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We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

Two interaction mechanisms of particles in a fluid are proposed on base of forces, mediated by hydrodynamic thermal fluctuations. The first one is similar to the conventional van der Waals interaction, but instead of been mediated by…

Soft Condensed Matter · Physics 2009-11-07 B. I. Ivlev

For like charged colloidal particles two mechanisms of attraction between them survive when the interparticle distance is larger than the Debye screening length. One of them is the conventional van der Waals attraction and the second one is…

Soft Condensed Matter · Physics 2009-08-25 T. Ocampo-Delgado , B. Ivlev

We present an approach to describing fluctuational electrodynamic (FED) interactions, particularly van der Waals (vdW) interactions as well as radiative heat transfer (RHT), between material bodies of vastly different length scales,…

Mesoscale and Nanoscale Physics · Physics 2020-08-12 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

A version of the Green's functions theory of the Van der Waals forces which can be conveniently used in the presence of spatial dispersion is presented. The theory is based on the fluctuation-dissipation theorem and is valid for interacting…

Statistical Mechanics · Physics 2009-05-22 L. P. Pitaevskii

A new scheme for the computation of dispersive interactions from first principles is presented. This cost-effective approach relies on a Wannier function representation compatible with density function theory descriptions. This is an…

Materials Science · Physics 2025-02-04 Diem Thi-Xuan Dang , Dai-Nam Le , Lilia M. Woods

Mutual Coulomb interactions between electrons lead to a plethora of interesting physical and chemical effects, especially if those interactions involve many fluctuating electrons over large spatial scales. Here, we identify and study in…

Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…

Quantum Physics · Physics 2007-05-23 Stefan Yoshi Buhmann , Ho Trung Dung , Dirk-Gunnar Welsch

The quantum theory of the fluctuations of the van der Waals (vdW) force between macroscopic bodies is developed. Unlike the mean vdW force that is determined by all quantum states that contribute to the optical absorption, the energies of…

Materials Science · Physics 2007-05-23 Shulim Kogan

Fluctuations in fluid velocity and fluctuations in electric fields may both give rise to forces acting on small particles in colloidal suspensions. Such forces in part determine the thermodynamic stability of the colloid. At the classical…

Soft Condensed Matter · Physics 2013-05-29 D. Drosdoff , A. Widom

Fluctuations of the thermal or classical component of the van der Waals force between two dielectric slabs, modelled as an ensemble of polarizable dipoles which interact via the usual electrostatic dipole-dipole interaction, are evaluated.…

Statistical Mechanics · Physics 2015-06-15 D. S. Dean , V. A. Parsegian , R. Podgornik

We use the theory of the fluctuating electromagnetic field to calculate the frictional drag between nearby two-and three dimensional electron systems. The frictional drag results from coupling via a fluctuating electromagnetic field, and…

Materials Science · Physics 2009-11-11 A. I. Volokitin , B. N. J. Persson

From microscopic fluid clusters to macroscopic droplets, the structure of fluids is governed by the Van der Waals force, a force that acts between polarizable objects. In this Letter, we derive a general theory that describes the…

Soft Condensed Matter · Physics 2013-12-10 Igor M. Kulic , Miodrag L. Kulic

The van der Waals friction between two semi-infinite solids, and between a small neutral particle and semi-infinite solid is reconsidered on the basis of thermal quantum field theory in the Matsubara formulation. The calculation of the…

Materials Science · Physics 2009-11-11 A. I. Volokitin , B. N. J. Persson

Ubiquitous van der Waals (vdW) interactions play a subtle yet crucial role in determining the precise atomic arrangements in solids, particularly in molecular crystals where these weak forces are the primary link between constituent…

Proper inclusion of van der Waals (vdW) interactions in theoretical simulations based on standard density functional theory (DFT) is crucial to describe the physics and chemistry of systems such as organic and layered materials. Many…

Materials Science · Physics 2023-07-19 Jinwoo Park , Byung Deok Yu , Suklyun Hong

We use a general theory of the fluctuating electromagnetic field to calculate the friction force acting on a small neutral particle, e.g., a physisorbed molecule, or a nanoscale object with arbitrary dispersive and absorptive dielectric…

Materials Science · Physics 2009-11-11 A. I. Volokitin , B. N. J. Persson

The van der Waals interaction between two ground-state atoms is calculated for two electrically or magnetically polarizable particles embedded in a dispersive magneto-dielectric medium. Unlike previous calculations which infer the atom-atom…

Quantum Physics · Physics 2009-11-13 S. Spagnolo , D. A. R. Dalvit , P. W. Milonni

A density functional theory (DFT) that accounts for van der Waals (vdW) interactions in condensed matter, materials physics, chemistry, and biology is reviewed. The insights that led to the construction of the Rutgers-Chalmers van der Waals…

A new general expression is derived for the fluctuating electromagnetic field outside a metal surface, in terms of its surface impedance. It provides a generalization to real metals of Lifshitz theory of molecular interactions between…

Quantum Physics · Physics 2008-11-26 Giuseppe Bimonte
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