · Physics 2015-11-05 Victor Geskin , Robert Stadler , Jérôme Cornil

The phosphorus-doped single wall carbon nanotube (PSWCNT) is studied by using First-Principle methods based on Density Function Theory (DFT). The formation energy, total energy, band structure, geometry structure and density of states are…

Mesoscale and Nanoscale Physics · Physics 2011-08-10 AQing Chen , QingYi Shao , ZhiCheng Lin

The $V_N N_B$ defect in hexagonal boron nitride (h-BN), comprising a nitrogen vacancy adjacent to a nitrogen-for-boron substitution, is modelled in regard to its possible usefulness in a nanophotonics device. The modelling is done on both a…

Materials Science · Physics 2020-10-21 A. Sajid , Jeffrey R. Reimers , Rika Kobayashi , Michael J. Ford

Recent nuclear magnetic resonance measurements on isotope engineered double walled carbon nanotubes (DWCNTs) surprisingly suggest a uniformly metallic character of all nanotubes, which can only be explained by the interaction between the…

Materials Science · Physics 2007-05-23 V. Zólyomi , J. Koltai , Á. Rusznyák , J. Kürti , Á. Gali , F. Simon , H. Kuzmany , Á. Szabados , P. R. Surján

We present the first-principles study of effects of the charge dopants such as Cesium and Iodine encapsulated on the electronic structure of carbon nanotubes. An encapsulated cesium atom donates an electron to the nanotube and produces…

Materials Science · Physics 2009-11-13 Woon Ih Choi , Jisoon Ihm , Gunn Kim

We show that the optical absorption spectra of boron nitride (BN) nanotubes are dominated by strongly bound excitons. Our first-principles calculations indicate that the binding energy for the first and dominant excitonic peak depends…

Materials Science · Physics 2013-08-07 Ludger Wirtz , Andrea Marini , Angel Rubio

In this letter we present an experimental realization of the quantum mechanics textbook example of two interacting electronic quantum states that hybridize forming a molecular state. In our particular realization, the quantum states…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. R. Graeber , M. Weiss , D. Keller , S. Oberholzer , C. Schoenenberger
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