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This work considers how the properties of hydrogen bonded complexes, D-H....A, are modified by the quantum motion of the shared proton. Using a simple two-diabatic state model Hamiltonian, the analysis of the symmetric case, where the donor…

Chemical Physics · Physics 2014-05-09 Ross H. McKenzie , Christiaan Bekker , Bijyalaxmi Athokpam , Sai G. Ramesh

Starting from IP-Glasma initial conditions, we investigate the effects of bulk pressure on thermal dilepton production at the Relativistic Heavy Ion Collider (RHIC) and the Large Hadron Collider (LHC) energies. Though results of the thermal…

The evolution of electron conductance in the presence of inelastic effects is studied as an atomic gold contact is formed evolving from a low-conductance regime (tunneling) to a high-conductance regime (contact). In order to characterize…

Mesoscale and Nanoscale Physics · Physics 2007-06-25 Thomas Frederiksen , Nicolas Lorente , Magnus Paulsson , Mads Brandbyge

The isotope effect in the melting temperature of ice Ih has been studied by free energy calculations within the path integral formulation of statistical mechanics. Free energy differences between isotopes are related to the dependence of…

Materials Science · Physics 2011-08-19 R. Ramirez , C. P. Herrero

We study the isotope effect on the temperature of the proton order/disorder phase transition between ice XI and ice Ih, using the quasiharmonic approximation combined with \textit{ab initio} density functional theory calculations. We show…

Materials Science · Physics 2015-10-14 Betül Pamuk , Philip B. Allen , M. -V. Fernández-Serra

We present first-principles calculations of the dI/dV characteristics of an H2 molecule sandwiched between Au and Pt electrodes in the presence of electron-phonon interactions. The conductance is found to decrease by a few percentage at…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 I. S. Kristensen , M. Paulsson , K. S. Thygesen , K. W. Jacobsen

The current-induced vibrational dynamics is a key factor determining the stability of molecular nanojunctions. Beyond conventional Joule heating, a different mechanism caused by nonconservative current-induced forces has been predicted for…

Mesoscale and Nanoscale Physics · Physics 2026-02-20 Martin Mäck , Michael Thoss , Samuel L. Rudge

We calculated reaction rate constants including atom tunneling of the reaction of dihydrogen with the hydroxy radical down to a temperature of 50 K. Instanton theory and canonical variational theory with microcanonical optimized…

Chemical Physics · Physics 2016-05-31 Jan Meisner , Johannes Kästner

We report the influence on the superconducting critical temperature $T_c$ in doped SrTiO$_3$ of the substitution of the natural $^{16}$O atoms by the heavier isotope $^{18}$O. We observe that for a wide range of doping this substitution…

Superconductivity · Physics 2016-11-03 A. Stucky , G. Scheerer , Z. Ren , D. Jaccard , J. -M. Poumirol , C. Barreteau , E. Giannini , D. van der Marel

Negative differential resistance - a decrease in current with increasing bias voltage - is a counter-intuitive effect that is observed in various molecular junctions. Here, we present a novel mechanism that may be responsible for such an…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Yonatan Dubi

We investigate the effect of a temperature dependent viscosity on the onset of thermal convection in a horizontal layer of a binary fluid mixture that is heated from below. For an exponential temperature dependence of the viscosity, we find…

Fluid Dynamics · Physics 2015-06-17 Markus Hilt , Martin Glässl , Walter Zimmermann

Particle-in-cell direct simulation Monte Carlo simulations reveal that ion-acoustic instabilities excited in presheaths can cause significant ion heating. Ion-acoustic instabilities are excited by the ion flow toward a sheath when the…

Plasma Physics · Physics 2022-01-05 Lucas Beving , Matthew Hopkins , Scott Baalrud

Relativistic heavy-ion collisions suggest that low momentum regions of the observed particle spectra are thermal and hydrodynamic, while medium-high momentum regions are non-thermal and perturbative. In this study, I construct a…

Nuclear Theory · Physics 2023-08-09 Akihiko Monnai

Atomic and single-molecule junctions represent the ultimate limit to the miniaturization of electrical circuits. They are also ideal platforms to test quantum transport theories that are required to describe charge and energy transfer in…

Mesoscale and Nanoscale Physics · Physics 2013-08-01 Woochul Lee , Kyeongtae Kim , Wonho Jeong , Linda Angela Zotti , Fabian Pauly , Juan Carlos Cuevas , Pramod Reddy

$Aims$: We revisit with new augmented accuracy the theoretical dynamics of basic isotope exchange reactions involved in the $^{12}$C/$^{13}$C, $^{16}$O/$^{18}$O, and $^{14}$N/$^{15}$N balance because these reactions have already been…

Astrophysics of Galaxies · Physics 2015-06-19 Mirjana Mladenović , Evelyne Roueff

Equilibrium properties of hydrogen-helium mixtures under conditions similar to the interior of giant gas planets are studied by means of first principle density functional molecular dynamics simulations. We investigate the molecular and…

Other Condensed Matter · Physics 2009-07-09 Jan Vorberger , I. Tamblyn , B. Militzer , S. A. Bonev

Inelastic neutron scattering was performed for an iron-based superconductor LaFeAsO0.9D0.1, where most of D (deuterium) replaces oxygen, while a tiny amount goes into interstitial sites. By first-principle calculation, we characterize the…

We consider how the infrared intensity of an O-H stretch in a hydrogen bonded complex varies as the strength of the H-bond varies from weak to strong. We obtain trends for the fundamental and overtone transitions as a function of…

Chemical Physics · Physics 2017-03-30 Bijyalaxmi Athokpam , Sai G. Ramesh , Ross H. McKenzie

We briefly review the effects of selective solvation of ions in aqueous mixtures, where the ion densities and the composition fluctuations are strongly coupled. We then examine the surface tension \gamma of a liquid-liquid interface in the…

Soft Condensed Matter · Physics 2015-06-04 Akira Onuki , Takeaki Araki

We present a theory of the isotope effect of the Curie temperature $T_{\rm c}$ in itinerant ferromagnets. The isotope effect in ferromagnets occurs via the electron-phonon vertex correction and the effective attractive interaction mediated…

Materials Science · Physics 2017-02-08 Takashi Yanagisawa , Izumi Hase , Kosuke Odagiri