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We review our recent x-ray scattering studies of charge and orbital order in doped manganites, with specific emphasis on the role of orbital correlations in Pr_1-xCa_xMnO_3. For x=0.25, we find an orbital structure indistinguishable from…

Photo-excitation in complex oxides1 transfers charge across semicovalent bonds, drastically perturbing spin and orbital orders2. Light may then be used in compounds like magnetoresistive manganites to control magnetism on nanometre…

X-ray resonant scattering has been used to measure the magnetic order of the Dy ions below 40K in multiferroic DyMn$_{2}$O$_{5}$. The magnetic order has a complex behaviour. There are several different ordering wavevectors, both…

Strongly Correlated Electrons · Physics 2008-04-21 R. A. Ewings , A. T. Boothroyd , D. F. McMorrow , D. Mannix , H. C. Walker , B. M. R. Wanklyn

We used resonant elastic x-ray scattering at the Cu $L_3$ and Dy $M_5$ edges to investigate charge order in thin films of underdoped DyBa$_2$Cu$_3$O$_{6+x}$ (DyBCO) epitaxially grown on NdGaO$_3$ (110) substrates. The films show an…

We studied the stripe phase of La1.8Sr0.2NiO4 using neutron diffraction, resonant soft x-ray diffraction (RSXD) at the Ni L2,3 edges, and resonant x-ray diffraction (RXD) at the Ni K threshold. Differences in the q-space resolution of the…

We present the results of a systematic x-ray scattering study of the charge and orbital ordering in the manganite series Pr$_{1-x}$Ca$_x$MnO$_3$ with $x$=0.25, 0.4 and 0.5. The temperature dependence of the scattering at the charge and…

Strongly Correlated Electrons · Physics 2009-10-31 M. v. Zimmermann , C. S. Nelson , J. P. Hill , Doon Gibbs , M. Blume , D. Casa , B. Keimer , Y. Murakami , C. -C. Kao , C. Venkataraman , T. Gog , Y. Tomioka , Y. Tokura

We report an x-ray scattering study of octahedral tilt ordering in the manganite series Pr$_{1-x}$Ca$_x$MnO$_3$ with x=0.4 and 0.25 and in LaMnO$_3$. The sensitivity to tilt ordering is achieved by tuning the incident x-ray energy to the…

The electron in a solid can be considered a bound state of the three independent, fundamental degrees of freedom creating quasi-particles: spinons, carrying the electron spin; plasmons carrying the collective charge mode and orbitons…

The complex metal oxides Mn2ASbO6 (A=In, Sc) with a corundum-related structure A3BO6 have been prepared as polycrystalline powders by a solid state reaction route. The crystal structure and magnetic properties have been investigated using a…

Materials Science · Physics 2011-11-21 S. A. Ivanov , P. Nordblad , R. Mathieu , R. Tellgren , E. Politova , G. André

We demonstrate that angle-resolved soft x-ray spectroscopy can resolve absorption by inequivalent oxygen sites and by different orbitals belonging to the same site in NaV2O5. By rotating the polarization direction, we see a dramatic change…

Strongly Correlated Electrons · Physics 2009-11-07 G. P. Zhang , G. T. Woods , Eric L. Shirley , T. A. Callcott , L. Lin , G. S. Chang , B. C. Sales , D. Mandrus , J. He

Resonant soft X-ray scattering with photon energies near the O K and the Cu L3 edges was used to study charge ordering in the system La_{1.8-x}Eu_{0.2}Sr_xCuO_4 as a function of temperature for x = 0.125 and 0.15. From the superstructure…

Superconductivity · Physics 2012-01-13 J. Fink , E. Schierle , E. Weschke , J. Geck , D. Hawthorn , H. Wadati , H. -H. Hu , H. A. Durr , N. Wizent , B. Buchner , G. A. Sawatzky

In layered manganites with orbital and charge orderings, the degeneracy of the Mn $4p$ orbitals as well as the $3d$ ones is lifted by the effects of the $4p$ bands and the local Coulomb interactions. We formulate the atomic scattering…

Strongly Correlated Electrons · Physics 2009-10-31 Sumio Ishihara , Sadamichi Maekawa

We report the first observation of `orbital truncation rods' -- the scattering arising from the termination of bulk orbital order at the surface of a crystal. The x-ray measurements, performed on a cleaved, single-layered perovskite,…

Strongly Correlated Electrons · Physics 2011-03-01 Y. Wakabayashi , M. H. Upton , S. Grenier , J. P. Hill , C. S. Nelson , J. -W. Kim , P. J. Ryan , A. I. Goldman , H. Zheng , J. F. Mitchell

Neutron diffraction measurements have been performed on a powder sample of BaMn2As2 over the temperature T range from 10 K to 675 K. These measurements demonstrate that this compound exhibits collinear antiferromagnetic ordering below the…

Superconductivity · Physics 2010-11-17 Yogesh Singh , M. A. Green , Q. Huang , A. Kreyssig , R. J. McQueeney , D. C. Johnston , A. I. Goldman

The emergence of superlattice periodicities at metal to insulator transitions in hole doped perovskite oxides responds to a rearrangement of the local atomic structure, and electron and spin density distribution. Originally, the ionic model…

Strongly Correlated Electrons · Physics 2015-05-14 Javier Herrero-Martin , Joaquín García , Blasco Javier , Claudio Mazzoli , G. Subías

Using first principle band structure calculations, we critically examine results of resonant x-ray scattering experiments which is believed to directly probe charge and orbital ordering. Considering the specific case of La0.5Sr1.5MnO4, we…

Strongly Correlated Electrons · Physics 2015-06-24 Priya Mahadevan , K. Terakura , D. D. Sarma

Soft x-ray resonant scattering at the Ni L2,3 edges is used to test models of magnetic and orbital-ordering below the metal-insulator transition in NdNiO3. The large branching ratio of the L3 to L2 intensities of the (1/2,0,1/2) reflection…

Strongly Correlated Electrons · Physics 2009-11-11 V. Scagnoli , U. Staub , A. M. Mulders , M. Janousch , G. I. Meijer , G. Hammerl , J. M. Tonnerre , N. Stojic

We report on Raman scattering measurements of the A-site ordered YBaMn2O6 in the wide temperature range of 10-650K. Upon cooling almost all phonon modes show pronounced temperature dependencies of frequency, linewidth, and scattering…

Strongly Correlated Electrons · Physics 2009-09-30 X. N. Zhang , K. -Y. Choi , P. Lemmens , T. Nakajima , Y. Ueda

Strong resonant enhancements of the charge-order and spin-order superstructure-diffraction intensities in La1.8Sr0.2NiO4 are observed when x-ray energies in the vicinity of the Ni L2,3 absorption edges are used. The pronounced photon-energy…

We report resonant x-ray scattering studies of charge and orbital order in Pr_{1-x}Ca_{x}MnO_3 with x=0.4 and 0.5. Below the ordering temperature, T_O=245 K, the charge and orbital order intensities follow the same temperature dependence,…

Strongly Correlated Electrons · Physics 2009-10-31 M. v. Zimmermann , J. P. Hill , Doon Gibbs , M. Blume , D. Casa , B. Keimer , Y. Murakami , Y. Tomioka , Y. Tokura