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We report first-principle atomistic simulations on the effect of local strain gradients on the nanoscale domain morphology of free-standing PbTiO$_3$ ultrathin films. First, the ferroelectric properties of free films at the atomic level are…

Materials Science · Physics 2015-06-22 G. D. Belletti , S. D. Dalosto , Silvia Tinte

We report observation of 90-degree ferroelectric domain structures in transmission electron microscopy (TEM) of epitaxially-grown films of PbTiO3. Using molecular dynamics (MD) simulations based on first-principles effective Hamiltonian of…

Dynamic phase transition phenomena in ultrathin films described by Blume-Capel model have been investigated using Monte Carlo simulations. Hysteresis loops, micromagnetic structures, and hysteresis loop area curves, as well as dynamic…

Statistical Mechanics · Physics 2015-06-16 Yusuf Yuksel

Magneto-electric effect in a multiferroic heterostructure film, i.e. a coupled ferromagnetic-ferroelectric thin film, has been investigated through the use of the Metropolis algorithm in Monte Carlo simulations. A classical Heisenberg model…

Mesoscale and Nanoscale Physics · Physics 2016-06-03 Zidong Wang , Malcolm Grimson

Surface and ferroelectric properties of PbTiO$_3$ thin films are investigated using an interatomic potential approach with parameters computed from first-principles calculations. We show that a model developed for the bulk describes…

Materials Science · Physics 2009-11-11 M. Sepliarsky , M. G. Stachiotti , R. L. Migoni

In thin film ferroelectric capacitor the chemical and electronic structure of the electrode/FE interface can play a crucial role in determining the kinetics of polarization switching. We investigate the electronic structure of a…

Using an effective Hamiltonian parametrized from first principles, Monte Carlo simulations are performed in order to study the piezoelectric response of BaTiO3 in the ferroelectric tetragonal phase as a function of temperature. The effect…

Materials Science · Physics 2009-10-30 Alberto Garcia , David Vanderbilt

Progress in the emerging fields of atomic and close-to-atomic scale manufacturing is underpinned by enhanced precision and optimization of laser-controlled nanostructuring. Understanding thin films' crystallographic orientations and…

Materials Science · Physics 2024-12-24 Hariprasath Ganesan , Stefan Sandfeld

This paper introduces a new approach for simulating magnetic properties of nanocomposites comprising magnetic particles embedded in a non-magnetic matrix, taking into account the 3D structure of the system in which particles' positions…

Mesoscale and Nanoscale Physics · Physics 2014-10-22 R. F. Neumann , M. Bahiana , L. G. Paterno , M. A. G. Soler , J. P. Sinnecker , J. G. Wen , P. C. Morais

Based on first-principles and model calculations we investigate the effect of polar interfaces on the ferroelectric stability of thin-film ferroelectrics. As a representative model, we consider a TiO2-terminated BaTiO3 film with LaO…

Materials Science · Physics 2010-10-05 Y. Wang , M. K. Niranjan , K. Janicka , J. P. Velev , M. Ye. Zhuravlev , S. S. Jaswal , E. Y. Tsymbal

Epitaxial thin films of relaxor PbMg1/3Nb2/3O3 and PbSc0.5Nb0.5O3, and ferroelectric PbZr0.65Ti0.35O3, Pb0.955La0.045Zr0.65Ti0.35O3, and Ba0.4Sr0.6TiO3 were prepared, and their dielectric properties were studied in a broad range of the…

Materials Science · Physics 2009-11-11 M. Tyunina , J. Levoska , I. Jaakola

Three-dimensional (3-D) topological insulators (TI) are characterized by the presence of metallic surface states and a bulk band gap. Recently theoretical and experimental studies have shown an induced gap in the surface state bands of TI…

Mesoscale and Nanoscale Physics · Physics 2012-12-21 Jiwon Chang , Leonard F. Register , Sanjay K. Banerjee

Highly-crystalline ferroelectric oxides integrated on Si hold great promise for energy-efficient memory and logic technologies. Exploiting epitaxial strain engineering in these materials is, however, severely hampered on Si, where the large…

Materials Science · Physics 2026-04-27 Jingtian Zhao , Beatriz Noheda , Martin F. Sarott

First-principles molecular dynamics simulation based on a plane wave/pseudopotential implementation of density functional theory is adopted to investigate atomic scale energy transport for semiconductors (silicon and germanium). By imposing…

Computational Physics · Physics 2016-02-02 Pengfei Ji , Yuwen Zhang

Molecular Dynamics is applied to Ferroelectric Perovskites in the framework of a first-principles derived effective Hamiltonian (Zhong, Vanderbilt, Rabe, Phys. Rev. Lett. {\bf 73} (1994), 1861). The degrees of freedom, that obey the Newton…

Materials Science · Physics 2009-01-26 Gregory Geneste

In this work we use a phenomenological theory of ferroelectric switching in BiFeO$_3$ thin films to uncover the mechanism of the two-step process that leads to the reversal of the weak magnetization of these materials. First, we introduce a…

Materials Science · Physics 2023-07-28 Natalya S. Fedorova , Dmitri E. Nikonov , John M. Mangeri , Hai Li , Ian A. Young , Jorge Íñiguez

Material defects remain as the main bottleneck to the progress of topological insulators (TIs). In particular, efforts to achieve thin TI samples with dominant surface transport have always led to increased defects and degraded mobilities,…

Scanning tunneling microscopy and spectroscopy have been used to investigate the femtosecond dynamics of Dirac fermions in the topological insulator Bi$_2$Se$_3$ ultrathin films. At two-dimensional limit, bulk electrons becomes quantized…

Mesoscale and Nanoscale Physics · Physics 2015-05-08 Can-Li Song , Lili Wang , Ke He , Shuai-Hua Ji , Xi Chen , Xu-Cun Ma , Qi-Kun Xue

Atomic-scale ferroelectrics are of great interest for high-density electronics, particularly field-effect transistors, low-power logic, and nonvolatile memories. We devised a film with a layered structure of bismuth oxide that can stabilize…

Electrocatalysis is greatly influenced by the local reaction environment, which is governed by the structure of the catalyst, the distribution of the electrolyte, and the local electric field. In catalytic systems comprised of complex…

Chemical Physics · Physics 2026-04-24 Dustin Vivod , Binny A. Davis , Tobias Binninger , Michael Eikerling