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An accurate determination of the electron correlation energy is essential for describing the structure, stability, and function in a wide variety of systems, ranging from gas-phase molecular assemblies to condensed matter and…

Chemical Physics · Physics 2014-03-05 Alberto Ambrosetti , Anthony M. Reilly , Robert A. DiStasio , Alexandre Tkatchenko

Excitation energies and transition probabilities of the first $2^+$ excitations in even tin and lead isotopes as well as the quadrupole moments of odd neighbors of these isotopes are calculated within the self-consistent Theory of Finite…

Nuclear Theory · Physics 2013-05-29 S. V. Tolokonnikov , S. Kamerdzhiev , D. Voytenkov , S. Krewald , E. E. Saperstein

Generalized mean-field approach for thermodynamic description of relativistic single- and multi-component gas in the grand canonical ensemble is formulated. In the framework of the proposed approach different phenomenological…

Nuclear Theory · Physics 2015-09-10 D. Anchishkin , V. Vovchenko

We study the role of pairwise long-range interactions in the formation of van der Waals molecules through direct three-body recombination processes A + B + B $\rightarrow$ AB + B, based on a classical trajectory method in hyperspherical…

Chemical Physics · Physics 2021-09-06 Marjan Mirahmadi , Jesús Pérez-Ríos

This study employs the isospin-dependent Boltzmann-Uehling-Uhlenbeck model to simulate intermediate-energy heavy-ion collisions between prolate nuclei $^{24}$Mg. The emphasis is on investigating the influence of centrality and orientation…

Nuclear Theory · Physics 2023-09-12 Xiao-Hua Fan , Zu-Xing Yang , Peng-Hui Chen , Shunji Nishimura , Zhi-Pan Li

For like charged colloidal particles two mechanisms of attraction between them survive when the interparticle distance is larger than the Debye screening length. One of them is the conventional van der Waals attraction and the second one is…

Soft Condensed Matter · Physics 2009-08-25 T. Ocampo-Delgado , B. Ivlev

We investigate the potential energy curves of rare-gas dimers with various ranges and strengths of interparticle interactions (nuclear-electron, electron-electron, and nuclear-nuclear interactions). Our investigation is based on the highly…

Chemical Physics · Physics 2016-02-05 Yu-Ting Chen , Kerwin Hui , Jeng-Da Chai

Van der Waals forces between atoms and molecules are universally assumed to act along the line separating them. Inspired by recent works on effects which can propel atoms parallel to a macroscopic surface via the Casimir--Polder force, we…

Quantum Physics · Physics 2020-09-03 Pablo Barcellona , Robert Bennett , Stefan Yoshi Buhmann

We present methods for accurate evaluation of van der Waals coefficients of dimers with excited atoms that have a strong decay channel. We calculate C_6 coefficients for the Yb-Yb 1S_0+ 3P_{0,1}, 3P_0+3P_0 and Yb-Rb 3P_1+5s, 1S_0+ 5p_{1/2}…

Atomic Physics · Physics 2013-07-11 S. G. Porsev , M. S. Safronova , A. Derevianko , Charles W. Clark

Energies of (3s2 3p6 3d9 4l4l'), (3s2 3p5 3d10 4l4l'), and (3s 3p6 3d10 4l4l') states for Cu-like ions with Z = 30 -100 are evaluated to second order in relativistic many-body perturbation theory (RMBPT) starting from a Ni-like Dirac-Fock…

Atomic Physics · Physics 2009-11-10 U. I. Safronova , W. R. Johnson , A. Shlyaptseva , S. Hamasha

In this work we improve upon previous results on the expansion of the interaction energy of two atoms. On the one hand we prove the van der Waals-London's law, assuming that only one of the ground state eigenspaces of the atoms is…

Mathematical Physics · Physics 2019-02-19 Ioannis Anapolitanos , Mathieu Lewin , Matthias Roth

A modified static exchange model is introduced, it could be useful to control the elastic s-wave scattering length in studying cold-atomic interaction. The theory includes the long-range van der Waals interaction in addition to short-range…

Atomic Physics · Physics 2012-10-09 Hasi Ray

The method of Monte Carlo configuration interaction (MCCI) [1,2] is applied to the calculation of multipole moments. We look at the ground and excited state dipole moments in carbon monoxide. We then consider the dipole of NO, the…

Chemical Physics · Physics 2013-04-12 J. P. Coe , D. J. Taylor , M. J. Paterson

We commence our study with review of dispersion interactions in electrolytes. We then reflect on how background media change atom-atom excited-state systems. To highlight the impact of nonlocal media, such as salt solutions, we predict that…

Quantum Physics · Physics 2025-12-29 L. Inácio , A. Kurumbail , S. K. Panja , I. Brevik , M. Boström

Relativistic dipolar to hexadecapolar polarizabilities of the ground state and some excited states of hydrogenic atoms are calculated by using numerically exact energies and wave functions obtained from the Dirac equation with the…

Atomic Physics · Physics 2016-04-27 Livio Filippin , Michel Godefroid , Daniel Baye

Intermolecular polarization interactions in water are determined using a minimal atomic multipole model constructed with distributed polarizabilities. Hydrogen bonding and other properties of water-water interactions are reproduced to fine…

Atomic and Molecular Clusters · Physics 2009-11-10 Eugene V. Tsiper

A new class of strongly infrared active structures is identified for phase III of compressed molecular H2 by constant-pressure ab initio molecular dynamics and density-functional perturbation calculations. These are planar quadrupolar…

Materials Science · Physics 2009-10-31 Jorge Kohanoff , Sandro Scandolo , Stefano de Gironcoli , Erio Tosatti

Based on macroscopic QED in linear, causal media, we present a consistent theory for the Casimir-Polder force acting on an atom positioned near dispersing and absorbing magnetodielectric bodies. The perturbative result for the van-der-Waals…

Quantum Physics · Physics 2016-08-16 S. Y. Buhmann , Ho Trung Dung , T. Kampf , L. Knöll , D. -G. Welsch

The azimuthal ($\Delta\varphi$) correlation distributions between heavy-flavor decay electrons and associated charged particles are measured in pp and p$-$Pb collisions at $\sqrt{s_{\rm{NN}}} = 5.02$ TeV. Results are reported for electrons…

Nuclear Experiment · Physics 2023-10-04 ALICE Collaboration

It is well known that for the case of two neutral but electrically polarizable atoms the consideration or not of retardation effects on the dispersive van der Waals force between them leads essentially to different power laws for the…

Atomic Physics · Physics 2007-05-23 C. Farina , F. C. Santos , A. C. Tort