Related papers: Ortho-para transition in molecular hydrogen
We calculate the rate of the spontaneous magnetic dipole radiation transitions from ortho- to para-states of the hydrogen molecule at the room temperature with the radiation wavelengths about 0.01 - 0.1 cm. Exponentially small differences…
We present the first systematic calculation of the electric dipole forbidden transitions in the homonuclear molecular ion H$_2^+$. We get that the transition rate from the ground "ortho" $(v\!=\!0,N\!=\!1,J\!=\!1/2)$ state to the ground…
We consider the noncommutative algebra which is rotationally invariant. The hydrogen atom is studied in a rotationally invariant noncommutative space. We find the corrections to the energy levels of the hydrogen atom up to the second order…
Molecular vibrational transitions are prime candidates for model-independent searches for variation of the proton-to-electron mass ratio. Searches for present-day variation achieve highest sensitivity with deep molecular potentials. We…
Low-frequency Raman peaks, below 250 cm-1, are observed in hydrogen between 2-174 GPa and 13-300 K. The origin of these features is attributed to reorientational transitions (DeltaJ = 0; Q0-branch), which shift from the Rayleigh line as…
Spontaneous nuclear ortho-para transitions are shown to be possible in hydrogen molecule and molecular ion as due to hyperfine interaction odd-odd relative to the space or spin nuclear coordinate permutations. A part of this interaction…
The water molecule occurs in two nuclear-spin isomers that differ by the value of the total nuclear spin of the hydrogen atoms, i.e., $I=0$ for para-H$_2$O and $I=1$ for ortho-H$_2$O. Spectroscopic transitions between rovibrational states…
We have detected the S(1), S(2), S(3), S(4) and S(5) pure rotational lines of molecular hydrogen toward the outflow source HH 54, using the Short Wavelength Spectrometer (SWS) on board the Infrared Space Observatory (ISO). The observed H2…
In this work we report the results concerning calculations for quantum-mechanical rotational transitions in molecular hydrogen, H$_2$, induced by an ultra-cold ground state anti-hydrogen atom $\bar{H}_{1s}$. The calculations are…
A detailed study of the lowest states $1s_0, 2p_{-1}, 2p_0$ of the hydrogen atom placed in a magnetic field $B\in(0-4.414\times 10^{13} {\rm G})$ and their electromagnetic transitions ($1s_{0} \leftrightarrow 2p_{-1}$ and $ 1s_{0}…
We report a measurement of the ortho-para transition rate in the p$\mu$p molecule. The experiment was conducted at TRIUMF via the measurement of the time dependence of the 5.2 MeV neutrons from muon capture in liquid hydrogen. The…
Theoretical cross sections for the pressure broadening by hydrogen of rotational transitions of water are compared to the latest available measurements in the temperature range 65-220 K. A high accuracy interaction potential is employed in…
We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous…
We present Herschel/HIFI observations of the fundamental rotational transitions of ortho- and para-H$_2^{16}$O and H$_2^{18}$O in absorption towards Sagittarius~B2(M) and W31C. The ortho/para ratio in water in the foreground clouds on the…
A calculation of the rotational S$_0$(0) frequencies in high pressure solid para-hydrogen is performed. Convergence of the perturbative series at high density is demonstrated by the calculation of second and third order terms. The results…
There has been disagreement in the literature on whether the hydrogen atom spectrum receives any tree-level correction due to noncommutativity. Here we shall clarify the issue and show that indeed a general argument on the structure of…
The extremely narrow natural linewidths of rovibrational energy levels in the molecular hydrogen ion $\textrm{H}_2^{\,+}$, and the prospect of synthesising its antimatter counterpart $\overline{\textrm{H}}_2^{\,-}$, make it a promising…
The laws of quantum mechanics are often tested against the behaviour of the lightest element in the periodic table, hydrogen. One of the most striking properties of molecular hydrogen is the coupling between molecular rotational properties…
Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star forming regions, and in particular the Class 0 protostar IRAS 16293-2422. The CHESS (Chemical…
Quantitative spectroscopy of molecular hydrogen has generated substantial demand, leading to the accumulation of diverse elementary-process data encompassing radiative transitions, electron-impact transitions, predissociations, and…