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The quantum dynamics of a system of Rb atoms, modeled by a V-type three-level system interacting with intense probe and pump pulses, are studied. The time-delay-dependent transient-absorption spectrum of an intense probe pulse is thus…

Atomic Physics · Physics 2018-02-14 Vadim Becquet , Stefano M. Cavaletto

The temporal evolution of electromagnetically induced transparency (EIT) and absorption (EIA) coherence resonances in pump-probe spectroscopy of degenerate two-level atomic transition is studied for light intensities below saturation.…

Quantum Physics · Physics 2009-11-07 P. Valente , H. Failache , A. Lezama

In this work we investigate the effects of the environment on the X-ray photoelectron spectra of hydrogen chloride and the chloride ions adsorbed on ice surfaces, as well as of chloride ions in water droplets. In our approach, we combine a…

Chemical Physics · Physics 2023-09-18 Richard A. Opoku , Céline Toubin , André Severo Pereira Gomes

Radiative transfer in hydrogen lines in supernova remnant (SNR) shock waves is studied taking into account the population of the hydrogen atom 2s-state. Measurements of Balmer line emission, especially of H~$\alpha$, are often relied upon…

High Energy Astrophysical Phenomena · Physics 2019-03-27 Jiro Shimoda , J. Martin Laming

X-ray absorption spectroscopy at the L-edge probes transitions of 2p-electrons into unoccupied d-states. Applied to transition metal atoms, this experimental technique can provide valuable information about the electronic structure of…

Materials Science · Physics 2021-02-03 Johann Lueder

Intersystem crossings between singlet and triplet states represent a crucial relaxation pathway in photochemical processes. Herein, we probe the intersystem crossing in hexafluoro-acetylacetone with ultrafast X-ray transient absorption…

We measure the photoionization cross-section of vibrationally excited levels in the S2 state of azulene by femtosecond pump-probe spectroscopy. At the wavelengths studied (349-265 nm in the pump) the transient signals exhibit two distinct…

X-ray absorption spectroscopy is a well established tool for obtaining information about orbital and spin degrees of freedom in transition metal- and rare earth-compounds. For this purpose usually the dipole transitions of the L- (2p to 3d)…

Strongly Correlated Electrons · Physics 2014-02-21 P. Hansmann , M. W. Haverkort , A. Toschi , G. Sangiovanni , F. Rodolakis , J. P. Rueff , M. Marsi , K. Held

We studied dissociation reactions of electron impact on water vapor for several fragment species at optical and near ultraviolet wavelengths (200 - 850 nm). The resulting spectrum is dominated by the Hydrogen Balmer series, by the OH (A…

Earth and Planetary Astrophysics · Physics 2020-01-08 D. Bodewits , J. Országh , J. Noonan , M. Ďurian , Š. Matejčík

We investigate the limit of X-ray detection at room temperature on rare-earth molecular films using lanthanum and a pyridine-based dicarboxamide organic linker as a model system. Synchrotron X-ray scanning tunneling microscopy is used to…

Details of simultaneous photometric and spectroscopic observations of the optical counterpart of the `supersoft' X-ray source 1E 0035.4-7230 (SMC 13) are presented. Although the spectrum is dominated by emission lines of He II, the Balmer…

Astrophysics · Physics 2007-05-23 David Crampton , J. B. Hutchings , A. P. Cowley , P. C. Schmidtke

We show that time-resolved x-ray scattering from molecules prepared in a superposition of electronic states moving through an avoided crossing has new features not found in diffraction from the corresponding classical mixed state.…

The reported ''dissociation times'' for the Br$_{2}$ C ($^{1}\Pi_{u}$ $1_{u}$) state by various measurement methods differ widely across the literature (30 to 340 fs). We consider this issue by investigating attosecond extreme ultraviolet…

Chemical Physics · Physics 2025-12-09 John E. Beetar , Jen-Hao Ou , Yuki Kobayashi , Stephen R. Leone

We report results of a theoretical study on an adsorbate induced surface reconstruction. Hydrogen adsorption on a W(100) surface causes a switching transition in the symmetry of the displacements of the W atoms within the ordered c(2x2)…

Condensed Matter · Physics 2009-10-22 Kari Kankaala , Tapio Ala-Nissila , See-Chen Ying

We have observed the soft X-ray transient XTE J0421+56 in quiescence with XMM-Newton. The observed spectrum is highly unusual being dominated by a broad feature at 6.5 keV and can be modeled by a strongly absorbed continuum. The spectra of…

Astrophysics · Physics 2007-05-23 L. Boirin , A. N. Parmar , D. Lumb , M. Orlandini , N. Schartel

We study the core hole-electron correlation in coherently coupled molecules by energy dispersive near edge X-ray absorption fine-structure spectroscopy. In a transient phase, which exists during the transition between two bulk arrangements,…

Materials Science · Physics 2013-12-03 M. Scholz , F. Holch , C. Sauer , M. Wiessner , A. Schöll , F. Reinert

Time-resolved optical spectroscopy (TR-OS) has emerged as a fundamental spectroscopic tool for probing complex materials, to both investigate ground-state-related properties and trigger phase transitions among different states with peculiar…

Vacuum-ultraviolet (VUV) photoabsorption spectra were recorded of the $A\,{}^2\Sigma^+(v'=0)\leftarrow{}X\,{}^2\Pi(v''=0)$, $D\,{}^2\Sigma^-(v'=0)\leftarrow{}X\,{}^2\Pi(v''=0)$ and $D\,{}^2\Sigma^-(v'=1)\leftarrow{}X\,{}^2\Pi(v''=0)$ bands…

Motivated by recent experiments on radiative recombination of two-dimensional electrons in acceptor doped GaAs-AlGaAs heterojunctions as well as the success of a harmonic solid model in describing tunneling between two-dimensional electron…

Strongly Correlated Electrons · Physics 2016-08-31 S. Kodiyalam , H. A. Fertig , S. Das Sarma

"Does God play dice with the Universe?" The natural width of excited hydrogen atoms are found using the Bohr's model of this atom and de Broglie's ideas. The mean life time of the excited states is a characteristic only of a statistical…

Atomic Physics · Physics 2007-05-23 Pavel S. Kamenov