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Molecular dynamics simulation methods are used to study the folding of polymer chains into packed cubic states. The polymer model, based on a chain of linked sites moving in the continuum, includes both excluded volume and torsional…

Soft Condensed Matter · Physics 2009-11-10 D. C. Rapaport

A simple model for the friction experienced by the one dimensional water chains that flow through subnanometer diameter carbon nanotubes is studied. The model is based on a lowest order perturbation theory treatment of the friction…

Fluid Dynamics · Physics 2023-05-17 J. B. Sokoloff , A. W. C. Lau

Forced desorption of a semiflexible polymer chain on a solid substrate is theoretically investigated. The pulling force versus displacement is studied for different adsorption energy and persistence length P. It is found that the…

Statistical Mechanics · Physics 2015-06-19 Pui-Man Lam , Yi Zhen

The thermally assisted detachment of a self-avoiding polymer chain from an adhesive surface by an external force applied to one of the chain ends is investigated. We perform our study in the "fixed height" statistical ensemble where one…

Soft Condensed Matter · Physics 2009-08-13 S. Bhattacharya , A. Milchev , V. G. Rostiashvili , T. A. Vilgis

Using analytical techniques and Langevin dynamics simulations, we investigate the dynamics of polymer translocation through a nanochannel embedded in two dimensions under an applied external field. We examine the translocation time for…

Soft Condensed Matter · Physics 2012-03-26 Huaisong Yong , Yilin Wang , Shichen Yuan , Bi Xu , Kaifu Luo

We obtain the entropy of flexible linear chains composed of M monomers placed on the square lattice using a transfer matrix approach. An excluded volume interaction is included by considering the chains to be self-and mutually avoiding, and…

Statistical Mechanics · Physics 2009-11-07 W. G. Dantas , J. F. Stilck

Chemical reactions inside cells are typically subject to the effects both of the cell's confining surfaces and of the viscoelastic behavior of its contents. In this paper, we show how the outcome of one particular reaction of relevance to…

Soft Condensed Matter · Physics 2015-06-04 Pinaki Bhattacharyya , Rati Sharma , Binny J. Cherayil

We study theoretically the dynamics of living polymers which can add and subtract monomer units at their live chain ends. The classic example is ionic living polymerization. In equilibrium, a delicate balance is maintained in which each…

Soft Condensed Matter · Physics 2007-05-23 Ben O'Shaughnessy , Dimitrios Vavylonis

A DNA-protein complex modelled by a semiflexible chain and an attractive spherical core is studied in the situation when an external stretching force is acting on one end monomer of the chain while the other end monomer is kept fixed in…

Soft Condensed Matter · Physics 2009-11-10 Takahiro Sakaue , Hartmut Löwen

The longitudinal response of single semiflexible polymers to sudden changes in externally applied forces is known to be controlled by the propagation and relaxation of backbone tension. Under many experimental circumstances, realized, e.g.,…

Soft Condensed Matter · Physics 2011-02-25 Florian Thüroff , Benedikt Obermayer , Erwin Frey

The process of adsorption on a planar repulsive, "marginal" and attractive wall of long-flexible polymer chains with excluded volume interactions is investigated. The performed scaling analysis is based on formal analogy between the polymer…

Soft Condensed Matter · Physics 2009-10-08 Z. Usatenko

An applied tension force changes the equilibrium conformations of a polymer chain tethered to a planar substrate and thus affects the adsorption transition as well as the coil-globule and crystallization transitions. Conversely, solvent…

Soft Condensed Matter · Physics 2015-06-22 Jutta Luettmer-Strathmann , Kurt Binder

Motivated by the experiments on DNA under torsion, we consider the problem of pulling a polymer out of a potential well by a force applied to one of its ends. If the force is less than a critical value, then the process is activated and has…

Soft Condensed Matter · Physics 2009-10-31 K. L. Sebastian

We report results of extensive Dynamical Monte Carlo investigations on self-assembled Equilibrium Polymers (EP) without loops in good solvent. (This is thought to provide a good model of giant surfactant micelles.) Using a novel algorithm…

Soft Condensed Matter · Physics 2009-10-31 J. P. Wittmer , A. Milchev , M. E. Cates

We develop a segment-scale, force-based theory for the breakdown of the unentangled Rouse model and subsequent emergence of isotropic mesoscopic localization and entropic elasticity in chain polymer liquids in the absence of…

Soft Condensed Matter · Physics 2017-04-26 Zachary E. Dell , Kenneth S. Schweizer

Large scale Monte Carlo simulations of dense layers of grafted polymer chains in good solvent conditions are used to explore the relaxation of a polymer brush. Monomer displacements are analyzed for the directions parallel and perpendicular…

Soft Condensed Matter · Physics 2021-04-13 Michael Lang , Marco Werner , Ron Dockhorn , Torsten Kreer

Polymer ejection from a capsid through a nanoscale pore is an important biological process with relevance to modern biotechnology. Here, we study generic capsid ejection using Langevin dynamics. We show that even when the ejection takes…

Biological Physics · Physics 2014-05-09 R. P. Linna , J. E. Moisio , P. M. Suhonen , K. Kaski

The structure of a polystyrene matrix filled with tightly cross-linked polystyrene nanoparticles, forming an athermal nanocomposite system, is investigated by means of a Monte Carlo sampling formalism. The polymer chains are represented as…

Soft Condensed Matter · Physics 2014-01-17 Georgios G. Vogiatzis , Evangelos Voyiatzis , Doros N. Theodorou

We study the static properties of a semiflexible polymer exposed to a quenched random environment by means of computer simulations. The polymer is modeled as two-dimensional Heisenberg chain. For the random environment we consider hard…

Soft Condensed Matter · Physics 2012-11-20 Sebastian Schoebl , Johannes Zierenberg , Wolfhard Janke

The present paper investigates the extension behavior of a wormlike chain with varied persistence length under the confinement of a cylindrical tube. Based on Odijk theory of a confined polymer chain, we have developed a theory which can…

Biological Physics · Physics 2019-11-05 Ming Li , Jizeng Wang