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We have grown single crystals of Na$_x$Ca$_y$CoO$_2$ and determined their superstructures as a function of composition using neutron and x-ray diffraction. Inclusion of Ca$^{2+}$ stabilises a single superstructure across a wide range of…

Strongly Correlated Electrons · Physics 2015-05-12 D. G. Porter , M. Roger , M. J. Gutmann , S. Uthayakumar , D. Prabhakaran , A. T. Boothroyd , M. S. Pandiyan , J. P. Goff

High quality single crystals of BaFe$_{12}$O$_{19}$ were grown using the floating zone technique in flowing oxygen pressurized to 100 atm. Single crystal neutron diffraction was used to determine the nuclear and magnetic structure of…

Materials Science · Physics 2015-06-25 H. B. Cao , Z. Y. Zhao , M. Lee , E. S. Choi , M. A. McGuire , B. C. Sales , H. D. Zhou , J. -Q. Yan , D. G. Mandrus

CuFeO$_2$ single crystals up to 50 mm in length and up to 10 mm in diameter were grown by the optical floating-zone method. Stoichiometric polycrystalline rods with a diameter of 6-12 mm were used as feed materials to produce crystals of…

Materials Science · Physics 2020-01-07 Nora Wolff , Tobias Schwaigert , Dietmar Siche , Darrell G. Schlom , Detlef Klimm

Cd-doped La(O,F)BiS2 single crystals were grown using a CsCl/KCl flux. The grown crystals have a plate-like shape with ~1-2 mm square size in a well-developed ab-plane. The Cd doping in the crystals was successfully characterized by single…

Superconductivity · Physics 2017-06-16 Masanori Nagao , Masashi Tanaka , Satoshi Watauchi , Yoshihiko Takano , Isao Tanaka

We report the growth of single crystals of SrCu2As2, SrCu2Sb2, SrCu2(As{0.84}Sb{0.16})2 and BaCu2Sb2 using the self-flux technique and their structural, magnetic, thermal and transport properties that were investigated by powder x-ray…

Superconductivity · Physics 2012-09-11 V. K. Anand , P. Kanchana Perera , Abhishek Pandey , R. J. Goetsch , A. Kreyssig , D. C. Johnston

Millimeter sized single crystals of CaFe$_{1-x}$Co$_x$AsF were grown using a self-flux method. It is found that high-quality single crystals can be grown from three approaches with different initial raw materials. The chemical compositions…

Superconductivity · Physics 2016-08-09 Yonghui Ma , Kangkang Hu , Qiucheng Ji , Bo Gao , Hui Zhang , Gang Mu , Fuqiang Huang , Xiaoming Xie

To investigate the origin of the enhanced Tc ({\approx} 110 K) of the trilayer cuprate superconductor Bi2Sr2Ca2Cu3O10+{\delta} (Bi-2223), its underdoped single crystals are a critical requirement. Here, we demonstrate the first successful…

Millimeter-sized single crystals of LaFeAsO, LaFeAsO1-xFx, and LaFe1-xCoxAsO were grown in NaAs flux at ambient pressure. The detailed growth procedure and crystal characterizations are reported. The as-grown crystals have typical…

F-substituted NdOBiS2 superconducting single crystals were grown using CsCl/KCl flux. This is the first example of the single-crystal growth of a BiS2-based superconductor. The obtained single crystals had a plate-like shape with a size of…

[Ca$_2$CoO$_3$]$_{0.62}$[CoO$_2$], a two dimensional misfit metallic compound, is famous for its rich phases accessed by temperature, $i.e.$ high temperature spin-state transition, metal-insulator transition (MIT) at intermediate…

We report infrared spectroscopic properties of the strongly correlated layered cobalt oxide [BiBa$_{0.66}$K$_{0.36}$O$_2$]CoO$_2$. These measurements performed on single crystals allow us to determine the optical conductivity as a function…

Strongly Correlated Electrons · Physics 2013-01-15 P. Limelette , V. Ta Phuoc , F. Gervais , R. Fresard

Single crystals of Cu$_{13}$Ba were successfully grown out of Ba-Cu self flux. Temperature dependent magnetization, $M(T)$, electrical resistivity, $\rho(T)$, and specific heat, $C_p(T)$, data are reported. Isothermal magnetization…

Materials Science · Physics 2014-01-28 A. Jesche , S. L. Bud'ko , P. C. Canfield

The thermal conductivity \kappa is measured in a series of La_{2-x}Sr_{x}CuO_{4} (x = 0 - 0.22) single crystals down to 90 mK to elucidate the evolution of the residual electronic thermal conductivity \kappa_{res}, which probes the extended…

Superconductivity · Physics 2009-11-07 J. Takeya , Yoichi Ando , Seiki Komiya , X. F. Sun

By using high pressure and high temperature (3.7 GPa, 1120 $^{\circ}$C) synthesis technique, we have grown (Cu,C)Ba$_2$Ca$_3$Cu$_4$O$_{11+\delta}$ single crystals. X-ray diffraction, scanning electron microscopy, resistivity and…

Superconductivity · Physics 2022-01-05 Chengping He , Xue Ming , Jin Si , Xiyu Zhu , Jinhua Wang , Hai-Hu Wen

We report on single-crystal growths of the SrTb$_2$O$_4$ compound by a super-necking technique with a laser-floating-zone furnace and study the stoichiometry, growth mode, and structural and magnetic properties by scanning electronic…

Single-crystalline whiskers of thermoelectric cobalt oxide, NaxCoO2, have been grown by an unconventional method from potassium-containing compositions, and their transport properties, and chemical compositions were determined. The growth…

Strongly Correlated Electrons · Physics 2009-11-10 G. Peleckis , T. Motohashi , M. Karppinen , H. Yamauchi

We investigated the in-plane anisotropy on the resistivity and thermopower of Bi2-xPbxSr2Co2Oy single crystals, which have a misfit structure between the hexagonal CoO2 layer and the rock salt Bi2Sr2O4 layer. The resistivity and thermopower…

Strongly Correlated Electrons · Physics 2009-11-07 Takenori Fujii , Ichiro Terasaki , Takao Watanabe , Azusa Matsuda

A systematic study of the compression creep properties of a single-crystalline Co-base superalloy (Co-9Al-7.5W-2Ta) was conducted at 950 {\deg}C, 975 {\deg}C and 1000 {\deg}C to reveal the influence of temperature and the resulting…

Ce(O,F)Sb(S,Se)2 single crystals were successfully grown using a CsCl/KCl flux method. The obtained crystals have a plate-like shape with the typical size of 1-2 mm and well-developed ab-plane, which enables X-ray single crystal structural…

Single crystals of Na$_{0.5}$CoO$_2$ were obtained through a flux method followed by de-intercalation of sodium. The Na$_{0.5}$CoO$_2$ samples were found to be vulnerable to water in the air and a hydration process in which H$_2$O molecules…

Strongly Correlated Electrons · Physics 2007-05-23 X. Z. Chen , Z. A. Xu , G. H. Cao , J. Q. Shen , L. M. Qiu , Z. H. Gan