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Atomic oxygen adsorption on the Mo(112) surface has been investigated by means of first-principles total energy calculations. Among the variety of possible adsorption sites it was found that the bridge sites between two Mo atoms of the…

Materials Science · Physics 2007-05-23 Adam Kiejna , R. M. Nieminen

We present a density-functional theory study addressing the on-surface adsorption of oxygen at the Pd(11N) (N =3,5,7) vicinal surfaces, which exhibit (111) steps and (100) terraces of increasing width. We find the binding to be…

Materials Science · Physics 2007-05-23 Yongsheng Zhang , Jutta Rogal , Karsten Reuter

The oxidation of the Ni(111) surface is studied experimentally with low energy electron microscopy and theoretically by calculating the electron reflectivity for realistic models of the NiO/Ni(111) surface with an ab-initio scattering…

Mesoscale and Nanoscale Physics · Physics 2012-03-08 J. Ingo Flege , Axel Meyer , Jens Falta , Eugene E. Krasovskii

X-ray photoelectron spectroscopy and diffraction (XPS, XPD) and scanning tunneling microscopy (STM) have been used for study of NbOx-structures on the Nb(110) surface. It is shown that niobium atoms are ordered to form a two-dimensional…

Materials Science · Physics 2008-11-11 A. S. Razinkin , E. V. Shalaeva , M. V. Kuznetsov

Extensive density-functional calculations are performed for chemisorption of atoms in the three first periods (H, B, C, N, O, F, Al, Si, P, S, and Cl) on the polar TiC(111) surface. Calculations are also performed for O on TiC(001), for…

Materials Science · Physics 2007-05-23 Carlo Ruberto , Bengt I. Lundqvist

The Nitrogen 1s near edge X-ray absorption fine structure (NEXAFS) of gallium nitride (GaN) shows a strong natural linear dichroism that arises from its anisotropic wurtzite structure. An additional spectroscopic variation arises from…

The applicability of standard methods for compositional analysis is limited for H-containing films. Neutron reflectometry is a powerful, non-destructive method that is especially suitable for these systems due to the large negative…

Non-fullerene acceptors (NFAs) are excellent light harvesters, yet the origin of such high optical extinction is not well understood. In this work, we investigate the absorption strength of NFAs by building a database of time-dependent…

The X-ray spectra of some magnetized isolated neutron stars (NSs) show absorption features with equivalent widths (EWs) of 50 - 200 eV, whose nature is not yet well known. To explain the prominent absorption features in the soft X-ray…

High Energy Astrophysical Phenomena · Physics 2011-11-11 V. Suleimanov , V. Hambaryan , A. Y. Potekhin , G. G. Pavlov , M. van Adelsberg , R. Neuhaeuser , K. Werner

We study the atomic oxygen adsorption on Pb(111) surface by using density-functional theory within the generalized gradient approximation and a supercell approach. The atomic and energetic properties of purely on-surface and subsurface…

Materials Science · Physics 2009-11-13 Bo Sun , Ping Zhang , Zhigang Wang , Suqing Duan , Xian-Geng Zhao , Xuchun Ma , Qi-Kun Xue

We devise a theoretical description for the response of nitrogen molecules (N2) to ultrashort and intense x rays from the free electron laser (FEL) Linac Coherent Light Source (LCLS). We set out from a rate-equation description for the…

The interaction of CO with the Fe3O4(001)-(rt2xrt2)R45{\deg} surface was studied using temperature programmed desorption (TPD), scanning tunneling microscopy (STM) and x-ray photoelectron spectroscopy (XPS), the latter both under ultrahigh…

Chemisorption of CO on the stepped Cu(211) surface is studied within ab-initio density functional theory (DFT) and scanning tunneling microscopy (STM) imaging as well as manipulation experiments. Theoretically we focus on the experimentally…

Materials Science · Physics 2009-11-10 Marek Gajdos , Andreas Eichler , Jurgen Hafner , Gerhard Meyer , Karl-Heinz Rieder

The adsorption of polymer and surfactant molecules onto colloidal particles or droplets in solution can be characterized non-destructively by scattering techniques. In a first part, the general framework of Dynamic Light Scattering, Small…

Soft Condensed Matter · Physics 2007-05-24 Julian Oberdisse

To help provide insight into the remarkable catalytic behavior of the oxygen/silver system for heterogeneous oxidation reactions, purely sub-surface oxygen, and structures involving both on-surface and sub-surface oxygen, as well as…

Materials Science · Physics 2009-11-10 Wei-Xue Li , Catherine Stampfl , Matthias Scheffler

The mechanism of adsorption of the 1,4,5,8-naphthalene-tetracarboxylic-dianhydride (NTCDA) molecule on the Ag(110) surface is elucidated on the basis of extensive density functional theory calculations. This molecule, together with its…

Materials Science · Physics 2007-05-23 Audrius Alkauskas , Alexis Baratoff , C. Bruder

A systematic experimental and theoretical study about substrate induced molecular conformation in rubrene thin films by varying film thickness from sub-monolayer to multilayer, which currently attracts substantial attention with regard to…

Mesoscale and Nanoscale Physics · Physics 2016-11-28 Sumona Sinha , Chia-Hsin Wang , Manbendra Mukherjee , Tapas Mukherjee

Chemical bonds formed by hydrazine-sulfide treatment of GaAs(111) were studied by synchrotron photoemission spectroscopy. At the B surface, the top arsenic atoms are replaced by nitrogen atoms, while GaAs(111)A is covered by sulfur, also…

The adsorption of MgO molecules on a Fe(001) surface was studied using density functional theory (DFT) and projector augmented wave methods. The energetically most favored configurations for different adsorption sites considered were…

Materials Science · Physics 2015-12-10 D. Wiśnios , A. Kiejna , J. Korecki

We investigate the origin of the broad absorption features detected near 1-1.4 keV in several Narrow Line Seyfert 1 galaxies, by modelling the absorbing medium with various physical parameters, using the ionization code PEGAS. The observed…

Astrophysics · Physics 2007-05-23 D. Porquet , M. Mouchet , A. -M. Dumont