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Inelastic light scattering spectra of Bi_2Se_3 and Sb_2Te_3 single crystals have been measured over the temperature range from 5 K to 300 K. The temperature dependence of dominant A^{2}_{1g} phonons shows similar behavior in both materials.…

We report the direct observation of a "resonance" mode in the lowest-energy optic phonon very near the zone center around (111) in the multiferroic BiFeO$_3$ using neutron scattering methods. The phonon scattering intensity is enhanced when…

We have investigated crystal field and phonon dynamics of the multiferroic orthoferrite DyFeO$_3$ via polarized infrared spectroscopy. Reflectance of single crystals was measured in the far- to mid-infrared spectral range at range of…

Strongly Correlated Electrons · Physics 2013-02-14 A. D. LaForge , J. Whalen , T. Siegrist , A. P. Ramirez , Z. Schlesinger

We present a comprehensive study of polar and magnetic excitations in BiFeO3 ceramics and a thin film epitaxially grown on an orthorhombic (110) TbScO3 substrate. Infrared reflectivity spectroscopy was performed at temperatures from 5 to…

Materials Science · Physics 2015-05-22 S. Skiadopoulou , V. Goian , C. Kadlec , F. Kadlec , X. F. Bai , I. C. Infante , B. Dkhil , C. Adamo , D. G. Schlom , S. Kamba

Inelastic light scattering studies on single crystal of electron-doped Ca(Fe0.95Co0.05)2As2 superconductor, covering the tetragonal to orthorhombic structural transition as well as magnetic transition at TSM ~ 140 K and superconducting…

The detailed temperature dependence of the infrared-active mode in Fe$_{1.03}$Te ($T_N\simeq 68$ K) and Fe$_{1.13}$Te ($T_N\simeq 56$ K) has been examined, and the position, width, strength, and asymmetry parameter determined using an…

Strongly Correlated Electrons · Physics 2016-05-18 C. C. Homes , Y. M. Dai , J. Schneeloch , R. D. Zhong , G. D. Gu

Compressively strained epitaxial (001) EuTiO3 thin films of tetragonal symmetry have been deposited on (001) (LaAlO3)_0.29-(SrAl_{1/2}Ta_{1/2}O3)_0.71 (LSAT) substrates by reactive molecular-beam epitaxy. Enhancement of the Neel temperature…

Raman study on a select few orthochromites, RCrO$_3$ (R = Y, Lu, Gd, Eu and Sm) shows that the phonon behavior at TN in compounds with magnetic R-ion (Gd and Sm) is remarkably different from that of non-magnetic R-ion (Y, Lu and Eu). While…

Materials Science · Physics 2013-06-11 Venkata Srinu Bhadram , B. Rajeswaran , A. Sundaresan , Chandrabhas Narayana

NiPS3 is a Van der Waals antiferromagnet that has been found to display spin-charge and spin-phonon coupling in its antiferromagnetically ordered state below TN = 155 K. Here, we study high-quality crystals of site-diluted Ni1-xZnxPS3 (0 <…

Strongly Correlated Electrons · Physics 2023-07-26 Nashra Pistawala , Ankit Kumar , Devesh Negi , Dibyata Rout , Luminita Harnagea , Surajit Saha , Surjeet Singh

The Raman scattering response of the biaxial antiferromagnet CoPS$_3$ has been investigated as a function of both magnetic field and temperature. The peaks observed in the low-frequency spectral range (90--200~cm$^{-1}$) have been…

We discuss the first infrared reflectivity measurement on a BiFeO3 single crystal between 5 K and room temperature. The 9 predicted ab-plane E phonon modes are fully and unambiguously determined. The frequencies of the 4 A1 c-axis phonons…

Materials Science · Physics 2011-11-10 R. P. S. M. Lobo , R. L. Moreira , D. Lebeugle , D. Colson

High quality single crystals of Bi2Se3 were grown using a modified Bridgman technique, the detailed study were carried out using Raman spectroscopy and characterized by Laue diffraction and high resolution transmission electron microscopy.…

EuTiO3 (ETO) has recently experienced an enormous revival of interest because of its possible multiferroic properties which are currently in the focus of research. Unfortunately ETO is an unlikely candidate for enlarged multifunctionality…

Materials Science · Physics 2015-06-05 A. Bussmann-Holder , Z. Guguchia , J. Köhler , H. Keller , A. Shengelaya , A. R. Bishop

The polarized Raman scattering spectra of nonsuperconducting $\alpha$-FeTe and of the newly discovered, As-free superconductor Fe$_{1.03}$Se$_{0.3}$Te$_{0.7}$ are measured at room temperature on single crystals. The phonon modes are…

Superconductivity · Physics 2009-05-11 Tian-Long Xia , D. Hou , S. C. Zhao , A. M. Zhang , G. F. Chen , J. L. Luo , N. L. Wang , J. H. Wei , Z. -Y. Lu , Q. M. Zhang

Infrared reflectance spectra of an epitaxial Bi2FeCrO6 thin film prepared by pulsed laser deposition on LaAlO3 substrate were recorded between 10 and 900 K. No evidence for a phase transition to the paraelectric phase was observed, but some…

Materials Science · Physics 2009-01-06 S. Kamba , D. Nuzhnyy , R. Nechache , K. Zaveta , D. Niznansky , E. Santava , C. Harnagea , A. Pignolet

We have measured polarized Raman scattering spectra of the Fe$_{1-x}$Co$_{x}$Sb$_{2}$ and Fe$_{1-x}$Cr$_{x}$Sb$_{2}$ (0$\leq x\leq $0.5) single crystals in the temperature range between 15 K and 300 K. The highest energy $B_{1g}$ symmetry…

Strongly Correlated Electrons · Physics 2016-09-20 N. Lazarević , Z. V. Popović , Rongwei Hu , C. Petrovic

We report on TmMnO3 far infrared emissivity and reflectivity spectra from 1910 K to 4 K. At the highest temperature the number of infrared bands is lower than that predicted for centrosymmetric P63/mmc (D6h4) (Z=2) space group due high…

The ZFC and FC magnetization dependence on temperature was measured for BiFeO3 ceramics at the applied magnetic field up to H=10T in 2K-1000K range. The antiferromagnetic order was detected from the hysteresis loops below the Neel…

Materials Science · Physics 2013-05-15 B. Andrzejewski , A. Molak , B. Hilczer , A. Budziak , R. Bujakiewicz-Koronska

We report a temperature-dependent Raman and neutron scattering investigation of the multiferroic material bismuth ferrite BiFeO3 (BFO).

Materials Science · Physics 2009-11-11 R. Haumont , J. Kreisel , P. Bouvier , F. Hippert

The spin-phonon coupling in magnetic materials is due to the modulation of the exchange integral by lattice vibrations. BaFe12O19 M-type hexaferrite, which is the most used magnetic material as permanent magnet, transforms into ferromagnet…

Materials Science · Physics 2015-06-22 Flávio M. Silva Júnior , Carlos W. A. Paschoal