Related papers: A selector for structural isomers of neutral molec…
We demonstrate the spatial separation of the cis- and trans-conformers of 3-fluorophenol in the gas phase based on their distinct electric dipole moments. For both conformers we create very polar samples of their lowest-energy rotational…
The rotational constants and the nitrogen nuclear quadrupole coupling constants of cis-3-aminophenol and trans-3-aminophenol are determined using Fourier-transform microwave spectroscopy. We examine several $J=2\leftarrow{}1$ and…
We establish that matter-wave interference at near-resonant ultraviolet optical gratings can be used to spatially separate individual conformers of complex molecules. Our calculations show that the conformational purity of the prepared beam…
Atomic-resolution-imaging approaches for single molecules, such as coherent x-ray diffraction at free-electron lasers, require the delivery of high-density beams of identical molecules. However, even very cold beams of biomolecules…
We discuss Stark deflectometry of micro-modulated molecular beams for the enrichment of biomolecular isomers as well as single-wall carbon nanotubes and we demonstrate the working principle of this idea with fullerenes. The sorting is based…
We have developed and experimentally demonstrated an improved electrostatic deflector for the spatial separation of molecules according to their dipole-moment-to-mass ratio. The device features a very open structure that allows for…
A beam of polar molecules can be focused and transported through an ac electric quadrupole guide. At a given ac frequency, the transmission of the guide depends on the mass-to-dipole-moment (m/\textmu) ratio of the molecular quantum state.…
The spatial separation of 2-propanol monomer from its clusters in a molecular beam by an electrostatic deflector was demonstrated. Samples of 2-propanol monomer with a purity of 90 % and a beam density of $7\times10^6~\text{cm}^{-3}$ were…
We experimentally demonstrate interferometer-type guiding structures for neutral atoms based on dipole potentials created by micro-fabricated optical systems. As a central element we use an array of atom waveguides being formed by focusing…
Many types of neutron spectrometer use a conventional primary spectrometer consisting of some collimator, a crystal monochromator and a second collimator. Conventional resolution descriptions use instrument parameter values to deduce the…
A series of non-symmetric dimers were synthesised containing either cyanobiphenyl or difluoroterphenyl moieties on one side and a range of long, short, bent, polar or apolar mesogens on the other side of the molecules. The dielectric…
We propose to search for coherent neutrino-nucleus scattering (CNNS)by means of a triple-sectioned low background proportional counter. As a working medium we plan to use argon and xenon at about 1 MPa. We have shown using bench-scale…
We describe a macroscopic beam splitter for polar neutral molecules. A complex electrode structure is required for the beam splitter which would be very difficult to produce with traditional manufacturing methods. Instead, we make use of a…
Homo- and heteronuclear alkali quartet trimers of the type K_{3-n}Rb_{n} (n=0,1,2,3) formed on helium nanodroplets are probed by one-color femtosecond photoionization spectroscopy. The obtained requencies are assigned to vibrations in…
Accurate representation of the molecular electrostatic potential, which is often expanded in distributed multipole moments, is crucial for an efficient evaluation of intermolecular interactions. Here we introduce a machine learning model…
Distinguishing between enantiomers is crucial in the study of chiral molecules in chemistry and pharmacology. Many optical approaches rely on enantiospecific cyclic electric-dipole transitions induced by three microwave or laser beams.…
Our first-principles calculations demonstrate that ${\rm C}_{60-n}{\rm B}_{n}$ and ${\rm C}_{60-m}{\rm N}_{m}$ molecules can be engineered as the acceptors and donors, respectively, which are needed for molecular electronics, by properly…
Tautomers are ubiquitous throughout chemistry, and typically considered inseparable in solution. Yet (bio)chemical activity is highly tautomer specific, with common examples being the amino and nucleic acids. While tautomers exist in an…
The tensors which may be defined on the conformal manifold for six dimensional CFTs with exactly marginal operators are analysed by considering the response to a Weyl rescaling of the metric in the presence of local couplings. It is shown…
This paper addresses the analysis and design of non-reciprocal filters based on time modulated resonators. We analytically show that time modulating a resonator leads to a set of harmonic resonators composed of the unmodulated lumped…