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Exploration of metal clusters (MCs) adaptive to both aqueous and oil phases without disturbing their size is promising for a broad scope of applications. The state-of-the-art approach via ligand-binding may perturb MC size due to varied…

Chemical Physics · Physics 2019-04-26 Su-Yun Zhang , Zdravko Kochovski , Hui-Chun Lee , Yan Lu , Jie Zhang , Jian-Ke Sun , Jiayin Yuan

The market quest for fast-charging, safe, long-lasting and performant batteries drives the exploration of new energy storage materials, but also promotes fundamental investigations of materials already widely used. Presently, revamped…

Electrical and optical properties of amorphous vanadium oxide thin films obtained by electrochemical anodic oxidation are studied. It is shown that under cathodic polarization the hydrogen insertion into vanadium oxide from an electrolyte…

The polyanionic compound Na2MnSiO4 is regarded as one of the promising cathode materials for Na-ion batteries due to good specific capacity with its attractive prospect of utilization of two electrons in the redox processes. So, in this…

Materials Science · Physics 2021-10-19 Vishnu Sudarsanan , Anu Maria Augustine , P Ravindran

Intercalation of alkali atoms within the lamellar transition metal dichalcogenides is a possible route toward a new generation of batteries. It is also a way to induce structural phase transitions authorizing the realization of optical and…

Electrochemical desalination devices that use redox-active cation intercalation electrodes show promise for desalination of salt-rich water resources with high water recovery and low energy consumption. While previous modeling and…

Applied Physics · Physics 2018-04-02 Sizhe Liu , Kyle C. Smith

Tetragonally distorted \(\rm{Mn}_{3-x}\rm{Ga}_x\) thin films with \(0.1< x < 2\) show a strong perpendicular magnetic anisotropy and low magnetization and thus have the potential to serve as electrodes in spin transfer torque magnetic…

We report on the non-trivial nanoscale kinetics of the deposition of novel complex oxide heterostructures composed of a unit-cell thick correlated metal LaNiO3 and dielectric LaAlO3. The multilayers demonstrate exceptionally good…

Strongly Correlated Electrons · Physics 2015-05-18 M. Kareev , S. Prosandeev , Jian Liu , B. Gray , P. Ryan , A. Kareev , Eun Ju Moon , J. Chakhalian

Co-intercalation is a potential approach to influence the voltage and mobility with which cations insert in electrodes for energy storage devices. Combining a robust thermodynamic model with first-principles calculations, we present a…

Electrical control of oxygen off-stoichiometry of transition-metal oxides at room temperature is a desired strategy to simultaneously switch the electrical conductance and magnetism of the device. Although the use of the electrochemical…

Materials Science · Physics 2016-04-05 Takayoshi Katase , Yuki Suzuki , Hiromichi Ohta

We developed two-step solution-phase reactions to form hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery applications. Mn3O4 nanoparticles grown selectively on RGO sheets over free…

Supercapacitors capable of providing high voltage, energy and power density but yet light, low volume occupying, flexible and mechanically robust are highly interesting and demanded for portable applications. Herein, freestanding flexible…

Improving the stability of electrocatalysts for the oxygen evolution reaction (OER) through materials design has received less attention than improving their catalytic activity. We explored the effect of Mn addition to a cobalt oxide for…

Materials Science · Physics 2022-02-23 Javier Villalobos , Dulce M. Morales , Denis Antipin , Götz Schuck , Ronny Golnak , Jie Xiao , Marcel Risch

X-ray diffraction, transmission electron microscopy, and magnetization measurements are employed to study the structural and magnetic properties of Mn-rich (Mn,Ga)As nanocrystals embedded in GaAs. These nanocomposites are obtained by…

A multilayer edge molecular electronics device (MEMED), which utilize the two metal electrodes of a metal-insulator-metal tunnel junction as the two electrical leads to molecular channels, can overcome the long standing fabrication…

Mesoscale and Nanoscale Physics · Physics 2019-12-04 Pawan Tyagi

Transition-metal perovskite oxides exhibit a wide range of extraordinary but imperfectly understood phenomena. Charge, spin, orbital, and lattice degrees of freedom all undergo order-disorder transitions in regimes not far from where the…

Strongly Correlated Electrons · Physics 2009-11-07 Ch. Renner , G. Aeppli , B-G. Kim , Yeong-Ah Soh , S. -W. Cheong

Natural abundance, impressive chemical characteristics and economic feasibility have rekindled the appeal for rechargeable sodium (Na) batteries as a practical solution for the growing energy demand, environmental sustainability and energy…

Describing Li-ion battery positive electrodes in terms of distinct transition metal or oxygen redox regimes can lead to confusion in understanding metal-ligand hybridisation, oxygen dimerisation, and degradation. There is a pressing need to…

Electrocatalysts based on transition metal sulfides are drawing accelerating concerns in renewable energy research because of their intrinsically excellent activities towards both hydrogen evolution reaction and oxygen evolution reaction.…

MXenes, a family of layered transition metal carbides and nitrides, have shown great promise for use in emerging electrochemical energy storage devices, including batteries and supercapacitors. MXene surfaces are terminated by mixed -O, -F…

Materials Science · Physics 2018-07-05 Nuala M. Caffrey