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A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…
It is argued the the idea of a single temperature-like variable, introduced in [1], which enters a generalized second law for Markovian open system in non-equilibrium environment is not sufficient for a consistent and useful thermodynamic…
We calculate the net change in generalized entropy occurring when one carries out the gedanken experiment in which a box initially containing energy $E$, entropy $S$ and charge $Q$ is lowered adiabatically toward a Reissner-Nordstr\"{o}m…
The zeroth principle of thermodynamics in the form "temperature is uniform at equilibrium" is notoriously violated in relativistic gravity. Temperature uniformity is often derived from the maximization of the total number of microstates of…
In our recent letter [1] we discussed that thermodynamics is violated in quantum Brownian motion beyond the weak coupling limit. In his comment, Tasaki [2] derives an inequality for the relative entropy and claims, without making any…
The thermodynamic second law in the evaporating black hole space-time is examined in the context of two-dimensional dilaton black hole. The dynamical evolution of entropy is investigated by using the analytical perturbation method and the…
Entropy is the distinguishing and most important concept of our efforts to understand and regularize our observations of a very large class of natural phenomena, and yet, it is one of the most contentious concepts of physics. In this…
When the difference between changes in energy and entropy at a given temperature is correlated with the ratio between the same changes in energy and entropy at zero average free energy of an ensemble of similar but distinct molecule-sized…
In the classical limit no work is needed to couple a system to a bath with sufficiently weak coupling strength (or with arbitrarily finite coupling strength for a linear system) at the same temperature. In the quantum domain this may be…
We give meaning to the first and second laws of thermodynamics in case of mesoscopic out-of-equilibrium systems which are driven by diffusion processes. The notion of the entropy production is analyzed. The role of the Helmholtz extremum…
The generalized zeroth law of thermodynamics indicates that the physical temperature in nonextensive statistical mechanics is different from the inverse of the Lagrange multiplier, beta. This leads to modifications of some of thermodynamic…
Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…
Landauer's bound relates changes in the entropy of a system with the inevitable dissipation of heat to the environment. The bound, however, becomes trivial in the limit of zero temperature. Here we show that it is possible to derive a…
A bath with a negative temperature is a subject of intense debate in recent times. It raises fundamental questions not only on our understanding of negative temperature of a bath in connection with thermodynamics but also on the…
It is sometimes argued that the unattainability of zero temperature is a consequence of the second law of thermodynamics. Historically, the independence of the unattainability of zero temperature from the second law was proven more than 80…
By using very general arguments, we show that the entropy loss conjecture at the glass transition violates the second law of thermodynamics and must be rejected.
We consider open quantum systems consisting of a finite system of independent fermions with arbitrary Hamiltonian coupled to one or more equilibrium fermion reservoirs (which need not be in equilibrium with each other). A strong form of the…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…
For an isolated assembly that comprises a system and its surrounding reservoirs, the total entropy ($S_{a}$) always monotonically increases as time elapses. This phenomenon is known as the second law of thermodynamics ($S_{a}\geq0$). Here…
New exact results about the nonequilibrium thermodynamics of open quantum systems at arbitrary timescales are obtained by considering all possible variations of initial conditions of a system, its environment, and correlations between them.…