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Electrical injection in organic semiconductors is a key prerequisite for the realization of organic spintronics. Using density-functional theory calculations we report the effect of electron transfer into the organic molecule Alq$_3$. Our…

Materials Science · Physics 2015-05-19 Kartick Tarafder , Biplab Sanyal , Peter M. Oppeneer

Spin-polarization is known to lead to important {\it magnetic} and {\it optical} effects in open-shell atoms and elemental solids, but has rarely been implicated in controlling {\it structural} selectivity in compounds and alloys. Here we…

mtrl-th · Physics 2009-10-28 Z. W. Lu , B. M. Klein , A. Zunger

Recent interests towards novel functionalities arising at domain walls of ferroic materials naturally call for a microscopic understanding. To this end, first-principles calculations have been performed in order to provide solid evidence of…

Materials Science · Physics 2014-04-09 Paolo Barone , Domenico Di Sante , Silvia Picozzi

By means of ab initio calculations and spin-polarized scanning tunneling microscopy experiments we show how to manipulate the local spin-polarization of a ferromagnetic surface by creating a complex energy dependent magnetic structure. We…

Ferroelectricity has been one major focus in modern fundamental research and technological application. We consider the physical origin of improper ferroelectricity in Mott insulating materials. Beyond the well-known…

Strongly Correlated Electrons · Physics 2025-06-23 Pengwei Zhao , Jiahao Yang , Gang v. Chen

While tremendous success has been achieved to date in creating both single phase and composite magnetoelectric materials, the quintessential electric-field control of magnetism remains elusive. In this work, we demonstrate a linear…

Materials Science · Physics 2011-11-10 J. M. Rondinelli , M. Stengel , N. A. Spaldin

Observation of ferroelectricity among non-d0 systems, which was believed for a long time an unrealistic concept, led to various proposals for the mechanisms to explain the same (i.e. magnetically induced ferroelectricity) during last…

A common scenario of magnetoelectric coupling in multiferroics is the electric polarization induced by spatially modulated spin structures. It is shown in this paper that the same mechanism works in magnetic dielectrics with inhomogeneous…

Materials Science · Physics 2012-11-13 A. P. Pyatakov , G. A. Meshkov , A. K. Zvezdin

Despite its great technological importance, the magnetoelectric (ME) couplings in \BF are barely understood. By using a first-principles approach, we uncover the {\it dynamic} ME couplings of the long-range spin-cycloid in BiFeO$_3$. Based…

Strongly Correlated Electrons · Physics 2016-04-01 Jun Hee Lee , Istvan Kézsmáki , Randy S. Fishman

We analyze the thermodynamic behavior of a ferromagnetic mean-spherical model with three distinct spin components and the addition of Dzyaloshinkii-Moriya interactions. Exact calculations are performed for classical and quantum versions of…

Statistical Mechanics · Physics 2022-08-12 William de Castilho , S. R. Salinas

Density-functional calculations are carried out to investigate incommensurate magnetic structures and ferroelectric polarization in newly discovered multiferroic material MnI$_2$. The exchange interactions among local moments on Mn are…

Strongly Correlated Electrons · Physics 2013-05-30 Xianxin Wu , Yingxiang Cai , Qing Xie , Hongming Weng , Heng Fan , Jiangping Hu

The spin-driven polarizations of type-I multiferroics are veiled by the preexisting ferroelectric (FE) polarization. Using first-principles calculations combined with a spin model, we uncover two hidden but huge spin-driven polarizations in…

Strongly Correlated Electrons · Physics 2015-04-28 Jun Hee Lee , Randy S. Fishman

A novel general method of describing the spin-lattice interactions in magnetic solids was proposed in terms of first principles calculations. The spin exchange and Dzyaloshinskii-Moriya interactions as well as their derivatives with respect…

Strongly Correlated Electrons · Physics 2011-12-30 H. J. Xiang , E. J. Kan , Su-Huai Wei , M. -H. Whangbo , X. G. Gong

Ferroelectricity is observed in orthorhombic $HoMnO_3$ and $YMnO_3$ at the magnetic lock-in transitions into an E-type structure or an incommensurate phase with a temperature independent wave vector, respectively. In $HoMnO_3$ the…

Strongly Correlated Electrons · Physics 2011-11-09 B. Lorenz , Y. Q. Wang , C. W. Chu

We have performed dielectric measurements and neutron diffraction experiments on the double perovskite In2NiMnO6. A ferroelectric polarization, P ~ 30 {\mu}C/m2, is observed in a polycrystalline sample below TN = 26 K where a magnetic phase…

Orthorhombic HoMnO3 is a multiferroic in which Mn antiferromagnetic order induces ferroelectricity. A second transition occurs within the multiferroic phase, in which a strong enhancement of the ferroelectric polarization occurs…

Strongly Correlated Electrons · Physics 2021-01-04 Y. W. Windsor , M. Ramakrishnan , L. Rettig , A. Alberca , T. Lippert , C. W. Schneider , U. Staub

We present results of local spin density approximation pseudopotential calculations for the ferroelectromagnet, yttrium manganite (YMnO3). The origin of the differences between ferroelectric and non-ferroelectric perovskite manganites is…

Materials Science · Physics 2015-06-25 Alessio Filippetti , Nicola A. Hill

The magnetic field induced rearrangement of the cycloidal spin structure in ferroelectric mono-domain single crystals of the room-temperature multiferroic BiFeO$_3$ is studied using small-angle neutron scattering (SANS). The cycloid…

Strongly Correlated Electrons · Physics 2018-04-11 S. Bordács , D. G. Farkas , J. S. White , R. Cubitt , L. DeBeer-Schmitt , T. Ito , I. Kézsmárki

Recent progress in the field of multiferroics led to the discovery of many new materials in which ferroelectricity is induced by cycloidal spiral orders. The direction of the electric polarization is typically constrained by spin…

This work addresses the effect of substituting Mn$^{3+}$ by Fe$^{3+}$ at the octahedral site of TbMnO$_3$ on the magnetic phase sequence, ferroelectric and magnetoelectric properties, keeping the Fe$^{3+}$ concentration below 5%. The…

Strongly Correlated Electrons · Physics 2017-05-29 R. Vilarinho , E. Queiros , D. J. Passos , D. A. Mota , P. B. Tavares , M. Mihalik , M. Zentkova , M. Mihalik , A. Almeida , J. Agostinho Moreira