Related papers: Van Der Waals Revisited
We consider the main physical notions and phenomena described by the author in his mathematical theory of thermodynamics. The new mathematical model yields the equation of state for a wide class of classical gases consisting of non-polar…
We propose a second version of the van der Waals density functional (vdW-DF2) of Dion et al. [Phys. Rev. Lett. 92, 246401 (2004)], employing a more accurate semilocal exchange functional and the use of a large-N asymptote gradient…
A quasi-particle theory for monatomic gases in equilibrium is formulated and evaluated to yield the exact virial contributions to the thermodynamic state functions in lowest order of the density. Van der Waals blocking has necessarily to be…
In this work, improvements are introduced to the current models of the ideal Fermi gas and the ideal Bose gas by incorporating the quantum nature of phase space, which is directly linked to the uncertainty principle. These improved models…
The virial expansion method is applied within a harmonic approximation to an interacting N-body system of identical fermions. We compute the canonical partition functions for two and three particles to get the two lowest orders in the…
A simple kinetic model, which is presumably minimum, for the phase transition of the van der Waals fluid is presented. In the model, intermolecular collisions for a dense gas has not been treated faithfully. Instead, the expected…
The study of quantum Coulomb systems at equilibrium is important for understanding properties of matter in many physical situations. Screening, recombination and van der Waals forces are basic phenomena which result from the interplay of…
The density operator for a quantum system in thermal equilibrium with its environment depends on Planck's constant, as well as the temperature. At high temperatures, the Weyl representation, that is, the thermal Wigner function, becomes…
A new density matrix and corresponding quantum kinetic equations are introduced for fermions undergoing coherent evolution either in time (coherent particle production) or in space (quantum reflection). A central element in our derivation…
We consider the thermoelectric properties of the mixed-dimensional quantum electrodynamics of the relativistic Dirac fermion and Wilson-Fisher boson. These models are self-dual, and can form non-trivial many-body phases depending on the…
A systematic study of the leading isotropic van der Waals coefficients for the alkali-metal atom + molecule and molecule + molecule systems is presented. Dipole moments and static and dynamic dipole polarizabilities are calculated employing…
A simple and computationally efficient scheme to calculate approximate imaginary-frequency dependent polarizability, hence asymptotic van der Waals coefficient, within density functional theory is proposed. The dynamical dipolar…
We establish the relation of the second virial coefficient of certain $(\tilde{\mu},q)$-deformed Bose gas model, recently proposed by the authors in [Ukr. J. Phys., 2013], to the interaction and compositeness parameters when either of these…
We consider dilute gases of dipolar bosons or fermions in the high-temperature limit in a spherically symmetric harmonic trapping potential. We examine the system using a virial expansion up to second order in the fugacity. Using the Born…
The general notion of distance dependent statistics in anyon-like systems is discussed. The two-body problem for such statistics is considered, the general formula for the second virial coefficient is derived and it is shown that in the…
The second virial coefficient $B_{2}^{nc}(T)$ for non-interacting particles moving in a two-dimensional noncommutative space and in the presence of a uniform magnetic field $\vec B$ is presented. The noncommutativity parameter $\te$ can be…
Various strong coupling theories of the one-component plasma have successfully predicted the thermodynamic and structural properties by separating the Coulomb potential into short- and long-ranged parts in {\itshape ad hoc} ways. Moreover,…
We derive an explicit analytic expression for the first quantum correction to the second virial coefficient of a $d$-dimensional fluid whose particles interact via the generalized Lennard-Jones $(2n,n)$ potential. By introducing an…
An exact analytic form for the second virial coefficient, valid for the entire range of temperature, is presented for the Lennard-Jones fluid in this paper. It is derived by making variable transformation that gives rise to the Hamiltonian…
Effects of quantum statistics for nuclear matter equation of state are analyzed in terms of the recently proposed quantum van der Waals model. The system pressure is expanded over a small parameter $\delta \propto…