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We consider the energy level statistics of non-interacting electrons which diffuse in a $ d $-dimensional disordered metallic conductor of characteristic Thouless energy $ E_c. $ We assume that the level distribution can be written as the…

Condensed Matter · Physics 2017-12-07 R. A. Jalabert , J. -L. Pichard , C. W. J. Beenakker

Bounds on the exchange-correlation energy of many-electron systems are derived and tested. By using universal scaling properties of the electron-electron interaction, we obtain the exponent of the bounds in three, two, one, and quasi-one…

Strongly Correlated Electrons · Physics 2009-05-21 E. Rasanen , S. Pittalis , K. Capelle , C. R. Proetto

We study non-linear adiabatic connection paths in density-functional theory using modified electron-electron interactions that perform a long-range/short-range separation of the Coulomb interaction. These adiabatic connections allows to…

Chemical Physics · Physics 2009-11-11 Julien Toulouse , Francois Colonna , Andreas Savin

Methods for estimating the correlation energy of molecules and other electronic systems are discussed based on the assumption that the correlation energy can be partitioned between atomic regions. In one method, the electron density is…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

High-$T_c$ superconductors are usually described as strongly correlated electronic systems. This feature deeply affects the one-particle and two-particle properties of the system. In particular, a large incoherent background developes on…

Superconductivity · Physics 2009-10-31 L. Boeri , E. Cappelluti , C. Grimaldi , L. Pietronero

In electronic structure calculations, the correlation energy is defined as the difference between the mean field and the exact solution of the non relativistic Schr\"odinger equation. Such an error in the different calculations is not…

Quantum Physics · Physics 2022-04-04 Kumar J. B. Ghosh , Sabre Kais , Dudley R. Herschbach

The energies of a pair of strongly-interacting subsystems with arbitrary noninteger charges are examined from closed and open system perspectives. An ensemble representation of the charge dependence is derived, valid at all interaction…

Other Condensed Matter · Physics 2009-11-11 Steven M. Valone , Susan R. Atlas

We calculate the correlation energy of a two-dimensional homogeneous electron gas using several available approximations for the exchange-correlation kernel $f_{\rm xc}(q,\omega)$ entering the linear dielectric response of the system. As in…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 R. Asgari , M. Polini , B. Davoudi , M. P. Tosi

Systems with long-range interactions have seen a surge of interest in the past decades. In the wake of this surge, the use of a system size dependent rescaling, sometimes termed "Kac prescription," of the long-range pair potential has seen…

Statistical Mechanics · Physics 2025-06-30 Michael Kastner

A method for increasing the accuracy of configuration interaction (CI) calculations of molecules and other electronic systems is proposed. The energy defect of a given calculation is associated with the electron pair origin of…

Chemical Physics · Physics 2025-11-18 Jerry L. Whitten

We review the binding and energy level alignment of $\pi$-conjugated systems on metals, a field which during the last two decades has seen tremendous progress both in terms of experimental characterization as well as in the depth of…

Materials Science · Physics 2020-05-01 Antoni Franco-Cañellas , Steffen Duhm , Alexander Gerlach , Frank Schreiber

We have studied the effect of including nearest-neighbor, electron-electron interactions, in particular the off-diagonal (non density-density) terms, on the spectra of truncated tetrahedral and icosahedral ``Hubbard molecules,'' focusing on…

Condensed Matter · Physics 2009-10-22 S. L. Sondhi , M. P. Gelfand , H. Q. Lin , D. K. Campbell

We construct the complementary short-range correlation relativistic local-density-approximation functional to be used in relativistic range-separated density-functional theory based on a Dirac-Coulomb Hamiltonian in the no-pair…

Chemical Physics · Physics 2021-05-26 Julien Paquier , Julien Toulouse

We analyze the effect of the non-vanishing range of electron-electron repulsion on the mechanism of unconventional superconductivity. We present asymptotically exact weak-coupling results for dilute electrons in the continuum and for the 2D…

Superconductivity · Physics 2012-09-13 S. Raghu , E. Berg , A. V. Chubukov , S. A. Kivelson

Strong electron correlation effects in the photophysics of quasi-one-dimensional $\pi$-conjugated organic systems such as polyenes, polyacetylenes, polydiacetylenes, etc., have been extensively studied. Far less is known on correlation…

Strongly Correlated Electrons · Physics 2014-02-18 K. Aryanpour , A. Roberts , A. Sandhu , R. Rathore , A. Shukla , S. Mazumdar

An accurate determination of the electron correlation energy is essential for describing the structure, stability, and function in a wide variety of systems, ranging from gas-phase molecular assemblies to condensed matter and…

Chemical Physics · Physics 2014-03-05 Alberto Ambrosetti , Anthony M. Reilly , Robert A. DiStasio , Alexandre Tkatchenko

Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron…

Materials Science · Physics 2009-11-11 Janos G. Angyan , Iann C. Gerber , Andreas Savin , Julien Toulouse

We consider electronic exchange and correlation effects in density-functional calculations of two-dimensional systems. Starting from wave function calculations of total energies and electron densities of inhomogeneous model systems, we…

Mesoscale and Nanoscale Physics · Physics 2012-05-30 Ilja Makkonen , Mikko M. Ervasti , Ville Kauppila , Ari Harju

The influence of long-range interactions decaying in d dimensions as 1/R^{d+\sigma} on the critical behavior of systems with Fisher's correlation-function exponent for short-range interactions \eta_{SR}<0, is re-examined. Such systems,…

Statistical Mechanics · Physics 2011-08-17 H. K. Janssen

The goal of this paper is to describe the various kinetic equations which arise from scaling limits of interacting particle systems. We provide a formalism which allows us to determine the kinetic equation for a given interaction potential…

Mathematical Physics · Physics 2020-12-10 Alessia Nota , Juan J. L. Velázquez , Raphael Winter