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We numerically and experimentally investigate graphene-based optical absorbers that exploit guided mode resonances (GMRs) achieving perfect absorption over a bandwidth of few nanometers (over the visible and near-infrared ranges) with a…

We show that surface-plasmon polaritons excited in negative permittivity metamaterials having shallow periodic surface corrugation profiles can be explored to push the absorption of single and continuous sheets of graphene up to 100%. In…

Mesoscale and Nanoscale Physics · Physics 2012-11-12 A. Ferreira , N. M. R. Peres

Graphene is a promising candidate to succeed silicon based devices and doping holds the key to graphene electronics. Conventional doping methods through surface functionalization or lattice modification are effective in tuning carrier…

Mesoscale and Nanoscale Physics · Physics 2016-11-16 Yangbo Zhou , Jakub Jadwiszczak , Darragh Keane , Ying Chen , Dapeng Yu , Hongzhou Zhang

We theoretically study absorption by an undoped graphene layer decorated with arrays of small particles. We discuss periodic and random arrays within a common formalism, which predicts a maximum absorption of $50\%$ for suspended graphene…

Mesoscale and Nanoscale Physics · Physics 2014-02-24 T. Stauber , G. Gómez-Santos , F. Javier García de Abajo

Monolayer of hexagonal boron nitride (h-BN), commonly known as "white graphene" is a promising wide bandgap semiconducting material for deep-ultaviolet optoelectronic devices. In this report, the light absorption of a single layer hexagonal…

Mesoscale and Nanoscale Physics · Physics 2011-09-26 Aniruddha Konar , Raj Jana , Tian Fang , Guowang Li , William O'Brien , Debdeep Jena

We propose a mechanism by which chloromethane and dichloromethane decomposition reaction occurs on the surfaces of graphene. To this end we have performed calculations on the graphene surface with metal adsorption on the sheet on the…

Chemical Physics · Physics 2016-02-23 Y. P. Ortiz , A. F. Jalbout

Using density-functional theory and a tight-binding approach we investigate the physical origin of distinct favourable geometries of adsorbed hydrogen atoms in various graphyne structures, and the relation with electronic properties. In…

Materials Science · Physics 2014-02-07 Hunpyo Lee , Jahyun Koo , Massimo Capone , Yongkyung Kwon , Hoonkyung Lee

We investigate the chemisorptions of oxygen molecules on bilayer graphene (BLG) and its electrically modified charge-doping effect using conductivity measurement of the field effect transistor channeled with BLG. We demonstrate that the…

Mesoscale and Nanoscale Physics · Physics 2011-08-10 Yoshiaki Sato , Kazuyuki Takai , Toshiaki Enoki

We have investigated the way in which the concentration and distribution of adatoms affect the geometric and electronic properties of graphene. Our calculations were based on the use of first principle under the density functional theory…

Mesoscale and Nanoscale Physics · Physics 2017-03-08 Ngoc Thanh Thuy Tran , Dipendra Dahal , Godfrey Gumbs , Ming-Fa Lin

We present a theoretical study of the structural and electronic properties of graphene monolayer functionalized with boron and nitrogen atoms substituting carbon atoms. Our study is based on the ab initio calculations in the framework of…

Materials Science · Physics 2013-07-29 Magdalena Woinska , Karolina Z. Milowska , Jacek A. Majewski

Adsorption of para-Hydrogen on the surface of graphite pre-plated with a single layer of atomic krypton is studied thoretically by means of Path Integral Ground State Monte Carlo simulations. We compute energetics and density profiles of…

Statistical Mechanics · Physics 2009-11-11 Joseph Turnbull , Massimo Boninsegni

We present a comparative study of DNA nucleobases [guanine (G), adenine (A), thymine (T), and cytosine (C)] adsorbed on hexagonal boron nitride (\textit{h}-BN) sheet and graphene, using local, semilocal, and van der Waals (vdW)…

Mesoscale and Nanoscale Physics · Physics 2013-07-04 Jun-Ho Lee , Yun-Ki Choi , Hyun-Jung Kim , Ralph H. Scheicher , Jun-Hyung Cho

Ab initio self-consistent total energy calculations using second order Moller-Plesset perturbation theory and Hay-Wadt effective core potentials for gallium and arsenic have been used to investigate the chemisorption of atomic oxygen on the…

Condensed Matter · Physics 2007-05-23 Michael L. Mayo , Asok K. Ray

The adsorption of fluorine, chlorine, bromine, and iodine diatomic molecules on graphene has been investigated using density functional theory with taking into account nonlocal correlation effects by means of vdW-DF approach. It is shown…

Mesoscale and Nanoscale Physics · Physics 2010-09-15 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Molecular adsorption on surfaces plays an important part in catalysis, corrosion, desalination, and various other processes that are relevant to industry and in nature. As a complement to experiments, accurate adsorption energies can be…

While doping and defects are often considered detrimental to material performance, at the nanoscale, modifications are needed to create novel properties beneficial for device applications. In this work, we focus on optimizing graphene as a…

Applied Physics · Physics 2025-05-21 Raju Kumar Yadav , Prince Philip , Boddepalli SanthiBhushan

Graphone is a half-hydrogenated graphene. The structure of graphone is illustrated as trigonal adsorption of hydrogen atoms on graphene at first. However, we found the trigonal adsorption is unstable. We present an illustration in detail to…

Mesoscale and Nanoscale Physics · Physics 2014-02-19 L. Feng , W. X. Zhang

First-principles calculations based on density functional theory (DFT) have been employed to investigate the structural, electronic, and gas-sensing properties of pure, defected, and doped germanene nanosheets. Our calculations have…

Materials Science · Physics 2017-07-13 Md Monirojjaman Monshi , Sadegh Mehdi Aghaei , Irene Calizo

Graphene-based materials (GBMs) constitute a large family of materials which has attracted great interest for potential applications. In this work, we apply first-principles calculations based on density functional theory (DFT) and fully…

Materials Science · Physics 2021-05-05 Enesio Marinho , Pedro A. S. Autreto

Two-dimensional porous carbon nanomaterials are proven to be promising hydrogen storage substrates as they possess high surface area, large number of active sites, low molecular mass, and hydrogen molecules can be adsorbed on both sides of…

Materials Science · Physics 2023-12-05 Vikram Mahamiya , Alok Shukla , Brahmananda Chakraborty