Related papers: N2H+ and N2D+ in interstellar molecular clouds. II…

Chloronium (H$_2$Cl$^+$) is an important intermediate of Cl-chemistry in space. The accurate knowledge of its collisional properties allows a better interpretation of the corresponding observations in interstellar clouds and therefore a…

Infrared dark clouds (IRDCs) are dense, molecular structures in the interstellar medium that can harbour sites of high-mass star formation. IRDCs contain supersonic turbulence, which is expected to generate shocks that locally heat pockets…

Using state-of-the-art ab initio interaction-induced dipole and potential-energy surfaces for hydrogen-helium (H2-He) pairs, we compute the rototranslational collision-induced absorption coefficient at 40-400 K for frequencies covering…

Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…

It has been suggested that the dark halos of galaxies are constituted by cloudlets of cold (< 10 K) H_2 and dense (> 10^7$ cm^{-3}) molecular gas. Such gas is extremely difficult to detect, because the classical tracers of molecular gas, CO…

We report the first detection in interstellar space of the 3-cyano propargyl radical (CH2C3N). This species was observed in the cold dark cloud TMC-1 using the Yebes 40m telescope. A total of seven rotational transitions for both ortho- and…

We report new observations of the 110-111 (6 cm) and 211-212 (2 cm) transitions of ortho-formaldehyde (o-H2CO) in absorption at z=0.68466 toward the gravitational lens system B0218+357. Radiative transfer modeling indicates that both…

We present observations of the \nh3 (J,K) = (1,1) and (2,2) inversion transitions toward the infrared dark cloud G28.34+0.06, using the Very Large Array. Strong NH3 emission is found to coincide well with the infrared absorption feature in…

The rotational excitation of the three asymmetric-top molecular ion isotopologues H$_2$O$^+$, HDO$^+$, and D$_2$O$^+$ is studied theoretically using a combined framework of electron-molecule R-matrix scattering theory, multichannel…

We analyze effects of neutron-antineutron transitions in neutron stars, specifically on (i) cooling, (ii) rotation rate, and (iii) for binary pulsars, the increase in the orbital period. We show that these effects are negligibly small.

We report JWST MIRI/MRS observations of the H2 S(1) 17.04 micron transition in two regions in the boundary of the Taurus Molecular Cloud. The two regions, denoted Edge (near the relatively sharp boundary of the 13CO J=1-0 emission) and Peak…

A one-dimensional method for reconstructing the structure of prestellar and protostellar clouds is presented. The method is based on radiative transfer computations and a comparison of theoretical and observed intensity distributions at…

The presence of H2D+ in dense cloud cores underlies ion-molecule reactions that strongly enhance the deuterium fractionation of many molecular species. We determine the H2D+ abundance in one starless core, Barnard 68, that has a…

The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species…

We present three-dimensional astrochemical simulations and synthetic observations of magnetised, turbulent, self-gravitating molecular clouds. We explore various galactic interstellar medium environments, including cosmic-ray ionization…

Sulphur-bearing species play crucial roles in interstellar chemistry, yet their precise characterisation remains challenging. Here, we present laboratory experiments aimed at extending the high-resolution spectroscopy of protonated carbonyl…

We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 972 GHz N…

The rotational spectral modulation (spectro-photometric variability) of brown dwarfs is usually interpreted as a sign of the presence of inhomogeneous cloud covers in the atmosphere. This paper aims at exploring the role of temperature…

Vibrational overtones in deeply bound molecules are sensitive probes for variation of the proton-to-electron mass ratio $\mu$. In nonpolar molecules, these overtones may be driven as two-photon transitions. Here, we present procedures for…

Sulfur-bearing molecules are central to interstellar chemistry, yet their observed abundances in the gas phase remain far below cosmic expectations in dense interstellar regions. Mixed N-S-O species such as thionylimide (HNSO) are…