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The structure, thermodynamics and slow activated dynamics of the equilibrated metastable regime of glass-forming fluids remains a poorly understood problem of high theoretical and experimental interest. We apply a highly accurate…

Soft Condensed Matter · Physics 2024-08-21 Subhashish Chaki , Baicheng Mei , Kenneth S. Schweizer

We propose that glass-forming liquids are intrinsically under the influences of both fluctuating interactions and random fields well-known in the field of spin systems. This is due to the frustration between the isotropic and anisotropic…

Disordered Systems and Neural Networks · Physics 2009-10-30 Hajime Tanaka

A reliable model of viscosity in liquids using a dual liquid model framework is developed. The analytical expression arrived at exhibits the correct T-dependence Arrhenius-like. It is compared with the values of viscosity for water with…

Mesoscale and Nanoscale Physics · Physics 2024-12-04 Fabio Peluso

A simple model of a glass former fluid, consisting of a bidisperse mixture of penetrable spheres is studied. The model shows a transition from fragile to strong behavior as temperature is reduced. This transition is driven by the…

Condensed Matter · Physics 2009-10-31 E. A. Jagla

A theoretical treatment of deeply supercooled liquids is difficult because their properties emerge from spatial inhomogeneities that are self-induced, transient, and nanoscopic. I use computer simulations to analyse self-induced static and…

Statistical Mechanics · Physics 2021-08-24 Ludovic Berthier

We argue that for generic systems close to a critical point, an extended Fluctuation-Dissipation relation connects the low frequency non-linear (cubic) susceptibility to the four-point correlation function. In glassy systems, the latter…

Statistical Mechanics · Physics 2009-11-11 Jean-Philippe Bouchaud , Giulio Biroli

The dynamical heterogeneity in supercooled liquids measured by a molecular dynamics simulation has been quantified on the basis of the multifractal formalism. The singularity spectrum becomes broader as the glass transition is approached.…

Statistical Mechanics · Physics 2009-11-07 W. Sakikawa , O. Narikiyo

We present a model for glassy dynamics in supercooled liquid mixtures. Given the relaxation behavior of individual supercooled liquids, the model predicts the relaxation times of their mixtures as temperature is decreased. The model is…

Statistical Mechanics · Physics 2019-09-11 Shachi Katira , Juan P. Garrahan , Kranthi K. Mandadapu

We monitor the transformation of a liquid into an amorphous solid in simulations of a glass forming liquid by measuring the variation of a structural order parameter with either changing temperature or potential energy to establish the…

Soft Condensed Matter · Physics 2023-06-07 Gang Sun , Peter Harrowell

In this paper we propose a short range generalization of the $p$-spin interaction spin-glass model. The model is well suited to test the idea that an entropy collapse is at the bottom-line of the dynamical singularity encountered in…

Condensed Matter · Physics 2009-10-28 Diego Alvarez , Silvio Franz , Felix Ritort

As approaching the glass transition, particle motion in liquids becomes highly heterogeneous and regions with virtually no mobility coexist with liquid-like domains. This complex dynamics is believed to be responsible for different…

Soft Condensed Matter · Physics 2018-03-28 F. Puosi , N. Jakse , A. Pasturel

Interacting magnetic nanoparticles display a wide variety of magnetic behaviors that are now being gathered in the emerging field of 'supermagnetism.' We have investigated how the out-of-equilibrium dynamics in the disordered superspin…

Disordered Systems and Neural Networks · Physics 2015-06-11 Sawako Nakamae , Caroline Crauste-Thibierge , Denis L'Hote , Eric Vincent , Emmanuelle Dubois , Vincent Dupuis , Regine Perzynski

All liquids are topologically disordered materials; however, the degree of disorder can vary as a result of internal fluctuations in structure and topology. These fluctuations depend on both the composition and temperature of the system.…

Statistical Mechanics · Physics 2018-08-15 Katelyn A. Kirchner , Seong H. Kim , John C. Mauro

We present a first-principles formalism for studying dynamical heterogeneities in glass forming liquids. Based on the Non-Equilibrium Self-Consistent Generalized Langevin Equation theory, we were able to describe the time-dependent local…

Soft Condensed Matter · Physics 2022-04-06 J. Lira-Escobedo , J. R. Velez-Cordero , Pedro E. Ramírez-González

A model for the slow dynamics of the supercooled liquid is formulated in terms of the standard equations of fluctuating nonlinear hydrodynamics (FNH) with the inclusion of an extra diffusive mode for the collective density fluctuations. If…

Statistical Mechanics · Physics 2016-03-23 Neeta Bidhoodi , Shankar P. Das

We introduce the ideal Gaussian glass-forming system as a model to describe the thermodynamics and dynamics of supercooled liquids on a local scale in terms of the properties of the potential energy landscape (PEL). The first ingredient is…

Materials Science · Physics 2009-11-13 A. Heuer , A. Saksaengwijit

Glass-forming liquids grow dramatically sluggish upon cooling. This slowdown has long been thought to be accompanied by a growing correlation length. Characteristic dynamical and static length scales, however, have been observed to grow at…

Disordered Systems and Neural Networks · Physics 2016-08-22 Patrick Charbonneau , Ethan Dyer , Jaehoon Lee , Sho Yaida

Dynamical heterogeneities -- strong fluctuations near the glass transition -- are believed to be crucial to explain much of the glass transition phenomenology. One possible hypothesis for their origin is that they emerge from soft…

Soft Condensed Matter · Physics 2012-01-10 Karina E. Avila , Horacio E. Castillo , Azita Parsaeian

We have analyzed a non-randomly frustrated spin model which exhibits behavior remarkably similar to the phenomenology of structural glasses. The high-temperature disordered phase undergoes a strong first-order transition to a long-range…

Statistical Mechanics · Physics 2008-02-03 Lei Gu , Bulbul Chakraborty

We assess the validity of "microscopic" approaches of glass-forming liquids based on the sole k nowledge of the static pair density correlations. To do so we apply them to a benchmark provided by two liquid models that share very similar…

Statistical Mechanics · Physics 2011-10-10 Ludovic Berthier , Gilles Tarjus