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We systematically investigate the structural, electronic and magnetic properties of Mn$_n$ clusters ($n =$ 2$-$20) within the {\it ab-initio} pseudopotential plane wave method using generalized gradient approximation for the…

Atomic and Molecular Clusters · Physics 2008-06-12 Mukul Kabir , Abhijit Mookerjee , D. G. Kanhere

We have studied the magnetic properties of free cobalt clusters in two semi-independent Stern-Gerlach deflection experiments at temperatures between 60 and 307 K. We find that clusters consisting of 13 to 200 cobalt atoms exhibit behavior…

Atomic and Molecular Clusters · Physics 2015-06-26 F. W. Payne , Wei Jiang , J. W. Emmert , Jun Deng , L. A. Bloomfield

We present the results of the density functional theory study of Co_n Mo_m nanoclusters with n+m=x and 2<=x<=6 atoms on the all-electron level using the generalized gradient approximation. The discussion of the properties of the pure cobalt…

Mesoscale and Nanoscale Physics · Physics 2015-04-29 Simon Liebing , Claudia Martin , Kai Trepte , Jens Kortus

Using first-principles density functional theory based calculations, we analyze the structural stability of small clusters of 3$d$ late transition metals. We consider the relative stability of the two structures - layer-like structure with…

Mesoscale and Nanoscale Physics · Physics 2011-08-15 Soumendu Datta , Mukul Kabir , Tanusri Saha-Dasgupta

Effects of alloying on the electronic and magnetic properties of Mn$_{x}$Co$_{y}$ ($x+y$=$n$=2-5; $x$=0-$n$) and Mn$_2$Co$_{11}$ nanoalloy clusters are investigated using the density functional theory (DFT). Unlike the bulk alloy, the…

Atomic and Molecular Clusters · Physics 2008-07-24 Shreemoyee Ganguly , Mukul Kabir , Soumendu Datta , Biplab Sanyal , Abhijit Mookerjee

Magnetic properties and bonding analyses of perovskite structure Co$_{4}$N nitride have been investigated within density functional theory using both pseudo potential and all electron methods. In the same time, the structural and magnetic…

Materials Science · Physics 2015-08-11 Abdesalem Houari , Samir F. Matar , Mohamed A. Belkhir

The structural, electronic and magnetic properties of small ${\rm Fe}_m {\rm Rh}_n$ clusters having $N = m+n \leq 8$ atoms are studied in the framework of a generalized-gradient approximation to density-functional theory. The correlation…

Atomic and Molecular Clusters · Physics 2011-10-13 Junais Habeeb Mokkath , G. M. Pastor

Recent experiments on isolated Co clusters have shown huge orbital magnetic moments in comparison with their bulk and surface counterparts. These clusters hence provide the unique possibility to study the evolution of the orbital magnetic…

Our recent studies on Co-clusters embedded in various matrices reveal that the co-deposition technique (simultaneous deposition of two beams : one for the pre-formed clusters and one for the matrix atoms) is a powerful tool to prepare…

Condensed Matter · Physics 2009-10-31 M. Jamet , V. Dupuis , P. Melinon , A. Perez , W. Wernsdorfer , A. Traverse , B. Baguenard

From magnetic deflection experiments on isolated Co doped Nb clusters we made the interesting observation of some clusters being magnetic, while others appear to be non-magnetic. There are in principle two explanations for this behavior.…

Strongly Correlated Electrons · Physics 2018-05-02 A. Diaz-Bachs , L. Peters , R. Logemann , V. Chernyy , J. M. Bakker , M. I. Katsnelson , A. Kirilyuk

The ground-state electronic, structural, and magnetic properties of small silver clusters, Ag$_n$ (2$\le$n$\le$22), have been studied using a linear combination of atomic Gaussian-type orbitals within the density functional theory. The…

Atomic and Molecular Clusters · Physics 2009-11-11 M. Pereiro , D. Baldomir , J. E. Arias

Spin and orbital magnetic moments of cationic iron, cobalt, and nickel clusters have been determined from x-ray magnetic circular dichroism spectroscopy. In the size regime of $n = 10 - 15$ atoms, these clusters show strong ferromagnetism…

Atomic and Molecular Clusters · Physics 2014-12-01 A. Langenberg , K. Hirsch , A. Lawicki , V. Zamudio-Bayer , M. Niemeyer , P. Chmiela , B. Langbehn , A. Terasaki , B. v. Issendorff , J. T. Lau

The structure and magnetic properties of Co clusters, comprising from 26 to 2700 atoms, self-organized or not on the graphene/Ir(111) moir\'e, were studied in situ with the help of scanning tunneling microscopy and X-ray magnetic circular…

Magnetic properties of two and three-dimensional clusters of quantum dots are studied with exact diagonalization of a generalized Hubbard model. We study the weak coupling limit, where the electrons interact only within a quantum dot and…

Strongly Correlated Electrons · Physics 2009-11-13 J. -P. Nikkarila , M. Koskinen , M. Manninen

The structural and magnetic properties of Co$_{18-m}$Cu$_m$ ($0\leq m\leq 18$) clusters are investigated with a genetic algorithm and a $spd$-band model Hamiltonian in the unrestricted Hartree-Hock approximation respectively. In general, Cu…

Atomic and Molecular Clusters · Physics 2007-05-23 Jinlan Wang , Guanghou Wang , Xiaoshuang Chen , Wei Lu , Jijun Zhao

The structural, electronic and magnetic properties of small ${\rm Fe}_m {\rm Rh}_n$ clusters having $N = m+n \leq 8$ atoms are studied in the framework of a generalized-gradient approximation to density-functional theory. For $N = m+n \leq…

Materials Science · Physics 2012-01-31 Junais Habeeb Mokkath , G. M. Pastor

In many ostensibly crystalline materials, unit-cell-based descriptions do not always capture the complete physics of the system due to disruption in long-range order. In the series of cobalt hydroxides studied here,…

Surprising enhancement of the magnetic moments recently observed in dilute Co-Mn alloy clusters is explained using ab initio electronic structure calculations. The calculated magnetic moments generally agree with the reported experimental…

Atomic and Molecular Clusters · Physics 2009-08-18 M. Pereiro , D. Baldomir , J. E. Arias

We report the structural and magnetic properties of a new class of cobaltates with the chemical formula (BaSr)4-xLa2xCo4O15 (x = 0, 0.5 and 1). These compounds crystallize in a hexagonal structure in which cobalt ions are distributed among…

Strongly Correlated Electrons · Physics 2015-06-11 V. O. Garlea , R. Jin , E. Garlea , G. Ehlers , E. Mamontov , D. B. Myers , F. Xie , R. Custelcean

The magnets are typically classified into Stoner and Heisenberg type, depending on the itinerant or localized nature of the constituent magnetic moments. In this work, we investigate theoretically the behaviour of the magnetic moments of…

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