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We reformulate and extend porous electrode theory for non-ideal active materials, including those capable of phase transformations. Using principles of non-equilibrium thermodynamics, we relate the cell voltage, ionic fluxes, and Faradaic…

Chemical Physics · Physics 2012-08-24 Todd R. Ferguson , Martin Z. Bazant

We investigate phase separation dynamics in a binary mixture subjected to a moving cooling source from which cold temperature fronts propagate radially outward into the mixture. The motion of the source introduces two distinct velocity…

Statistical Mechanics · Physics 2026-04-29 Lakshmipriya K , Harssh Karn , Sutapa Roy

Phase transformations such as freezing typically start with heterogeneous nucleation. Heterogeneous nucleation near a wetting transition, of a crystalline phase is studied. The wetting transition occurs at or near a vapour-liquid transition…

Statistical Mechanics · Physics 2009-11-07 Richard P. Sear

Tackling the low-temperature fate of supercooled liquids is challenging due to the immense timescales involved, which prevent equilibration and lead to the operational glass transition. Relating glassy behaviour to an underlying,…

Statistical Mechanics · Physics 2017-08-16 Francesco Turci , C. Patrick Royall , Thomas Speck

We study here how phase transitions are induced in colloidal suspensions by a point-like heat source, an optically trapped metal oxide particle absorbing light. We find that thermophoresis increases the number density of colloids around the…

Soft Condensed Matter · Physics 2019-11-26 Nicolas Bruot , Hajime Tanaka

In simulations of a water-like model (ST2) that exhibits a liquid-liquid phase transition, we test for the occurrence of a thermodynamic region in which the liquid can be modelled as a two-component mixture. We assign each molecule to one…

Statistical Mechanics · Physics 2011-03-24 Megan J. Cuthbertson , Peter H. Poole

We examine the force between two charged surfaces immersed in aqueous mixtures having a coexistence curve. For a homogeneous water-poor phase, as the distance between the surfaces is decreased, a water-rich phase condenses at a distance…

Statistical Mechanics · Physics 2015-05-27 Sela Samin , Yoav Tsori

Phase separation and transitions among different molecular states are ubiquitous in living cells. Such transitions can be governed by local equilibrium thermodynamics or by active processes controlled by biological fuel. It remains largely…

Biological Physics · Physics 2021-11-24 G. Bartolucci , O. Adame-Arana , X. Zhao , C. A. Weber

We consider two point charges in electrostatic interaction between them within the framework of a nonlinear model, associated with QED, that provides finiteness of their field energy. We argue that if the two charges are equal to each other…

High Energy Physics - Theory · Physics 2016-11-22 A. I. Breev , A. E. Shabad

Colloid-polymer mixtures are an archetype for modeling phase transition processes, as they a exhibit low-density gas phase, high-density crystalline phase and an intervening liquid phase. While their equilibrium behavior has been studied…

Soft Condensed Matter · Physics 2024-12-18 Lauren Barnes , Boris Khusid , Lou Kondic , William V. Meyer , Anand U. Oza

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant

Rydberg atoms and beams of ultracold polar molecules have become highly useful experimental tools in recent years. There is therefore a need for accessible calculations of interaction potentials between such particles and nearby surfaces…

Quantum Physics · Physics 2012-03-05 Simen Å. Ellingsen , Stefan Yoshi Buhmann , Stefan Scheel

Many materials containing colloids or polymers are polydisperse: They comprise particles with properties (such as particle diameter, charge, or polymer chain length) that depend continuously on one or several parameters. This review…

Soft Condensed Matter · Physics 2007-05-23 Peter Sollich

We present an experimental and theoretical study of the phase behavior of a binary mixture of colloids with opposite adsorption preferences in a critical solvent. As a result of the attractive and repulsive critical Casimir forces, the…

Soft Condensed Matter · Physics 2011-10-03 O. Zvyagolskaya , A. J. Archer , C. Bechinger

The dominant modes of charge transport in variant polar liquid based nanoparticulate colloidal dispersions (dilute) have been theorized. Theories formulating electrical characteristics of colloids have often been found to over or under…

Soft Condensed Matter · Physics 2015-12-01 Purbarun Dhar , Arvind Pattamatta , Sarit K. Das

We develop an efficient Ewald method of molecular dynamics simulation for calculating the electrostatic interactions among charged and polar particles between parallel metallic plates, where we may apply an electric field with an arbitrary…

Soft Condensed Matter · Physics 2013-10-01 Kyohei Takae , Akira Onuki

Lattice models are crucial for studying thermodynamic properties in many physical, biological and chemical systems. We investigate Lattice Restricted Primitive Model (LRPM) of electrolytes with different discretization parameters in order…

Statistical Mechanics · Physics 2009-11-11 Maxim N. Artyomov , Anatoly B. Kolomeisky

One dimensional non-equilibrium systems with short-range interaction can undergo phase transitions from homogeneous states to phase separated states as interaction ($\epsilon$) among particles is increased. One of the model systems where…

Statistical Mechanics · Physics 2011-05-31 Anasuya Kundu , P. K. Mohanty

We find that a system of particles interacting through a simple isotropic potential with a softened core is able to exhibit a rich phase behavior including: a liquid-liquid phase transition in the supercooled phase, as has been suggested…

Soft Condensed Matter · Physics 2009-10-31 G. Malescio , G. Pellicane

We consider ferroelectric phase transitions in both short-circuited and biased ferroelectric-semiconductor films with a space (depletion) charge which leads to some unusual behavior. It is shown that in the presence of the charge the…

Statistical Mechanics · Physics 2009-10-31 A. M. Bratkovsky , A. P. Levanyuk