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Spin crossover is expected to enrich unusual physical states in various types of condensed matter. Through inelastic neutron scattering, we study the spin-state excitations in the canonical and advanced platform, LaCoO$_3$, and reveal that…

Strongly Correlated Electrons · Physics 2018-08-20 K. Tomiyasu , T. Nomura , Y. Kobayashi , S. Ishihara , S. Ohira-Kawamura , M. Kofu

We carried out inelastic neutron scattering to study the spin-orbital (SO) exciton in a single crystal sample of CoTiO$_3$ as a function of temperature. CoTiO$_3$ is a honeycomb magnet with dominant XY-type magnetic interaction and an…

Strongly Correlated Electrons · Physics 2020-10-14 Bo Yuan , M. B. Stone , Guo-Jiun Shu , F. C. Chou , Xin Rao , J. P. Clancy , Young-June Kim

The magnetic, electric and thermal properties of the ($Ln_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ perovskites ($Ln$~=~Pr, Nd) were investigated down to very low temperatures. The main attention was given to a peculiar metal-insulator…

Strongly Correlated Electrons · Physics 2015-05-18 J. Hejtmánek , E. Šantavá , K. Knížek , M. Maryško , Z. Jirák T. Naito , H. Sasaki , H. Fujishiro

We present an extensive investigation (magnetic, electric and thermal measurements and X-ray absorption spectroscopy) of the Pr0.5Ca0.5CoO3 and (Pr1-yYy)0.7Ca0.3CoO3 (y=0.0625-0.15) perovskites, in which a peculiar metal-insulator (M-I)…

Materials Science · Physics 2015-06-12 J. Hejtmanek , Z. Jirak , O. Kaman , K. Knizek , E. Santava , K. Nitta , T. Naito , H. Fujishiro

The ground state properties of the pure perovskite compounds PrMnO$_3$ and NdMnO$_3$ were investigated by magnetization, magnetic AC susceptibility and specific heat measurements. A strongly anisotropic behavior has been detected for…

Condensed Matter · Physics 2007-05-23 J. Hemberger , M. Brando , R. Wehn , V. Yu. Ivanov , A. A. Mukhin , A. M. Balbashov , A. Loidl

We study ferromagnetic ordering and microscopic inhomogeneity in tensile strained LaCoO$_3$ using numerical simulations. We argue that both phenomena originate from effective superexchange interactions between atoms in the high-spin (HS)…

Strongly Correlated Electrons · Physics 2020-06-03 Andrii Sotnikov , Kyo-Hoon Ahn , Jan Kuneš

One- and multi-phonon excitations of the single crystalline LaCoO3 were studied using Raman spectroscopy in the temperature region of 5 K - 300 K. First-order Raman spectra show a larger number of phonon modes than allowed for the…

Strongly Correlated Electrons · Physics 2022-05-31 V. Gnezdilov , K. -Y. Choi , Yu. Pashkevich , P. Lemmens , S. Shiryaev , G. Bychkov , S. Barilo , V. Fomin , A. V. Yeremenko

The spin transition in LaCoO$_3$ has been investigated within the density-functional theory + dynamical mean-field theory formalism using continuous time quantum Monte Carlo. Calculations on the experimental rhombohedral atomic structure…

Strongly Correlated Electrons · Physics 2015-01-15 M. Karolak , M. Izquierdo , S. L. Molodtsov , A. I. Lichtenstein

LaCoO3 thin films grown under epitaxial tensile strain exhibit a robust ferromagnetic insulating state that is absent in the bulk. Despite many studies, both experimental and computational, the microscopic origin of this phenomenon is not…

Materials Science · Physics 2026-04-08 Ali Barooni , Murod Mirzhalilov , Mohit Randeria , Patrick M. Woodward , Maryam Ghazisaeidi

We present a comprehensive ellipsometric study of an untwinned, nearly stoichiometric LaMnO_3 crystal in the spectral range 1.2-6.0 eV at temperatures 20 K < T < 300 K. The complex dielectric response along the b and c axes of the Pbnm…

Strongly Correlated Electrons · Physics 2015-05-13 N. N. Kovaleva , Andrzej M. Oles , A. M. Balbashov , A. Maljuk , D. N. Argyriou , G. Khaliullin , B. Keimer

Perovskite oxide interfaces have attracted tremendous research interest for their fundamental physics and promising all-oxide electronics applications. Here, based on first-principles calculations, we propose a novel surface La interstitial…

Materials Science · Physics 2017-12-06 Jun Zhou , Ming Yang , Yuan Ping Feng , Andrivo Rusydi

The samples LaCoO3 with dilute substitutions on cobalt sites have been studied using the resistivity, thermopower and magnetic susceptibility measurements over the temperature range up to ~900 K. The Co-site substitution does not affect the…

Materials Science · Physics 2010-07-30 J. Hejtmanek , Z. Jirak , K. Knizek , M. Marysko , M. Veverka , C. Autret

We demonstrate efficient intrinsic spin-to-charge current conversion in a two-dimensional electron gas using an all-epitaxial single-crystal heterostructure of LaSrMnO3/ LaAlO3 (LAO)/ SrTiO3 (STO), which can suppress spin scattering and…

Materials Science · Physics 2020-01-22 Shinobu Ohya , Daisei Araki , Le Duc Anh , Shingo Kaneta , Munetoshi Seki , Hitoshi Tabata , Masaaki Tanaka

Interplay of spin, charge, orbital and lattice degrees of freedom in oxide heterostructures results in a plethora of fascinating properties, which can be exploited in new generations of electronic devices with enhanced functionalities. The…

Recently, the perovskite BiCoO$_3$ has been shown experimentally to be isostructural with PbTiO$_3$, while simultaneously the $d^6$ Co$^{3+}$ ion has a high spin ground state with $C$-type antiferromagnetic ordering. Using hybrid density…

Materials Science · Physics 2016-05-04 Leigh Weston , Xiangyuan Cui , Simon P. Ringer , Catherine Stampfl

Interfaces between correlated complex oxides are promising avenues to realize new forms of magnetism that arise as a result of charge transfer, proximity effects and locally broken symmetries. We report upon the discovery of a non-collinear…

We probe the spectrum of elementary excitations in SrIrO$_3$ by using heterostructured [(SrIrO$_3$)$_m$/(SrTiO$_3$)$_l$] samples to approach the bulk limit. Our resonant inelastic x-ray scattering (RIXS) measurements at the Ir $L_3$-edge…

Transport and magnetic measurements and structural and NMR studies have been carried out on (Pr1-yR'y)1-xAxCoO3 {R'=(rare earth elements and Y); A=(Ca, Ba and Sr)} at ambient pressure or under high pressure. The system exhibits a phase…

We sought the origin of the metal-insulator transition in Sr2-xLaxCoO4, using electron-correlation corrected density functional calculations. Our results show that Sr2CoO4 is in an intermediate-spin (IS) state and a strong Co4+ 3d-O 2p…

Strongly Correlated Electrons · Physics 2015-06-11 Hua Wu

By performing resonant inelastic x-ray scattering (RIXS) measurements at the Ir $\mathit{L_{\mathrm{3}}}$ edge, we have investigated the low-energy elementary excitations in a series of double perovskite iridate single crystals,…

Strongly Correlated Electrons · Physics 2022-05-19 Wentao Jin , Sae Hwan Chun , Jungho Kim , Diego Casa , Jacob P. C. Ruff , C. J. Won , K. D. Lee , N. Hur , Young-June Kim