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The ground-state structural and electronic properties of ferroelectric BiFeO$_3$ are calculated using density functional theory within the local spin-density approximation and the LSDA+U method. The crystal structure is computed to be…

Materials Science · Physics 2007-05-23 J. B. Neaton , C. Ederer , U. V. Waghmare , N. A. Spaldin , K. M. Rabe

Nitride perovskites are supposed to exhibit excellent properties as oxide analogues and may even have better performance in specific fields for their more covalent characters. However, till now, very limited nitride perovskites have been…

Materials Science · Physics 2020-12-02 Churen Gui , Shuai Dong

Ferroelectric materials display exotic polarization textures at the nanoscale that could be used to improve the energetic efficiency of electronic components. The vast majority of studies were conducted in two dimensions on thin films, that…

An atomistic effective Hamiltonian technique is used to investigate the finite-temperature energy storage properties of a ferroelectric nanocomposite consisting of an array of BaTiO$_{3}$ nanowires embedded in a SrTiO$_{3}$ matrix, for…

We present the results of magnetic measurements on Nd6Co(1.67)Si3, a compound recently reported to crystallize in a hexagonal structure (space group P6_3/m) and to undergo long range magnetic ordering below 84 K. The results reveal that the…

Strongly Correlated Electrons · Physics 2009-11-13 Niharika Mohapatra , S. Narayana Jammalamadaka , Sitikantha D. Das , E. V. Sampathkumaran

First-principles calculations were performed to investigate the ferroelectric properties of barium titanate and bismuth ferrite, as well as phonon dispersion of BaTiO3, using density functional theory and density functional perturbation…

Materials Science · Physics 2014-12-08 Hong-Jian Feng

Reversible intercalation of hydrogen into samarium nickelate, SmNiO$_3$ (SNO), has been of recent interest. Upon entering SNO, the hydrogen dissociates: the H$^+$ binds to an oxygen and the valence electron localizes on a nearby NiO$_6$…

Materials Science · Physics 2024-06-04 Michele Kotiuga , Karin M. Rabe

We use molecular dynamics simulations to understand the mechanisms of polarization switching in ferroelectric BaTiO$_3$ achieved with external electric field. For tetragonal and orthorhombic ferroelectric phases, we determine the switching…

Materials Science · Physics 2009-11-13 Jaita Paul , Takeshi Nishimatsu , Yoshiyuki Kawazoe , Umesh V. Waghmare

The direction of ferroelectric polarization is prescribed by the symmetry of the crystal structure. Therefore, rotation of the polarization direction is largely limited, despite the opportunity it offers in understanding important…

Polarization dynamics and domain structure evolution in ferroelectric Al$_{0.93}$B$_{0.07}$N are studied using piezoresponse force microscopy and spectroscopies in ambient and controlled atmosphere environments. The application of negative…

The spontaneous polarization, dynamical Born charges, and piezoelectric constants of the III-V nitrides AlN, GaN, and InN are studied ab initio using the Berry phase approach to polarization in solids. The piezoelectric constants are found…

Materials Science · Physics 2009-10-30 Fabio Bernardini , Vincenzo Fiorentini , David Vanderbilt

Ferroelectric materials are a class of dielectrics that exhibit spontaneous polarization which can be reversed under an external electric field. The emergence of ferroelectric order in incipient ferroelectrics is a topic of considerable…

Materials Science · Physics 2025-10-31 Yu Zhu , Luigi Ranalli , Taikang Chen , Wei Ren , Cesare Franchini

Low temperature studies of the behavior of the sound velocity and attenuation of acoustic modes have been performed on a single crystal NdFe_3(BO_3)_4. Transitions of the magnetic subsystem to the antiferromagnetically ordered state at T_N…

Strongly Correlated Electrons · Physics 2015-05-27 G. A. Zvyagina , K. R. Zhekov , I. V. Bilych , A. A. Zvyagin , I. A. Gudim , V. L. Temerov

Antiferroelectrics generate significant interest since their polarization versus electric field (PE) curves show typical double-hysteresis loops appealing for various applications. Unfortunately, antiferroelectrics are rare. In magnetic…

Ferroelectricity, a hallmark of spontaneous inversion-symmetry breaking, has been a central concept in condensed matter physics and functional materials research, yet recent discoveries are revealing that switchable polarization can emerge…

Materials Science · Physics 2026-05-11 Yudi Yang , Changming Ke , Shi Liu

In this paper we study the size effects of the ferroelectric nanotube and nanowire phase diagrams and polar properties allowing for radial stress and depolarization field influence. The approximate analytical expression for the…

Materials Science · Physics 2009-05-09 Anna N. Morozovska , Maya D. Glinchuk , Eugene A. Eliseev

Macroscopic polarization, both of intrinsic and piezoelectric nature, is unusually strong in III-V nitrides, and the built in electric fields in the layers of nitride-based nanostructures, stemming from polarization changes at…

Materials Science · Physics 2009-10-31 Fabio Bernardini , Vincenzo Fiorentini

Size-driven transition of an antiferroelectric into a polar ferroelectric or ferrielectric state is a strongly debated issue from both experimental and theoretical perspectives. While critical thickness limits for such transitions have been…

We demonstrate that small but finite ferroelectric polarization ($\sim$0.01 $\mu$C/cm$^2$) emerges in orthorhombic LuFeO$_3$ ($Pnma$) at $T_N$ ($\sim$600 K) because of commensurate (k = 0) and collinear magnetic structure. The synchrotron…

Weakly coupled ferroelectric/dielectric superlattice thin film heterostructures exhibit complex nanoscale polarization configurations that arise from a balance of competing electrostatic, elastic, and domain-wall contributions to the free…