Related papers: N2H+ and N2D+ in interstellar molecular clouds. II…

We report the results of initial FUSE observations of molecular hydrogen (H2) in translucent clouds. These clouds have greater optical depth than any of the diffuse clouds previously observed for far-UV H2 absorption, and provide new…

Much of the dense gas in molecular clouds has a filamentary structure but the detailed structure and evolution of this gas is poorly known. We have observed 54 cores in infrared dark clouds (IRDCs) using N$_2$H$^+$ (1-0) and (3-2) to…

Many theoretical and laboratory studies predict H2 to be formed in highly excited ro-vibrational states. The consequent relaxation of excited levels via a cascade of infrared transitions might be observable in emission from suitable…

We have detected the J=4-3 rotational transition of 12CO in absorption at z=0.89 towards the quasar PKS1830-211, but not the 12CO 5-4 or the 3P1-3P0 fine structure line of neutral carbon. The intervening molecular medium thus has a total…

Aims. This paper reports accurate laboratory frequencies of the rotational ground state transitions of two astronomically relevant molecular ions, NH3D+ and CF+. Methods. Spectra in the millimeter-wave band were recorded by the method of…

C$_2$H is one of the first radicals to be detected in the interstellar medium. Its higher rotational transitions have recently become available with the Herschel Space Observatory. We aim to constrain the physical parameters of the C$_2$H…

We report the first detection of HS2 towards the cold dark cloud TMC-1. This is the first observation of a chemical species containing more than one sulphur atom in this type of sources. The astronomical observations are part of QUIJOTE, a…

We present a high-resolution millimeter study of the very young Class 0 protostar IRAM 04191+1522 in the Taurus molecular cloud. N2H+(1-0) observations with the IRAM Plateau de Bure Interferometer and 30m telescope demonstrate that the…

Rotational transitions in molecular hydrogen collisions are computed. The two most recently developed potential energy surfaces for the H2-H2 system are used from the following works: 1) A.I. Boothroyd, P.G. Martin, W.J. Keogh, M.J.…

We present an extensive range of quantum calculations for the state-changing rotational dynamics involving two simple molecular anions which are expected to play some role in evolutionary analysis of chemical networks in the Interstellar…

We present a nonrelativistic calculation of the rotation-vibration levels of the molecular ions H2+, D2+ and HD+, relying on the diagonalization of the exact three-body Hamiltonian. The J=2 levels are obtained with a very high accuracy of…

Two different ab initio potential energy surfaces are employed to investigate the efficiency of the rotational excitation channels for the polar molecular ion HeH$^+$ interacting with He atoms. We further use them to investigate the quantum…

Cross sections have been computed for rotational transitions of H2, induced by collisions with H atoms, using a recent H - H2 potential calculated by Mielke et al. [1]. These results are compared with those obtained with earlier potentials.…

We report the first identification in space of HC$_3$N$^+$, the simplest member of the family of cyanopolyyne cations. Three rotational transitions with half-integer quantum numbers from $J$=7/2 to 11/2 have been observed with the Yebes 40m…

We report the detection of absorption lines by the reactive ions OH+, H2O+ and H3O+ along the line of sight to the submillimeter continuum source G10.6$-$0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe…

We have detected new HD absorption systems at high redshifts, z_abs=2.626 and z_abs=1.777, identified in the spectra of the quasars J0812+3208 and Q1331+170, respectively. Each of these systems consists of two subsystems. The HD column…

The $\rm H_2$ mass of molecular clouds has traditionally been traced by the CO(J=1-0) rotational transition line. This said, CO is relatively easily photodissociated, and can also be destroyed by cosmic rays, thus rendering some fraction of…

A series of Multichannel Quantum Defect Theory-based computations have been performed, in order to produce the cross sections of rotational transitions (excitations $N_{i}^{+}-2 \rightarrow$ $N_{i}^{+}$, de-excitations $N_{i}^{+}$…

The carbon monoxide (CO) rotational transition lines are the most common tracers of molecular gas within giant molecular clouds (MCs). We study the ratio ($R_{2-1/1-0}$) between CO's first two emission lines and examine what information it…

The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…