English

Forbidden "ortho"--"para" electric dipole transitions in H$_2^+$ ion

Atomic Physics 2023-03-01 v3

Abstract

We present the first systematic calculation of the electric dipole forbidden transitions in the homonuclear molecular ion H2+_2^+. We get that the transition rate from the ground "ortho" (v ⁣= ⁣0,N ⁣= ⁣1,J ⁣= ⁣1/2)(v\!=\!0,N\!=\!1,J\!=\!1/2) state to the ground "para" (v ⁣= ⁣0,N ⁣= ⁣0,J ⁣= ⁣1/2)(v\!=\!0,N\!=\!0,J\!=\!1/2) state is 4.9 ⁣× ⁣10144.9\!\times\!10^{-14} s1^{-1} that corresponds to the lifetime of 6.4 ⁣× ⁣1056.4\!\times\!10^5 yr. The Einstein coefficient AnnA_{nn'} for the (v ⁣= ⁣1,N ⁣= ⁣1,J ⁣= ⁣1/2) ⁣ ⁣(v ⁣= ⁣0,N ⁣= ⁣0,J ⁣= ⁣1/2)(v\!=\!1,N\!=\!1,J\!=\!1/2)\!\to\!(v\!=\!0,N\!=\!0,J\!=\!1/2) transition is equal to 0.12 ⁣× ⁣1090.12\!\times\!10^{-9} s1^{-1}, which is of "comparable" order with the values for quadrupole transitions in H2+_2^+. It gives hope that the "ortho"--"para" transitions in H2+_2^+ can be induced by the laser spectroscopy.

Keywords

Cite

@article{arxiv.2211.09396,
  title  = {Forbidden "ortho"--"para" electric dipole transitions in H$_2^+$ ion},
  author = {V. I. Korobov and D. Bakalov},
  journal= {arXiv preprint arXiv:2211.09396},
  year   = {2023}
}

Comments

5 pages, 3 tables, submitted to PRA