Related papers: Validity of the "sharp-kink approximation" for wat…
We explore the pressure of active particles on curved surfaces and its relation to other interfacial properties. We use both direct simulations of the active systems as well as simulations of an equilibrium system with effective (pair)…
The surface of a liquid near a moving contact line is highly curved owing to diverging viscous forces. Thus, microscopic physics must be invoked at the contact line and matched to the hydrodynamic solution farther away. This matching has…
We study water between parallel metal walls under applied electric field accounting for the image effect at $T=298$ K. The electric field due to the surface charges serves to attract and orient nearby water molecules, while it tends to a…
This paper presents a broad theoretical and simulation study of the high temperature behavior of crystalline alkali halide surfaces typified by NaCl(100), of the liquid NaCl surface near freezing, and of the very unusual partial wetting of…
The quality of a liquid-repellent surface is quantified by both the apparent contact angle $\theta_0$ that a sessile drop adopts on it, and the value of the liquid pressure threshold the surface can withstand without being impaled by the…
The contact angle of a macroscopic droplet on a heterogeneous but flat substrate is studied using the interface displacement model which can lead to the augmented Young-Laplace equation. Droplets under the condition of constant volume as…
Liquids flowing against solid surfaces experience friction. While solid friction is familiar to anyone with a sense of touch, liquid friction is much more exotic. At macroscopic scales indeed, the assumption of inifinite friction, i.e. that…
The state of protonation/deprotonation of surfaces has far-ranging implications in all areas of chemistry: from acid-base catalysis$^1$ and the electro- and photocatalytic splitting of water$^2$, to the behavior of minerals$^3$ and…
We determine the surface tension of aqueous electrolyte solutions in contact with non-polar dielectric media using a thermomechanical approach, which involves deriving the stress tensor from the thermodynamic potential of an inhomogeneous…
An analytical model is proposed for the Young-Laplace equation of two-dimensional (2D) drops under gravity. Inspired by the pioneering work of Landau & Lifshitz (1987), we derive analytical expressions of the profile of drops on flat…
A particle-water discrete element based approach to describe water movement in partially saturated granular media is presented and tested. Water potential is governed by both capillary bridges, dominant at low saturations, and the pressure…
Surface tension tends to minimize the area of interfaces between pieces of matter in different thermodynamic phases, be they in the solid or the liquid state. This can be relevant for the macroscopic shape of very soft solids, and lead to a…
When a liquid droplet impacts a vibrated micro-structured surface with asymmetric topology, the liquids perform a horizontal motion during its bouncing. The moving effect is observed when the liquid is in contact with a low surface energy…
When a liquid droplet is located above a super-hydrophobic surface, it only barely touches the solid portion of the surface, and therefore slides very easily on it. More generally, super-hydrophobic surfaces have been shown to lead to…
Making use of experimental and theoretical considerations, in this Letter we deduce a criterion to determine the critical velocity for which a drop impacting a smooth dry surface either spreads over the substrate or disintegrates into…
A microscopic density functional theory is used to investigate the adsorption of short chains on attractive solid surfaces. We analyze the structure of the adsorbed fluid and investigate how the wetting transition changes with the change of…
Previous research has indicated the possible existence of a liquid-liquid critical point (LLCP) in models of silica at high pressure. To clarify this interesting question we run extended molecular dynamics simulations of two different…
We explain the findings by Di Leonardo et al. [Phys. Rev. Lett. 84, 6054 (2000)] that the effective temperature of a Lennard-Jones glass depends only on the final value of the density in the volume and/or temperature jump that produces the…
Formulas, analogous to the Triezenberg-Zwanzig expression for the surface tension of a planar interface, are presented for the Tolman length, the bending rigidity, and the rigidity constant associated with Gaussian curvature. These…
We have studied the breakup and subsequent fluid flow in very thin films of partially wetting liquid on solid substrates, using molecular dynamics simulations. The liquid is made of short chain molecules interacting with Lennard-Jones…