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We have performed a resonant x-ray scattering study at the Co pre-K edge on a single crystal of Ca3Co2O6. The measurements reveal an abrupt transition to a magnetically ordered state immediately below T_N = 25 K, with a magnetic correlation…

Other Condensed Matter · Physics 2008-05-10 S. Agrestini , C. Mazzoli , A. Bombardi , M. R. Lees

We report 23Na NMR studies of the polycrystalline samples of bilayer hydrated cobalt oxides Na0.35CoO2-1.3H2O with the superconducting transition temperatures Tc < 1.8 and ~ 4.5 K. The magnitude of the 23Na nuclear spin-lattice relaxation…

Superconductivity · Physics 2007-05-23 H. Ohta , Y. Itoh , C. Michioka , K. Yoshimura

We report the magnetic properties of the double perovskites SrLaCuSbO$_6$ (SLCSO) and SrLaCuNbO$_6$ (SLCNO). The temperature dependence of the magnetic susceptibilities of both compounds shows a broad maximum characteristic of an…

Strongly Correlated Electrons · Physics 2022-03-02 Masari Watanabe , Nobuyuki Kurita , Hidekazu Tanaka , Wataru Ueno , Kazuki Matsui , Takayuki Goto , Masato Hagihala

Room-temperature ferrimagnetism was discovered for the anti-site-disordered perovskite Ca2MnOsO6 with Tc = 305 K. Ca2MnOsO6 crystallizes into an orthorhombic structure with a space group of Pnma, in which Mn and Os share the…

The pseudo-one dimensional brannerite type compound CoV2O6 has been studied by magnetisation and heat capacity measurements in the temperature range 1.8 < T < 300 K and in applied fields of up to 9 T. Our measurements show an unusual…

Strongly Correlated Electrons · Physics 2008-04-21 Simon A. J. Kimber , Dimitri N. Argyriou , J. Paul Attfield

We present an inelastic neutron scattering study of the low energy crystal-field excitations in the lightly doped cobalt perovskite La_0.998Sr_0.002CoO_3. In contrast to the parent compound LaCoO_3 an inelastic peak at energy transfer ~0.75…

Strongly Correlated Electrons · Physics 2008-02-22 A. Podlesnyak , K. Conder , E. Pomjakushina , A. Mirmelstein , P. Allenspach , D. I. Khomskii

In this paper we have studied, by means of high-resolution neutron powder diffraction and magnetic susceptibility, the structural and magnetic features of selected samples of the HoBaCo2O5+delta layered cobaltite in the low oxygen content…

Materials Science · Physics 2009-11-13 Lorenzo Malavasi , Yuri Diaz-Fernandez , M. Cristina Mozzati , Clemens Ritter

High quality epitaxial thin films of LaBiMn4/3Co2/3O6 perovskite were fabricated on (001)-oriented SrTiO3 and LaAlO3 substrates by the pulsed laser deposition technique. Magnetization measurements reveal a strong magnetic anisotropy and a…

Materials Science · Physics 2008-02-18 R. Ranjith , Asish K. Kundu , M. Filippi , B. Kundys , W. Prellier , B. Raveau , J. Laverdiere , M. P. Singh , S. Jandl

Na$_{4-\delta}$NiTeO$_{6}$ is a rare example in the transition-metal tellurate family of realizing an $S$ = 1 spin-chain structure. By performing neutron powder diffraction measurements, the ground-state magnetic structure of…

Strongly Correlated Electrons · Physics 2022-08-04 Cheng Su , Xu-Tao Zeng , Yi Li , Nvsen Ma , Zhengwang Lin , Chuandi Zhang , Chin-Wei Wang , Ziyu Chen , Xingye Lu , Wei Li , Xian-Lei Sheng , Wentao Jin

Perovskite iridates of 6H hexagonal structure present a plethora of possibilities in terms of the variety of ground states resulting from a competition between spin-orbit coupling (SOC), hopping, noncubic crystal field ($\Delta_{CFE}^{NC}$)…

Strongly Correlated Electrons · Physics 2019-08-15 Md Salman Khan , Abhisek Bandyopadhyay , Abhishek Nag , Vinod Kumar , A. V. Mahajan , Sugata Ray

We study magnetic, transport and thermal properties of Cobalt carbide nanocomposite with a mixture of Co2C and Co3C phases in 1:1 ratio, with an average particle diameter of 40$\pm 15$ nm. We show that the behavior of the nanocomposite is…

Strongly Correlated Electrons · Physics 2020-03-31 Nirmal Roy , Arpita Sen , Prasenjit Sen , S. S. Banerjee

The possibility to segregate cobalt and iron in a single perovskite, at a nanoscale in the form of layers has been investigated, using sol gel technic synthesis. Quite remarkably, it is shown that such a nanoscale ordering, which can only…

We report polarized- and unpolarized-neutron scattering measurements of magnetic excitations in single-crystal Na0.75CoO2. The data confirm ferromagnetic correlations within the cobalt-layers and reveal antiferromagnetic correlations…

Strongly Correlated Electrons · Physics 2007-05-23 L. M. Helme , A. T. Boothroyd , R. Coldea , D. Prabhakaran , D. A. Tennant , A. Hiess , J. Kulda

We present magnetization and specific heat data of a La5/3Sr1/3NiO4 single crystal in high magnetic fields. From the charge and spin stripe ordering temperatures, as well as a magnetic low temperature transition, we have constructed the…

Strongly Correlated Electrons · Physics 2014-03-13 R. Klingeler , B. Büchner , S-W. Cheong , M. Huecker

The honeycomb cobaltate Na$_2$Co$_2$TeO$_6$ has recently been proposed as a candidate material for hosting field-induced quantum spin liquid (QSL) behavior. Here, we present a comprehensive thermodynamic study of its low-temperature,…

We report the magnetism and transport measurements of CaCo$_2$As$_2$ and Ca$_{0.9}$Sr$_{0.1}$Co$_2$As$_2$ single crystals. Antiferromagnetic transition was observed at about 70 K and 90 K for CaCo$_2$As$_2$ and…

Strongly Correlated Electrons · Physics 2012-06-15 J. J. Ying , Y. J. Yan , A. F. Wang , Z. J. Xiang , P. Cheng , G. J. Ye , X. H. Chen

Through a combination of neutron diffraction and Landau theory we describe the spin ordering in the ground state of the quadruple perovskite manganite CaMn7O12 - a magnetic multiferroic supporting an incommensurate orbital density wave that…

Strongly Correlated Electrons · Physics 2016-05-25 R. D. Johnson , D. D. Khalyavin , P. Manuel , A. Bombardi , C. Martin , L. C. Chapon , P. G. Radaelli

The observation of giant coercivity exceeding 20 kOe at low temperatures in several transition-metal-based compounds has attracted significant attention from a fundamental perspective. This research is also relevant to developing…

Materials Science · Physics 2023-09-27 Jiro Kitagawa , Himawari Nomura , Terukazu Nishizaki

We report the crystal structure, magnetization and neutron scattering measurements on the double perovskite Ba$_2$YOsO$_6$. The $Fm\overline{3}m$ space group is found both at 290~K and 3.5~K with cell constants $a_0 = 8.3541(4)$~{\AA} and…

Pr-containing perovskite cobaltites exhibit unusual valence transitions, coupled to coincident structural, spin-state, and metal-insulator transitions. Heteroepitaxial strain was recently used to control these phenomena in the model…

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