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With expanding interest in graphene-based electronics, it is crucial that high quality graphene films be grown. Sublimation of Si from the 4H-SiC(0001) Si-terminated) surface in ultrahigh vacuum is a demonstrated method to produce epitaxial…

Materials Science · Physics 2009-11-11 J. Hass , C. A. Jeffrey , R. Feng , T. Li , X. Li , Z. Song , C. Berger , W. A. de Heer , P. N. First , E. H. Conrad

We report graphene films composed mostly of one or two layers of graphene grown by controlled carbon precipitation on the surface of polycrystalline Ni thin films during atmospheric chemical vapor deposition(CVD). Controlling both the…

The development of wafer-scale continuous single-crystal graphene layers is key in view of its prospective applications. To this end, here we pave the way for a graphene growth model in the framework of the Langmuir adsorption theory and…

Materials Science · Physics 2013-05-14 HoKwon Kim , Eduardo Saiz , Manish Chhowalla , Cecilia Mattevi

Graphene is formed on SiC(000-1) surfaces (the so-called C-face of the crystal) by annealing in vacuum, with the resulting films characterized by atomic force microscopy, Auger electron spectroscopy, scanning Auger microscopy and Raman…

Materials Science · Physics 2015-05-13 Luxmi , P. J. Fisher , N. Srivastava , R. M. Feenstra , Yugang Sun , J. Kedzierski , P. Healey , Gong Gu

The transfer-free synthesis of high-quality, large-area graphene on a given dielectric substrate, which is highly desirable for device applications, remains a significant challenge. In this paper, we report on a simple rapid thermal…

An atomic-scale study utilizing scanning tunneling microscopy (STM) in ultrahigh vacuum (UHV) is performed on large single crystalline graphene grains synthesized on Cu foil by a chemical vapor deposition (CVD) method. After thermal…

Mesoscale and Nanoscale Physics · Physics 2014-09-12 Jifa Tian , Helin Cao , Wei Wu , Qingkai Yu , Nathan P. Guisinger , Yong P. Chen

Here we theoretically show, by designing and manipulating spatially inhomogeneous, non-uniform conductivity patterns across a single flake of graphene, that this single-atom-layered material can serve as a "one-atom-thick" platform for…

Optics · Physics 2011-01-20 Ashkan Vakil , Nader Engheta

Graphene is at the centre of nanotechnology research. In order to fully exploit its outstanding properties, a mass production method is necessary. Two main routes are possible: large-scale growth or large-scale exfoliation. Here, we…

Graphene has emerged as a promising material for next-generation electronic and thermal devices owing to its exceptional charge transport and thermal conductivity. However, high-quality samples are predominantly obtained via mechanical…

The direct growth of high-quality, large single-crystalline domains of graphene on a dielectric substrate is of vital importance for applications in electronics and optoelectronics. Traditionally, graphene domains grown on dielectrics are…

In previous studies, it proved difficult to realize periodic graphene ripples with wavelengths of few nanometers. Here we show that one-dimensional periodic graphene ripples with wavelengths from 2 nm to tens of nanometers can be…

Mesoscale and Nanoscale Physics · Physics 2014-08-25 Ke-Ke Bai , Yu Zhou , Hong Zheng , Lan Meng , Hailin Peng , Zhongfan Liu , Jia-Cai Nie , Lin He

We demonstrate anisotropic etching of single-layer graphene by thermally-activated nickel nanoparticles. Using this technique, we obtain sub-10nm nanoribbons and other graphene nanostructures with edges aligned along a single…

Graphene is a mechanically robust 2D material promising for flexible optoelectronic applications. However, its electromagnetic properties under strain are experimentally poorly understood. Here we present the far-infrared transmission…

Mesoscale and Nanoscale Physics · Physics 2017-05-22 Manisha Chhikara , Iaroslav Gaponenko , Patrycja Paruch , Alexey. B. Kuzmenko

We have developed a novel method for crystalline hydrogenation of graphene on the nanoscale. Molecular hydrogen was physisorbed at 5 K onto pristine graphene islands grown on Cu(111) in ultrahigh vacuum. Field emission local to the tip of a…

Mesoscale and Nanoscale Physics · Physics 2017-06-06 S. J. Tjung , S. M. Hollen , G. A. Gambrel , N. M. Santagata , E. Johnston-Halperin , J. A. Gupta

Single-layer superconductors are ideal materials for fabricating superconducting nano devices. However, up to date, very few single-layer elemental superconductors have been predicted and especially no one has been successfully synthesized…

Materials Science · Physics 2019-08-06 Qinyan Gu , Dingyu Xing , Jian Sun

We experimentally investigated the properties of graphite layers produced by an easy and non-conventional method of repeatedly rubbing conventional random stacked graphite bulk against insulating and semiconductor substrates. The patterned…

Materials Science · Physics 2014-02-18 A. R. Mailian , G. Sh. Shmavonyan , M. R. Mailian

Topographic scanning tunneling microscopy (STM) images of epitaxial single layer graphene on the Rh(111) surface reveal that extended single crystalline graphene domains are produced without any defects on a large scale. High resolution…

Materials Science · Physics 2010-10-08 M. Fonin , M. Sicot , O. Zander , S. Bouvron , Ph. Leicht , U. Rüdiger , M. Weser , Yu. S. Dedkov , K. Horn

Applying time-dependent photoemission we unravel the graphene growth process on a metallic surface by chemical vapor deposition (CVD). Graphene CVD growth is in stark contrast to the standard growth process of two--dimensional films because…

Materials Science · Physics 2015-05-13 Alexander Grüneis , Kurt Kummer , Denis V. Vyalikh

Graphene layers were created on both C and Si faces of semi-insulating, on-axis, 4H- and 6H-SiC substrates. The process was performed under high vacuum (<10-4 mbar) in a commercial chemical vapor deposition SiC reactor. A method for H2…

We demonstrate a method by which few-layer graphene samples can be etched along crystallographic axes by thermally activated metallic nanoparticles. The technique results in long (>1 micron) crystallographic edges etched through to the…

Materials Science · Physics 2009-05-08 Sujit S. Datta , Douglas R. Strachan , Samuel M. Khamis , A. T. Charlie Johnson
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