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This review on graphene, a one atom thick, two-dimensional sheet of carbon atoms, starts with a general description of the graphene electronic structure as well as a basic experimental toolkit for identifying and handling this material.…

Materials Science · Physics 2010-11-22 Caterina Soldano , Ather Mahmood , Erik Dujardin

A great efficacy of molecular quantum chemistry applied to basic graphene problems has been recently demonstrated by the authors when studying the formation of peculiar composites between carbon nanotubes and graphene as well as considering…

Mesoscale and Nanoscale Physics · Physics 2011-02-07 Elena F Sheka , Nadezhda A Popova

The adsorption energies and orientation of methanol on graphene are determined from first-principles density functional calculations. We employ the well-tested vdW-DF method that seamlessly includes dispersion interactions with all of the…

Materials Science · Physics 2013-03-18 Elsebeth Schroder

Pristine graphene is not suitable for hydrogen storage at ambient conditions since it binds the hydrogen molecules only by van der Waals interactions. However, the adsorption energy of the hydrogen molecules can be improved by doping or…

Materials Science · Physics 2022-10-24 Vikram Mahamiya , Alok Shukla , Nandini Garg , Brahmananda Chakraborty

Adsorption of hydrogen atoms to a carbon atom vacancy in graphene is investigated by means of periodic \emph{first principles} calculations, up to the fully hydrogenated state where six H atoms chemically bind to the vacancy. Addition of a…

Materials Science · Physics 2013-12-30 M. Casartelli , S. Casolo , G. F. Tantardini , R. Martinazzo

Compressed hydrogen passes through a series of layered structures in which the layers can be viewed as distorted graphene sheets. The electronic structures of these layered structures can be understood by studying simple model systems- an…

Materials Science · Physics 2013-05-22 Ivan I. Naumov , R. E. Cohen , Russell J. Hemley

Based on a new self-energy for atom-phonon interaction, preceding Comment argues about the insufficiency of the mathematical techniques within the Independent Boson Model (IBM) to study physisorption in graphene membranes. In this Reply, we…

Materials Science · Physics 2020-07-15 Sanghita Sengupta

Graphene has been studied in detail due to its mechanical, electrical, and thermal properties. It is well documented that the introduction of dopants or defects in the lattice can be used to tune material properties for a specific…

Materials Science · Physics 2025-09-11 Benedict Saunders , Lukas Hörmann , Reinhard J. Maurer

Two different types of boron-doped graphene/copper interfaces synthesized using two different flow rates of Ar through the bubbler containing the boron source were studied. X-ray photoelectron spectra (XPS) and optically stimulated electron…

Boron-doped graphene was reported to be the best non-metal doped graphene electrocatalyst for the oxygen reduction reaction (ORR) working at an onset potential of 0.035 V [JACS 136 (2014) 4394]. In the present DFT study, intermediates and…

Materials Science · Physics 2016-07-28 Gianluca Fazio , Lara Ferrighi , Cristiana Di Valentin

We calculate the optical properties of atomic-sized core-shell graphene - boron nitride nanoflakes with triangular shaped crossection using the density functional theory. The optical properties can be tuned by using different sizes and…

Mesoscale and Nanoscale Physics · Physics 2014-12-25 Andreea A. Nila , George Alexandru Nemnes , Andrei Manolescu

Inspired by a recent experimental and theoretical study [Yang et al., 2017], wherein protrusions in graphene have been proposed as an effective strategy to enhance the performance of sodium ion batteries, a comprehensive study of the…

Applied Physics · Physics 2020-06-08 Babita Rani , Vladimir Bubanja , Vijay K. Jindal

Graphene/hBN heterostructures can be considered as one of the basic building blocks for the next-generation optoelectronics mostly owing to the record-high electron mobilities. However, currently, the studies of the intrinsic optical…

Mean field analysis of the effective interfacial Hamiltonian shows that with increasing temperature the adsorption on a periodically corrugated substrate can proceed in two steps: first, there is the filling transition in which the…

Statistical Mechanics · Physics 2009-10-31 K. Rejmer , M. Napiorkowski

Graphene has received a great deal of attention and this has more recently extended to boron nitride sheets (BNS) with a similar structure. Both have hexagonal lattices and it is only the alternation of atoms in boron nitride, which changes…

Chemical Physics · Physics 2016-02-23 A. F. Jalbout , T. H. Seligman

Molecular hydrogen is at the core of hydrogen energy applications and has the potential to significantly reduce the use of carbon dioxide emitting energy processes. However, hydrogen gas storage is a major bottleneck for its large-scale use…

Materials Science · Physics 2025-01-22 Yasmine S. Al-Hamdani , Andrea Zen , Dario Alfé

We have investigated by means of first principles calculations the structural and electronic properties of hydrogenated graphene structures with distinct grain boundary defects. Our total energy results reveal that the adsorption of a…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 W. H. Brito , R. Kagimura , R. H. Miwa

We study the low temperature properties of a single layer of parahydrogen adsorbed on graphene, by means of Quantum Monte Carlo simulations. The computed phase diagram is very similar to that of helium on the same substrate, featuring…

Mesoscale and Nanoscale Physics · Physics 2018-05-02 Marisa Dusseault , Massimo Boninsegni

Using first-principles calculations, we show that the formation of carbohydrate directly from carbon and water is energetically favored when graphene membrane is subjected to aqueous environment with difference in chemical potential across…

Mesoscale and Nanoscale Physics · Physics 2010-03-17 Wei L. Wang , Efthimios Kaxiras

By using first principles calculations we report a chemical doping induced gap in graphene. The structural and electronic properties of CrO$_3$ interacting with graphene layer are calculated using ab initio methods based on the density…

Materials Science · Physics 2007-11-08 I. Zanella S. Guerini , S. B. Fagan , J. Mendes Filho , A. G. Souza Filho
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