English

Towards an understanding of dipole-dipole interactions in nonlocal media

Quantum Physics 2025-12-29 v1 Mesoscale and Nanoscale Physics Atomic Physics

Abstract

We commence our study with review of dispersion interactions in electrolytes. We then reflect on how background media change atom-atom excited-state systems. To highlight the impact of nonlocal media, such as salt solutions, we predict that a new contribution to the resonance interaction energy emerges in a form eκDρ/ρ\propto e^{-\kappa_{\rm D} \rho}/\rho. Here κD\kappa_{\rm D} is the Debye length and ρ\rho is the distance between the atoms. This contribution vanishes at zero temperature, where a new term proportional to 1/ρ41/\rho^4 (similar to free space) occurs. This new term is dampened by the electrolyte at large distances, causing it to decrease much faster, proportional to 1/ρ71/\rho^7. The long-range electrolyte-induced resonance interaction at finite temperature may, in addition to the dominating van der Waals attraction (which goes as 1/ρ61/\rho^6), take part in the molecular formation of biological fluids.

Keywords

Cite

@article{arxiv.2512.22041,
  title  = {Towards an understanding of dipole-dipole interactions in nonlocal media},
  author = {L. Inácio and A. Kurumbail and S. K. Panja and I. Brevik and M. Boström},
  journal= {arXiv preprint arXiv:2512.22041},
  year   = {2025}
}

Comments

15 pages, 2 figures