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We have generalized the Edwards' method of collective description of dense polymer systems in terms of effective potentials to polymer blends in the presence of a surface. With this method we have studied conformationally asymmetric…

Soft Condensed Matter · Physics 2009-11-11 Semjon Stepanow , Andrei A. Fedorenko

Within self-consistent field theory we study the phase behaviour of a symmetric binary AB polymer blend confined into a thin film. The film surfaces interact with the monomers via short range potentials. One surface attracts the A component…

Statistical Mechanics · Physics 2009-10-31 M. Mueller , K. Binder , E. V. Albano

We study surface effects in amorphous polymer systems by means of computer simulation. In the framework of molecular dynamics, we present two different methods to prepare such surfaces. {\em Free} surfaces are stabilized solely by…

Condensed Matter · Physics 2009-10-28 Thorsten Hapke , Andreas Linke , Gerald Paetzold , Dieter W. Heermann

We trace with unprecedented numerical accuracy the phase diagram of the Gaussian-core model, a classical system of point particles interacting via a Gaussian-shaped, purely repulsive potential. This model, which provides a reliable…

Soft Condensed Matter · Physics 2011-10-25 S. Prestipino , F. Saija , P. V. Giaquinta

It has recently been proposed that the miscibility of nanoparticles with a polymer matrix can be controlled by grafting polymer chains to the nanoparticle surface. As a first step to study this situation, we have used molecular dynamics…

Soft Condensed Matter · Physics 2010-08-06 Joshua Kalb , Douglas Dukes , Sanat K. Kumar , Robert S. Hoy , Gary S. Grest

We consider self-avoiding lattice polygons, in the hypercubic lattice, as a model of a ring polymer adsorbed at a surface and either being desorbed by the action of a force, or pushed towards the surface. We show that, when there is no…

Statistical Mechanics · Physics 2018-02-14 AJ Guttmann , EJ Janse van Rensburg , I Jensen , SG Whittington

We study the influence of many-particle interaction in a system which, in the single particle case, exhibits a metal-insulator transition induced by a finite amount of onsite pontential fluctuations. Thereby, we consider the problem of…

Disordered Systems and Neural Networks · Physics 2009-11-07 Cosima Schuster , Rudolf A. Roemer , Michael Schreiber

The interfacial structure formed in thermoreversible associating polymer solutions is studied within the density functional approach based on Flory's arguments of tree-like configurations of cluster associations. The unique characteristics…

Condensed Matter · Physics 2007-05-23 Aleksander V. Ermoshkin , Igor Erukhimovich , Jeff Z. Y. Chen

PEP-PEO block copolymer micelles offer the possibility to investigate phase behaviour and interactions of star polymers (ultra-soft colloids). A star-like architecture is achieved by an extremely asymmetric block ratio (1:20). Micellar…

Soft Condensed Matter · Physics 2009-11-11 M. Laurati , J. Stellbrink , R. Lund , L. Willner , D. Richter , E. Zaccarelli

A coarse-graining strategy, previously developed for polymer solutions, is extended here to mixtures of linear polymers and hard-sphere colloids. In this approach groups of monomers are mapped onto a single pseudoatom (a blob) and the…

Soft Condensed Matter · Physics 2015-01-07 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni

The crazing behavior of polymer nanocomposites formed by blending polymer grafted nanoparticles with an entangled polymer melt is studied by molecular dynamics simulations. We focus on the three key differences in the crazing behavior of a…

Soft Condensed Matter · Physics 2016-10-04 Dong Meng , Sanat K. Kumar , Ting Ge , Mark O. Robbins , Gary S. Grest

There are indications that interstellar and interplanetary dust grains have an inhomogeneous and fluffy structure. We investigate different methods to describe light scattering by such composite particles. Both a model of layered particles…

Astrophysics · Physics 2009-11-10 N. V. Voshchinnikov , V. B. Il'in , Th. Henning

Experimental mechanisms that yield the growth of homochiral copolymers over their heterochiral counterparts have been advocated by Lahav and co-workers. These chiral amplification mechanisms proceed through racemic {\beta}-sheet-controlled…

Quantitative Methods · Quantitative Biology 2012-12-19 Celia Blanco , David Hochberg

We investigate interfacial properties between two highly incompatible polymers of different stiffness. The extensive Monte Carlo simulations of the binary polymer melt yield detailed interfacial profiles and the interfacial tension via an…

Statistical Mechanics · Physics 2009-10-30 Marcus Mueller , Andreas Werner

We calculate statistical properties of amorphous polymer chains between crystalline lamellae by self-consistent field model simulations. In our model, an amorphous subchain is modelled as a polymer chain of which ends are grafted onto the…

Soft Condensed Matter · Physics 2015-06-23 Takashi Uneyama , Takafumi Miyata , Koh-hei Nitta

We use cluster dynamical mean field theory to study the phase diagram of the square lattice bilayer Hubbard model with an interlayer interaction. The layers are populated by two-component fermions, and the densities in both layers and the…

We use lattice-Boltzmann molecular dynamics (LBMD) simulations to study the compression of a confined polymer immersed in a fluid and pushed by a large spherical colloid with a diameter comparable to the channel width. We examined the…

Soft Condensed Matter · Physics 2024-06-24 Setarehalsadat Changizrezaei , Mikko Karttunen , Colin Denniston

We consider a coarse-grained model in which polymers under good-solvent conditions are represented by soft spheres whose radii, which should be identified with the polymer radii of gyrations, are allowed to fluctuate. The corresponding pair…

Soft Condensed Matter · Physics 2012-06-19 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni

Studies of strong gravitational lensing in current and upcoming wide and deep photometric surveys, and of stellar kinematics from (integral-field) spectroscopy at increasing redshifts, promise to provide valuable constraints on galaxy…

Astrophysics · Physics 2015-05-13 Glenn van de Ven , Rachel Mandelbaum , Charles R. Keeton

An extended theoretical study of interface potentials in adsorbed colloid-polymer mixtures is performed. To describe the colloid-polymer mixture near a hard wall, a simple Cahn-Nakanishi-Fisher free-energy functional is used. The bulk phase…

Soft Condensed Matter · Physics 2015-06-19 Jesper Koning , Yves Vandecan , Joseph Indekeu
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