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A simple formula for correlation energy $E_c$ of the $\pi$ electron systems is obtained under an approximation for the electron-electron interactions. This formula is related directly to square of the bond order matrix and the…

Other Condensed Matter · Physics 2007-05-23 Hua Zhao

The combination of density functional theory with other approaches to the many-electron problem through the separation of the electron-electron interaction into a short-range and a long-range contribution is a promising method, which is…

Materials Science · Physics 2009-11-11 Paola Gori-Giorgi , Andreas Savin

The term "long-range interactions" refers to electrostatic and magnetostatic potential energies between atoms and molecules with mutual distances ranging from a few tens to a few hundreds Bohr radii. The involved energies are much smaller…

Quantum Physics · Physics 2017-04-11 Maxence Lepers , Olivier Dulieu

By splitting the Coulomb interaction into long-range and short-range components, we decompose the energy of a quantum electronic system into long-range and short-range contributions. We show that the long-range part of the energy can be…

Chemical Physics · Physics 2009-11-10 Julien Toulouse , Francois Colonna , Andreas Savin

Short-range corrections to long-range selected configuration interaction calculations are derived from perturbation theory considerations and applied to harmonium (with two to six electrons for some low-lying states). No fitting to…

Chemical Physics · Physics 2024-07-19 Anthony Scemama , Andreas Savin

The problem of long-range correlations of particles produced in high- energy collisions is discussed. Long-range correlations involve large groups of particles. Among them are, e.g., those correlations which lead to ring-like and elliptic…

High Energy Physics - Phenomenology · Physics 2016-09-06 I. M. Dremin

In this work, we study some general property of a strongly correlated electron system defined on a lattice. Assuming that the lattice system exhibits off-diagonal long range order, we show rigorously that this assumption would lead to…

Condensed Matter · Physics 2007-05-23 C. A. Piguet , D. F. Wang , C. Gruber

We calculate the short-range exchange-correlation energy of the uniform electron gas with two modified electron-electron interactions. While the short-range exchange functionals are calculated analytically, Coupled-Cluster and…

Materials Science · Physics 2016-08-16 Julien Toulouse , Andreas Savin , Heinz-Jürgen Flad

The role that non-local short-range correlation plays at metal surfaces is investigated by analyzing the correlation surface energy into contributions from dynamical density fluctuations of various two-dimensional wave vectors. Although…

Materials Science · Physics 2009-11-07 J. M. Pitarke , J. P. Perdew

Thermodynamic and dynamical properties of systems with long range pairwise interactions (LRI) which decay as 1/r^{d+\sigma} at large distances r in $d$ dimensions are reviewed in these Notes. Two broad classes of such systems are…

Statistical Mechanics · Physics 2009-05-12 David Mukamel

The effects of a long range electronic potential on a one dimensional chain of spinless fermions are investigated by numerical techniques (Exact Diagonalisation of rings with up to 30 sites complemented by finite size analysis) and analytic…

Strongly Correlated Electrons · Physics 2009-10-31 Sylvain Capponi , Didier Poilblanc , Thierry Giamarchi

We analyze a decomposition of the Coulomb electron-electron interaction into a long-range and a short-range part in the framework of density functional theory, deriving some scaling relations and the corresponding virial theorem. We study…

Chemical Physics · Physics 2015-06-26 Julien Toulouse , Paola Gori-Giorgi , Andreas Savin

Correlation effects of an electron gas in an external potential are derived using an Effective Action functional method. Corrections beyond the random phase approximation (RPA) are naturally incorporated by this method. The Effective Action…

Materials Science · Physics 2009-11-10 A. Rebei , W. N. G. Hitchon

In recent years, studies of long-range interacting (LRI) systems have taken centre stage in the arena of statistical mechanics and dynamical system studies, due to new theoretical developments involving tools from as diverse a field as…

Statistical Mechanics · Physics 2017-04-05 Shamik Gupta , Stefano Ruffo

Thermodynamic and dynamical properties of systems with long-range pairwise interactions (LRI), which decay as $1/r^{d+\sigma}$ at large distances $r$ in $d$ dimensions, are reviewed. Two broad classes of such systems are discussed. (i)…

Statistical Mechanics · Physics 2013-12-03 Freddy Bouchet , Shamik Gupta , David Mukamel

Accurate knowledge of interaction potentials among the alkali atoms and alkaline earth ions is very useful in the studies of cold atom physics. Here we carry out theoretical studies of the long-range interactions among the Li, Na, K, and Rb…

Atomic Physics · Physics 2014-09-26 Jasmeet Kaur , D. K. Nandy , Bindiya Arora , B. K. Sahoo

The correlation energy of the homogeneous three-dimensional interacting electron gas is calculated using the variational and fixed-node diffusion Monte Carlo methods, with trial functions that include backflow and three-body correlations.…

Strongly Correlated Electrons · Physics 2009-10-31 Yongkyung Kwon , D. M. Ceperley , Richard M. Martin

Theory of long-range interactions between an atom in its ground S state and a linear molecule in a degenerate state with a non-zero projection of the electronic orbital angular momentum is presented. It is shown how the long-range…

Chemical Physics · Physics 2015-05-20 Wojciech Skomorowski , Robert Moszynski

A new method to determine electron correlation energy is described. This method is based on a better representation of the potential due to interacting electrons that is obtained by specifying both the average and standard deviation. The…

Materials Science · Physics 2007-05-23 T. R. S. Prasanna

We present a theoretical study of van der Waals interaction forces in disordered linear molecule chains. We demonstrate that the interaction energy strongly and nonmonotonously depends on the disorder correlation length. Semianalytical…

Disordered Systems and Neural Networks · Physics 2024-12-25 Yuval Mualem , Alexander N. Poddubny
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