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We study electron densities of eigenfunctions of atomic Schroedinger operators. We prove the existence of rho~'''(0), the third derivative of the spherically averaged atomic density rho~ at the nucleus. For eigenfunctions with corresponding…

Mathematical Physics · Physics 2015-06-26 Søren Fournais , Maria Hoffmann-Ostenhof , Thomas Østergaard Sørensen

We derive an upper estimate for electronic density $\rho_\Psi (x)$ in heavy atoms and molecules. While not sharp, on the distances $\gtrsim Z^{-1}$ from the nuclei it is still better than the known estimate $CZ^3$ ($Z$ is the total charge…

Mathematical Physics · Physics 2020-04-02 Victor Ivrii

We investigate properties of the spherically averaged atomic one-electron density rho~(r). For a rho~ which stems from a physical ground state we prove that rho~ > 0. We also give exponentially decreasing lower bounds to rho~ in the case…

A new formula that relates the electron density at the nucleus of atoms,rho(0,Z), and the atomic number,Z, is proposed. This formula,rho(0,Z)=a(Z-bZ^(0.5))^3, contains two unknown parameters (a,b) that are derived using a least square…

Chemical Physics · Physics 2015-10-27 Alireza Marefat Khah , Shant Shahbazian

Only one third of the nucleons in $^{208}$Pb occupy the saturation density area. Consequently nuclear observables related to average properties of nuclei, such as masses or radii, constrain the equation of state (EOS) not at saturation…

Nuclear Theory · Physics 2015-06-04 E. Khan , J. Margueron , I. Vidana

The motion of an electron in an image field and a blocking electric field is considered in semiclassical approximation. An exact analytical expression is found for the density of the energy spectrum of states. The dependence of spectral…

Mesoscale and Nanoscale Physics · Physics 2021-04-28 P. A. Golovinski , M. A. Preobrazhenskii , I. S. Surovtzev

Different kinds of averaging of the wavefunctions/densities of the two-electron atomic systems are investigated. Using the Pekeris-like method, the ground state wave functions $\Psi$ of the helium-like atoms with nucleus charge $1\leq…

Atomic Physics · Physics 2020-04-22 Evgeny Liverts , Rajmund Krivec

We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\ln Z+(E^{\TF}(\lambda)+{1/2}c^{\rm H})Z^2+o(Z^2)$ when…

Mathematical Physics · Physics 2011-06-17 Phan Thanh Nam , Fabian Portmann , Jan Philip Solovej

The strong Scott conjecture about the electron density at a distance 1/Z from an atomic nucleus of charge $Z$ and its generalization for molecules are proved. The density, suitably scaled, converges to an explicit limiting density as $Z \to…

Condensed Matter · Physics 2007-05-23 Alexei Iantchenko , Elliott H. Lieb , Heinz Siedentop

Spatial localization of the electrons of an atom or molecule is studied in models of non-relativistic matter coupled to quantized radiation. We give two definitions of the ionization threshold. One in terms of spectral data of cluster…

Mathematical Physics · Physics 2007-05-23 Marcel Griesemer

We consider a pseudorelativistic model of atoms and molecules, where the kinetic energy of the electrons is given by $\sqrt{p^2+m^2}-m$. In this model the eigenfunctions are generally not even bounded, however, we prove that the…

Mathematical Physics · Physics 2013-10-30 Søren Fournais , Thomas Østergaard Sørensen

We consider a gas of bosons interacting through a hard-sphere potential with radius $\frak{a}$ in the thermodynamic limit. We derive a simple upper bound for the ground state energy per particle at low density. Our bound captures the…

The non-relativistic interacting electron gas in an external field of positively charged massive cores is dealt with in the scheme of second quantization. Ladder operators that change between stationary states of contiguous energy…

Quantum Physics · Physics 2025-02-27 Miguel Lagos

Consider $N$ bosons in a finite box $\Lambda= [0,L]^3\subset \mathbf R^3$ interacting via a two-body smooth repulsive short range potential. We construct a variational state which gives the following upper bound on the ground state energy…

Mathematical Physics · Physics 2009-10-05 Horng-Tzer Yau , Jun Yin

The eigenfunctions of electronic Hamiltonians determine the stable structures and dynamics of molecules through the local distributions of their densities. In this paper an a priori upper bound for such local distributions of the densities…

Mathematical Physics · Physics 2023-11-14 Sohei Ashida

For a dilute system of non-relativistic bosons interacting through a positive, radial potential $v$ with scattering length $a$ we prove that the ground state energy density satisfies the bound $e(\rho) \geq 4\pi a \rho^2 (1- C \sqrt{\rho…

Mathematical Physics · Physics 2020-04-22 Birger Brietzke , Søren Fournais , Jan Philip Solovej

Consider $N$ bosons in a finite box $\Lambda= [0,L]^3\subset \bR^3$ interacting via a two-body nonnegative soft potential $V= \lambda \tilde V$ with $\tilde V$ fixed and $\lambda>0$ small. We will take the limit $L, N \to \infty$ by keeping…

Mathematical Physics · Physics 2009-11-13 Laszlo Erdos , Benjamin Schlein , Horng-Tzer Yau

The density dependence of the nuclear symmetry energy governs important aspects of very neutron rich systems such as heavy nuclei and their collisions, neutron stars and their mergers. Many analyses of experimental data have generated…

Nuclear Experiment · Physics 2018-05-29 W. G. Lynch , M. B. Tsang

Upper and lower bounds are derived for the ground-state energy of neutral atoms which for $Z\to\infty$ both involve the limits of exact Green's functions with one-body potentials. The limits of both bounds are shown to coincide with the…

Quantum Physics · Physics 2007-06-13 Edouard B. Manoukian , Jarin Osaklung

Differential cross sections for elastic scattering of photons have been measured for $^{40}$Ca at energies of 58 and 74 MeV and for $^{16}$O and $^4$He at 61 MeV, in the angular range from 45$^o$ to 150$^o$. Evidence is obtained that there…

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