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We report on the magnetic, resistive, and structural studies of perovskite La$_{1/3}$Sr$_{2/3}$CoO$_{3-\delta}$. By using the relation of synthesis temperature and oxygen partial pressure to oxygen stoichiometry obtained from…

Materials Science · Physics 2009-11-11 S. Kolesnik , B. Dabrowski , J. Mais , M. Majjiga , O Chmaissem , A. Baszczuk , J. D. Jorgensen

Calculations employing the local density approximation combined with static and dynamical mean-field theories (LDA+U and LDA+DMFT) indicate that the metal-insulator transition observed at 32 GPa in paramagnetic LaMnO3 at room temperature is…

Strongly Correlated Electrons · Physics 2007-05-23 A. Yamasaki , M. Feldbacher , Y. -F. Yang , O. K. Andersen , K. Held

We study the structural, magnetic, transport and electronic properties of LaCoO$_3$ with Sr/Nb co-substitution, i.e., La$_{(1-2x)}$Sr$_{2x}$Co$_{(1-x)}$Nb$_{x}$O$_3$ using x-ray and neutron diffraction, dc and ac-magnetization, neutron…

Strongly Correlated Electrons · Physics 2020-08-19 Rishabh Shukla , Anil Jain , M. Miryala , M. Murakami , K. Ueno , S. M. Yusuf , R. S. Dhaka

Magnetic and transport properties of the perovskite-type $3d$ transition-metal oxide (La,Sr)MnO$_3$ are theoretically studied using the double-exchange model in infinite dimension. Magnetoresistance properties as well as the magnetic…

Condensed Matter · Physics 2009-10-28 Nobuo Furukawa

The material class of rare earth nickelates with high Ni$^{3+}$ oxidation state is generating continued interest due to the occurrence of a metal-insulator transition with charge order and the appearance of non-collinear magnetic phases…

Strongly Correlated Electrons · Physics 2018-01-11 H. Guo , Z. W. Li , L. Zhao , Z. Hu , C. F. Chang , C. -Y. Kuo , W. Schmidt , A. Piovano , T. W. Pi , O. Sobolev , D. I. Khomskii , L. H. Tjeng , A. C. Komarek

\lco{} is known for its two-step spin crossover as a function of temperature. Despite efforts spanning over half a century, the origin of this phenomenon is still debated, particularly regarding how the microscopic spin states are involved…

Strongly Correlated Electrons · Physics 2024-11-18 Akihiko Ikeda , Yasuhiro H. Matsuda , Keisuke Sato , Joji Nasu

For decades transition-metal oxides have generated a huge interest due to the multitude of physical phenomena they exhibit. In this class of materials, the rare-earth nickelates, $R$NiO$_3$, stand out for their rich phase diagram stemming…

Strongly Correlated Electrons · Physics 2023-09-18 Luca Binci , Michele Kotiuga , Iurii Timrov , Nicola Marzari

The non-stoichiometric double perovskite oxide La2Ni1.19Os0.81O6 was synthesized by solid state reaction and its crystal and magnetic structures were investigated by powder x-ray and neutron diffraction. La2Ni1.19Os0.81O6 crystallizes in…

Strongly Correlated Electrons · Physics 2018-05-16 Hai L. Feng , Manfred Reehuis , Peter Adler , Zhiwei Hu , Michael Nicklas , Andreas Hoser , Shih-Chang Weng , Claudia Felser , Martin Jansen

The electronic structure of epitaxial films on LaCoO3(LCO) has been studied within first principle electronic structure calculations. A spin state transition is found to take place as a function of lattice strain which freezes in the…

Strongly Correlated Electrons · Physics 2009-01-05 Kapil Gupta , Priya Mahadevan

The structural and magnetic properties of two mixed-valence cobaltites with formal population of 0.30 Co$^{4+}$ ions per f.u., (Pr$_{1-y}$Y$_{y}$)$_{0.7}$Ca$_{0.3}$CoO$_3$ ($y=0$ and 0.15), have been studied down to very low temperatures by…

Materials Science · Physics 2015-06-17 K. Knizek , J. Hejtmanek , M. Marysko , P. Novak , E. Santava , Z. Jirak , T. Naito , H. Fujishiro , C. R. dela Cruz

We study the two-step spin crossover in a double-layered elastic model based on transition metal complexes each taking high spin (HS) and low spin (LS) states. Here, only the simplest elastic interactions between adjacent molecules are…

Materials Science · Physics 2017-11-15 Daisuke Taniguchi , Jun Okabayashi , Chisa Hotta

Sr$_2$FeOsO$_6$ is an insulating double perovskite compound which undergoes antiferromagnetic transitions at 140 K ($T_{N1}$) and 67 K ($T_{N2}$). To study the underlying electronic and magnetic interactions giving rise to this behavior we…

Neutron powder diffraction measurements, combined with magnetization and resistivity data, have been carried out in the doped perovskite La$_{1-x}$Ca$_x$MnO$_3$ ($x=0.47$, 0.50, and 0.53) to elucidate the structural, magnetic, and…

Strongly Correlated Electrons · Physics 2009-10-31 Q. Huang , J. W. Lynn , R. W. Erwin , A. Santoro , D. C. Dender , V. N. Smolyaninova , K. Ghosh , R. L. Greene

Using density functional theory plus self-consistent Hubbard $U$ (DFT$+U_{sc}$) calculations, we have investigated the structural and electronic properties of the rare-earth cobaltites \textit{R}CoO$_3$ (\textit{R} = Pr -- Lu). Our…

Strongly Correlated Electrons · Physics 2016-07-27 M. Topsakal , C. Leighton , R. M. Wentzcovitch

In this work we explore the overall structural behaviour of the [(CH3)2NH2][Mn(HCOO)3] multiferroic compound across the temperature range where its ferroelectric transition takes place by means of calorimetry, thermal expansion measurements…

Emergent magnetic states at oxide interfaces arise from the interplay of charge transfer, orbital reconstruction, and dimensional confinement, offering a route to engineered correlated-electron behavior in nanoscale spintronic materials.…

We report an electric field driven destabilization of the insulating state in nominally pure LaMnO3 single crystal with a moderate field which leads to a resistive state transition below 300 K. The transition is between the insulating state…

Strongly Correlated Electrons · Physics 2015-06-12 Rajib Nath , A. K. Raychaudhuri , Ya. M. Mukovskii , Parthasarathi Mondal , Dipten Bhattacharya , P. Mandal

We propose a method of controlling the metal-insulator transition of one perovskite material at its interface with a another ferroelectric material based on first principle calculations. The operating principle is that the rotation of…

Materials Science · Physics 2016-03-11 Xu He , Kui-juan Jin , Chen Ge , Zhong-shui Ma , Guo-zhen Yang

We investigate lattice dynamics in LaCoO$_3$ using inelastic neutron and x-ray scattering over $T = 2\mbox{-}650\,\mathrm{K}$, spanning the spin-state crossover at $T_{1} \approx 100\,\mathrm{K}$ and the insulator--metal transition at…

A detailed electronic phase diagram of perovskite-type oxides Sr$_{1-x}$La$_x$FeO$_3$ $(0\leq x \leq 0.5)$ was established by synchrotron X-ray diffraction, magnetization, and transport measurements for polycrystalline samples synthesized…

Strongly Correlated Electrons · Physics 2022-09-15 Masaho Onose , Hidefumi Takahashi , Hajime Sagayama , Yuichi Yamasaki , Shintaro Ishiwata
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