Related papers: Van Der Waals Revisited
We consider thermodynamics of the van der Waals fluid of quantum systems. We derive general relations of thermodynamic functions and parameters of any ideal gas and the corresponding van der Waals fluid. This provides unambiguous…
We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional…
A result from Dodd and Gibbs[1] for the second virial coefficient of particles in 1 dimension, subject to delta-function interactions, has been obtained by direct integration of the wave functions. It is shown that this result can be…
Thermodynamic properties of non-relativistic bosons and fermions in two spatial dimensions and without interactions are derived. All the virial coefficients are the same except for the second, for which the signs are opposite. This results…
The second virial coefficient for non-Abelian Chern-Simons particles is recalculated. It is shown that the result is periodic in the flux parameter just as in the Abelian theory.
From the unified statistical thermodynamics of quantum gases, the virial coefficients of ideal Bose and Fermi gases which are trapped under generic power law potential are derived systematically. From the general result of virial…
We study the thermodynamical properties of an ideal gas of non-Abelian Chern-Simons particles and we compute the second virial coefficient, considering the effect of general soft-core boundary conditions for the two-body wavefunction at…
In this paper, we generally expressed the virial expansion of ideal quantum gases by the heat kernel coefficients for the corresponding Laplace type operator. As examples, we give the virial coefficients for quantum gases in $d$-dimensional…
We discuss the statistical mechanics of a two-dimensional gas of non-Abelian Chern-Simons particles which obey the non-Abelian braid statistics. The second virial coefficient is evaluated in the framework of the non-Abelian Chern-Simons…
This work extends the seminal work of Gottfried on the two-body quantum physics of particles interacting through a delta-shell potential to many-body physics by studying a system of non-relativistic particles when the thermal De-Broglie…
A comparable study of the quantum van der Waals and Walecka models of nuclear matter is presented. Each model contains two parameters which characterize the repulsive and attractive interactions between nucleons. These parameters are fixed…
Equation of state with quantum statistics corrections is derived for a multi-component gas of particles interacting through the repulsive and attractive van der Waals (vdW) forces up to first few orders over a small parameter $\delta…
This work presents a pedagogical derivation of the thermodynamics of a van der Waals fluid by explicitly incorporating pairwise molecular interactions and the finite size of particles into the statistical-mechanical description. Starting…
We study the roles of the dynamical high order perturbation and statistically non-linear infrared fluctuation/correlation in the virial equation of state for the Fermi gas in the unitary limit. Incorporating the quantum level crossing…
We analyze the properties of a generic cosmological fluid described by the van der Waals equation of state. Exact solutions for the energy density evolution are found as implicit functions of the scale factor for a flat…
The second virial coefficient and the second acoustic virial coefficient for helium-4 and helium-3 are computed for a wide range of temperatures (0.5 - 1000K) using a highly accurate nonrelativistic interaction potential [M. Przybytek et…
A remarkable thermodynamic fermion-boson symmetry is found for the canonical ensemble of ideal quantum gases in harmonic oscillator potentials of odd dimensions. The bosonic partition function is related to the fermionic one extended to…
Equation of state with quantum statistics corrections is derived for systems of the Fermi and Bose particles by using their van der Waals (vdW) and effective density-dependent Skyrme mean-field interactions. First few orders of these…
We explore the properties of the equilibrium space of van der Waals thermodynamic systems. We use an invariant representation of the fundamental equation by using the law of corresponding states, which allows us to perform a general…
In this work, the van der Waals fluid model, a diffuse-interface model for liquid-vapor two-phase flows, is numerically investigated. The thermodynamic properties of the van der Waals fluid are first studied. Dimensional analysis is…