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Few-layer graphene possesses low-energy carriers which behave as massive fermions, exhibiting intriguing properties in both transport and light scattering experiments. Lowering the excitation energy of resonance Raman spectroscopy down to…

Polycyclic aromatic hydrocarbons (PAHs) are responsible for a variety of near- and mid-infrared spectral features in Galactic and extragalactic sources. A feature at 1.05 $\mu$m arising from electronic transitions in PAH cations is…

Astrophysics of Galaxies · Physics 2026-03-25 Dennis Lee , Brandon S. Hensley , Tzu-Ching Chang , Olivier Doré

While crystalline two-dimensional materials have become an experimental reality during the past few years, an amorphous 2-D material has not been reported before. Here, using electron irradiation we create an sp2-hybridized one-atom-thick…

Materials Science · Physics 2011-03-22 J. Kotakoski , A. V. Krasheninnikov , U. Kaiser , J. C. Meyer

We present a new method to decompose the emission features of polycyclic aromatic hydrocarbons (PAHs) from mid-infrared spectra using theoretical PAH templates in conjunction with modified blackbody components for the dust continuum and an…

Astrophysics of Galaxies · Physics 2018-06-26 Yanxia Xie , Luis C. Ho , Aigen Li , Jinyi Shangguan

We study, theoretically and experimentally, optical properties of different types of honeycomb photonic structures, known also as `photonic graphene'. First, we employ the two-photon polymerization method to fabricate the honeycomb…

Mesoscale and Nanoscale Physics · Physics 2017-08-01 Artem D. Sinelnik , Mikhail V. Rybin , Stanislav Y. Lukashenko , Mikhail F. Limonov , Kirill B. Samusev

The properties of polycrystalline materials are often dominated by the size of their grains and by the atomic structure of their grain boundaries. These effects should be especially pronounced in 2D materials, where even a line defect can…

Laser-Arc evaporation of a graphite target has been used to deposit carbon films that exhibit high hardness (45 GPa) and elastic recovery (85%). High Resolution Electron Microscopy (HREM) and Electron Energy Loss Spectroscopy (EELS) were…

Materials Science · Physics 2009-10-31 I. Alexandrou , H. -J. Scheibe , C. J. Kiely , A. J. Papworth , G. A. J. Amaratunga , B. Schultrich

We compare the main feature of the measured Raman scattering spectra from single layer graphene with a bilayer in which the two layers are arbitrarily misoriented. The profiles of the 2D bands are very similar having only one component,…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Philippe Poncharal , Anthony Ayari , Thierry Michel , Jean-Louis Sauvajol

The buffer layer has been analysed by combined micro-Raman and micro-transmission experiments. The epitaxial graphene growth on the (0001) Si face of 6H-SiC substrates was tuned to get a mixed surface at the early stage of graphitization…

Mesoscale and Nanoscale Physics · Physics 2012-12-07 A. Tiberj , J. R. Huntzinger , N. Camara , P. Godignon , J. Camassel

This paper reports the experimental determination of the phase-breaking length L of conduction electrons in graphene using Raman spectroscopy. Based on the double-resonance model, we extract L from the spatial dependence of the D band…

Materials Science · Physics 2008-02-27 Luiz Gustavo Cancado , Ryan Beams , Lukas Novotny

Lattice structure and symmetry of two-dimensional (2D) layered materials are of key importance to their fundamental mechanical, thermal, electronic and optical properties. Raman spectroscopy, as a convenient and nondestructive tool, however…

Mesoscale and Nanoscale Physics · Physics 2015-08-28 Yanqing Feng , Wei Zhou , Yaojia Wang , Jian Zhou , Erfu Liu , Yajun Fu , Zhenhua Ni , Xinglong Wu , Hongtao Yuan , Feng Miao , Baigeng Wang , Xiangang Wan , Dingyu Xing

The paper presents a joint consideration of Raman spectra of sp2 amorphous carbons alongside with the nature and type of their amorphicity. The latter was attributed to the enforced fragmentation. The fragments, presented with…

Materials Science · Physics 2020-07-14 E. F. Sheka , Ye. A. Golubev , N. A. Popova

The phonon properties, electronic structures and optical properties of novel carbon allotropes, such as monolayer penta-graphene (PG), double-layer PG and T12-carbon, were explored by means of first-principles calculations. Results of…

In this report we present an investigation of the optical properties and band structure calculations for the photonic structures based on the functional materials- ferroelectrics. A theoretical approach to the optical properties of the 2D…

Optics · Physics 2013-05-08 Sevket Simsek , Amirullah M. Mamedov , Ekmel Ozbay

The recent spectacular progress in the experimental and theoretical understanding of graphene, the basic constituent of graphite, is applied here to compute, from first principles, the UV extinction of nano-particles made of stacks of…

Astrophysics of Galaxies · Physics 2015-06-15 R. J. Papoular , S. Yuan , R. Roldan , M. I. Katsnelson , R. Papoular

Raman spectroscopy has been employed to distinguish between the Raman spectrum of pristine hydrogenated diamond like carbon (PHDLC) and that of electrochemically hydrogenated diamond like carbon (ECHDLC). The enhancement of the background…

Materials Science · Physics 2013-12-02 Hari Shankar Biswas , Jagannath Datta , Pintu Sen , Uday Chand Ghosh , Nihar Ranjan Ray

There is only a handful of scanning techniques that can provide surface topography at nanometre resolution. At the same time, there are no methods that are capable of non-invasive imaging of the three-dimensional surface topography of a…

Instrumentation and Detectors · Physics 2017-03-07 Tatiana Latychevskaia , Wei-Hao Hsu , Wei-Tse Chang , Chun-Yueh Lin , Ing-Shouh Hwang

We study the spatial distribution and chemistry of small hydrocarbons in the Orion Bar PDR. We used the IRAM-30m telescope to carry out a millimetre line survey towards the Orion Bar edge, complemented with ~2'x2' maps of the C2H and c-C3H2…

Astrophysics of Galaxies · Physics 2015-03-04 S. Cuadrado , J. R. Goicoechea , P. Pilleri , J. Cernicharo , A. Fuente , C. Joblin

We present a Raman study of Ar(+)-bombarded graphene samples with increasing ion doses. This allows us to have a controlled, increasing, amount of defects. We find that the ratio between the D and G peak intensities for a given defect…

Electrochemical exfoliation is one of the most promising methods for scalable production of graphene. However, limited understanding of its Raman spectrum as well as lack of measurement standards for graphene strongly limit its industrial…